Validation Log 2025-12-15 00:39:05.036830 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003789/mwtab/json Study ID: ST002322 Analysis ID: AN003789 File format: json Status: Contains Validation Issues Number of Issues: 18 Number of Warnings: 10 Number of Value Errors: 10 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "1_2-dilinolenoyl-GPC (18:3/18:3)*" "1_2-dilinoleoyl-GPC (18:2/18:2)" "1_2-dilinoleoyl-GPE (18:2/18:2)*" "1_2-dioleoyl-GPC (18:1/18:1)" "1_2-dioleoyl-GPE (18:1/18:1)" "1_2-dipalmitoyl-GPC (16:0/16:0)" "1_2-dipalmitoyl-GPE (16:0/16:0)*" "1_2-distearoyl-GPC (18:0/18:0)" "2^-deoxyadenosine" "2^-deoxyadenosine 3^-monophosphate" "2^-deoxyadenosine 5^-monophosphate" "2^-deoxycytidine" "2^-deoxycytidine 5^-monophosphate" "2^-deoxyguanosine" "2^-deoxyinosine" "2^-deoxyuridine" "(3^-5^)-adenylyladenosine*" "(3^-5^)-adenylylcytidine" "(3^-5^)-adenylylguanosine*" "(3^-5^)-adenylyluridine" "3^-dephospho-CoA-glutathione*" "3^-dephosphocoenzyme A" "5_6-dihydrouridine" "adenosine 2^-monophosphate (2^-AMP)" "adenosine 3^-monophosphate (3^-AMP)" "adenosine 5^-diphosphoribose (ADP-ribose)" "adenosine 5^-monophosphate (AMP)" "ceramide (d16:1/24:1_ d18:1/22:1)*" "ceramide (d18:1/14:0_ d16:1/16:0)*" "ceramide (d18:1/17:0_ d17:1/18:0)*" "ceramide (d18:2/24:1_ d18:1/24:2)*" "cytidine 5^-diphosphocholine" "cytidine-5^-diphosphoethanolamine" "cytidine 5^-monophosphate (5^-CMP)" "fructose 1_6-diphosphate/glucose 1_6-diphosphate/myo-inositol diphosphates" "glutathione_ oxidized (GSSG)" "glutathione_ reduced (GSH)" "glycosyl ceramide (d16:1/24:1_ d18:1/22:1)*" "glycosyl ceramide (d18:1/20:0_ d16:1/22:0)*" "glycosyl ceramide (d18:2/24:1_ d18:1/24:2)*" "guanosine 5^-diphosphate (GDP)" "guanosine 5^-diphospho-fucose" "guanosine 5^-monophosphate (5^-GMP)" "hydroxy-N6_N6_N6-trimethyllysine*" "inosine 5^-monophosphate (IMP)" "N2_N2-dimethylguanosine" "N6_N6_N6-trimethyllysine" "N_N_N-trimethyl-5-aminovalerate" "N_N_N-trimethyl-alanylproline betaine (TMAP)" "S-(1_2-dicarboxyethyl)glutathione" "sphingomyelin (d17:1/16:0_ d18:1/15:0_ d16:1/17:0)*" "sphingomyelin (d18:0/18:0_ d19:0/17:0)*" "sphingomyelin (d18:1/14:0_ d16:1/16:0)*" "sphingomyelin (d18:1/17:0_ d17:1/18:0_ d19:1/16:0)" "sphingomyelin (d18:1/18:1_ d18:2/18:0)" "sphingomyelin (d18:1/19:0_ d19:1/18:0)*" "sphingomyelin (d18:1/20:0_ d16:1/22:0)*" "sphingomyelin (d18:1/22:1_ d18:2/22:0_ d16:1/24:1)*" "sphingomyelin (d18:1/22:2_ d18:2/22:1_ d16:1/24:2)*" "sphingomyelin (d18:1/24:1_ d18:2/24:0)*" "sphingomyelin (d18:2/16:0_ d18:1/16:1)*" "sphingomyelin (d18:2/23:0_ d18:1/23:1_ d17:1/24:1)*" "sphingomyelin (d18:2/24:1_ d18:1/24:2)*" "thymidine 5^-monophosphate" "trigonelline (N^-methylnicotinate)" "uridine 3^-monophosphate (3^-UMP)" "uridine 5^-diphosphate (UDP)" "uridine 5^-monophosphate (UMP)" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "1,2-dilinolenoyl-GPC (18:3/18:3)*" "1,2-dilinoleoyl-GPC (18:2/18:2)" "1,2-dilinoleoyl-GPE (18:2/18:2)*" "1,2-dioleoyl-GPC (18:1/18:1)" "1,2-dioleoyl-GPE (18:1/18:1)" "1,2-dipalmitoyl-GPC (16:0/16:0)" "1,2-dipalmitoyl-GPE (16:0/16:0)*" "1,2-distearoyl-GPC (18:0/18:0)" "2'-deoxyadenosine" "2'-deoxyadenosine 3'-monophosphate" "2'-deoxyadenosine 5'-monophosphate" "2'-deoxycytidine" "2'-deoxycytidine 5'-monophosphate" "2'-deoxyguanosine" "2'-deoxyinosine" "2'-deoxyuridine" "(3'-5')-adenylyladenosine*" "(3'-5')-adenylylcytidine" "(3'-5')-adenylylguanosine*" "(3'-5')-adenylyluridine" "3'-dephospho-CoA-glutathione*" "3'-dephosphocoenzyme A" "5,6-dihydrouridine" "adenosine 2'-monophosphate (2'-AMP)" "adenosine 3'-monophosphate (3'-AMP)" "adenosine 5'-diphosphoribose (ADP-ribose)" "adenosine 5'-monophosphate (AMP)" "ceramide (d16:1/24:1, d18:1/22:1)*" "ceramide (d18:1/14:0, d16:1/16:0)*" "ceramide (d18:1/17:0, d17:1/18:0)*" "ceramide (d18:2/24:1, d18:1/24:2)*" "cytidine 5'-diphosphocholine" "cytidine-5'-diphosphoethanolamine" "cytidine 5'-monophosphate (5'-CMP)" "fructose 1,6-diphosphate/glucose 1,6-diphosphate/myo-inositol diphosphates" "glutathione, oxidized (GSSG)" "glutathione, reduced (GSH)" "glycosyl ceramide (d16:1/24:1, d18:1/22:1)*" "glycosyl ceramide (d18:1/20:0, d16:1/22:0)*" "glycosyl ceramide (d18:2/24:1, d18:1/24:2)*" "guanosine 5'-diphosphate (GDP)" "guanosine 5'-diphospho-fucose" "guanosine 5'-monophosphate (5'-GMP)" "hydroxy-N6,N6,N6-trimethyllysine*" "inosine 5'-monophosphate (IMP)" "N2,N2-dimethylguanosine" "N6,N6,N6-trimethyllysine" "N,N,N-trimethyl-5-aminovalerate" "N,N,N-trimethyl-alanylproline betaine (TMAP)" "S-(1,2-dicarboxyethyl)glutathione" "sphingomyelin (d17:1/16:0, d18:1/15:0, d16:1/17:0)*" "sphingomyelin (d18:0/18:0, d19:0/17:0)*" "sphingomyelin (d18:1/14:0, d16:1/16:0)*" "sphingomyelin (d18:1/17:0, d17:1/18:0, d19:1/16:0)" "sphingomyelin (d18:1/18:1, d18:2/18:0)" "sphingomyelin (d18:1/19:0, d19:1/18:0)*" "sphingomyelin (d18:1/20:0, d16:1/22:0)*" "sphingomyelin (d18:1/22:1, d18:2/22:0, d16:1/24:1)*" "sphingomyelin (d18:1/22:2, d18:2/22:1, d16:1/24:2)*" "sphingomyelin (d18:1/24:1, d18:2/24:0)*" "sphingomyelin (d18:2/16:0, d18:1/16:1)*" "sphingomyelin (d18:2/23:0, d18:1/23:1, d17:1/24:1)*" "sphingomyelin (d18:2/24:1, d18:1/24:2)*" "thymidine 5'-monophosphate" "trigonelline (N'-methylnicotinate)" "uridine 3'-monophosphate (3'-UMP)" "uridine 5'-diphosphate (UDP)" "uridine 5'-monophosphate (UMP)" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.