Validation Log 2025-12-15 00:34:53.509543 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003707/mwtab/json Study ID: ST002269 Analysis ID: AN003707 File format: json Status: Contains Validation Issues Number of Issues: 191 Number of Warnings: 185 Number of Value Errors: 188 Number of Consistency Errors: 0 Number of Format Errors: 2 Issue Log: Error: The value, "8.7-18.6 (year)", in ["SUBJECT"]["AGE_OR_AGE_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: The value, "Male and female", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The value, "50", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing. Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][10] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][11] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][12] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][13] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][14] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][15] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][16] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][17] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][18] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][19] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][20] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][21] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][22] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][23] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][24] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][25] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][26] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][27] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][28] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][29] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][30] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][31] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][32] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][33] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][34] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][35] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][36] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][37] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][38] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][39] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][40] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][41] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][42] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][43] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][44] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][45] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][46] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][47] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][48] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][49] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][50] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][51] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][52] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][53] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][54] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][55] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][56] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][57] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][58] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][59] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][60] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][61] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][62] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][63] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][64] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][65] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][66] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][67] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][68] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][69] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][70] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][71] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][72] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][73] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][74] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][75] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][76] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][77] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][78] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][79] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][80] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][81] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][82] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][83] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][84] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][85] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][86] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][87] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][88] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][89] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][90] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][91] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][92] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][93] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][94] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][95] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][96] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][97] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][98] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][99] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][100] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][101] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][102] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][103] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][104] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][105] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][106] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][107] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][108] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][109] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][110] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][111] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][112] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][113] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][114] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][115] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][116] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][117] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][118] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][119] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][120] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][121] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][122] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][123] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][124] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][125] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][126] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][127] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][128] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][129] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][130] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][131] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][132] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][133] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][134] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][135] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][136] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][137] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][138] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][139] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][140] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][141] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][142] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][143] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][144] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][145] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][146] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][147] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][148] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][149] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][150] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][151] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][152] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][153] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][154] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][155] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][156] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][157] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][158] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][159] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][160] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][161] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][162] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][163] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][164] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][165] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][166] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][167] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][168] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][169] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][170] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][171] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][172] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][173] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.