Validation Log 2025-12-15 00:42:53.068047 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003866/mwtab/json Study ID: ST002371 Analysis ID: AN003866 File format: json Status: Contains Validation Issues Number of Issues: 15 Number of Warnings: 10 Number of Value Errors: 11 Number of Consistency Errors: 2 Number of Format Errors: 1 Issue Log: Error: The value in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "11^-Carboxy-alpha-chromanol" "1_3-diphosphoglycerate /2_3-diphosphoglycerate /(1_3BPG or2_3BPG)" "3_5-dihydroxy-3_4-dihydro-1_4-benzothiazine" "4-hydroxy-2-nonenal/3_4-epoxynonanal" "4-Hydroxyphenylacetate/2-Hydroxyphenylacetate/3_4-Dihydroxyphenylacetaldehyde" "5_6-dihydrothymine" "8_11_14-Eicosatrienoic acid (DGLA)" "9_10-hydroxyoctadec-12(Z)-enoate/12_13-hydroxyoctadec-9(Z)-enoate" "beta-D-Fructose 1_6-bisphosphate" "clupanodonic acid/docosa-4_7_10_13_16-pentaenoic acid" "sedoheptulose 1_7-bisphosphate" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "11'-Carboxy-alpha-chromanol" "1,3-diphosphoglycerate /2,3-diphosphoglycerate /(1,3BPG or2,3BPG)" "3,5-dihydroxy-3,4-dihydro-1,4-benzothiazine" "4-hydroxy-2-nonenal/3,4-epoxynonanal" "4-Hydroxyphenylacetate/2-Hydroxyphenylacetate/3,4-Dihydroxyphenylacetaldehyde" "5,6-dihydrothymine" "8,11,14-Eicosatrienoic acid (DGLA)" "9,10-hydroxyoctadec-12(Z)-enoate/12,13-hydroxyoctadec-9(Z)-enoate" "beta-D-Fructose 1,6-bisphosphate" "clupanodonic acid/docosa-4,7,10,13,16-pentaenoic acid" "sedoheptulose 1,7-bisphosphate" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.