Validation Log
2025-12-15 00:42:21.039281
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003855/mwtab/json
Study ID:      ST002361
Analysis ID:   AN003855
File format:   json
Status: Contains Validation Issues
Number of Issues: 18

Number of Warnings: 11

Number of Value Errors: 13

Number of Consistency Errors: 2

Number of Format Errors: 1

Issue Log:
Error: The value, "0.3ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "30", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "20min", in ["CHROMATOGRAPHY"]["ANALYTICAL_TIME"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['min']. Ignore this when more complicated descriptions are required.
Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing.
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"1_3-DIAMINOPROPANE"
	"1_4-DIAMINOBUTANE (PUTRESCINE)"
	"2_4-DIHYDROXYPTERIDINE"
	"ACETYLHEXOSAMINE (GLU_ GALA_ MANNOSE)"
	"ADENOSINE 2^_3^-CYCLIC PHOSPHATE"
	"CYTIDINE 2^_3^-CYCLIC PHOSPHATE"
	"N_N-DIMETHYLARGININE"
	"N_N_N-TRIMETHYLLYSINE"
	"SUGAR ALCOHOL (RIBITOL_ XYLITOL_ ARABITOL)"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"1,3-DIAMINOPROPANE"
	"1,4-DIAMINOBUTANE (PUTRESCINE)"
	"2,4-DIHYDROXYPTERIDINE"
	"ACETYLHEXOSAMINE (GLU, GALA, MANNOSE)"
	"ADENOSINE 2',3'-CYCLIC PHOSPHATE"
	"CYTIDINE 2',3'-CYCLIC PHOSPHATE"
	"N,N-DIMETHYLARGININE"
	"N,N,N-TRIMETHYLLYSINE"
	"SUGAR ALCOHOL (RIBITOL, XYLITOL, ARABITOL)"
Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
6        2-ACETAMIDO-2-DEOXY-BETA-D-GLUCOSYLAMINE
10                             2-PHOSPHOGLYCERATE
16                              3-METHOXYTYROSINE
34          ACETYLHEXOSAMINE (GLU, GALA, MANNOSE)
41                       ALPHA-HYDROXYISOBUTYRATE
68                                     D4-TAURINE
97                             GLYCEROL-MYRISTATE
102                      HEXOESAMINE(GLUCOSAMINE)
105                      HOMOCYSTEINE THIOLACTONE
125                                 MEVALOLACTONE
127                           MONOMETHYLGLUTARATE
129                               N-ACETYLALANINE
145                                   OPHTHALMATE
151                                       PENTOSE
174    SUGAR ALCOHOL (RIBITOL, XYLITOL, ARABITOL)
179                      THREONINE and HOMOSERINE
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table.
Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.