Validation Log 2025-12-15 00:33:57.015565 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003688/mwtab/txt Study ID: ST002258 Analysis ID: AN003688 File format: txt Status: Contains Validation Issues Number of Issues: 53 Number of Warnings: 48 Number of Value Errors: 48 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #41 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #42 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #43 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #44 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #45 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #46 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #47 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #48 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME"