Validation Log
2025-12-15 00:28:17.265874
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003595/mwtab/txt
Study ID:      ST002196
Analysis ID:   AN003595
File format:   txt
Status: Contains Validation Issues
Number of Issues: 99

Number of Warnings: 92

Number of Value Errors: 94

Number of Consistency Errors: 0

Number of Format Errors: 5

Issue Log:
Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section  is missing.
Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #41 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #42 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #43 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #44 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #45 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #46 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #47 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #48 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #49 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #50 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #51 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #52 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #53 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #54 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #55 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #56 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #57 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #58 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #59 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #60 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #61 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #62 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #63 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #64 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #65 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #66 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #67 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #68 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #69 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #70 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #71 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #72 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #73 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #74 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #75 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #76 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #77 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #78 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #79 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #80 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #81 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #82 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #83 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #84 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #85 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #86 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #87 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #88 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #89 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #90 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The "PubChem" column at position 2 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Kegg ID" column at position 3 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.