Validation Log 2025-12-15 00:43:28.428716 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003879/mwtab/txt Study ID: ST002380 Analysis ID: AN003879 File format: txt Status: Contains Validation Issues Number of Issues: 17 Number of Warnings: 9 Number of Value Errors: 9 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: The value, "Not applicable", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "1_3-diaminopropane" "2_4-diaminobutyric acid" "2_5-dihydroxypyrazine NIST" "3_4-dihydroxybenzoic acid" "3_6-anhydro-D-galactose" "5^-deoxy-5^-methylthioadenosine" "uridine-5^-monophosphate" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "1,3-diaminopropane" "2,4-diaminobutyric acid" "2,5-dihydroxypyrazine NIST" "3,4-dihydroxybenzoic acid" "3,6-anhydro-D-galactose" "5'-deoxy-5'-methylthioadenosine" "uridine-5'-monophosphate" Warning: The "moverz_quant" column at position 9 in the METABOLITES table, matches a standard column name, "moverz_quant", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 85:271.0 86:7066.0 87:1248.0 88:332.0 95:184.0... 1 85:705.0 86:51.0 89:1086.0 90:140.0 91:307.0 9... 2 85:574.0 86:56.0 87:709.0 88:73.0 89:747.0 90:... 3 85:11049.0 86:1066.0 87:1727.0 88:2503.0 89:43... 4 85:2387.0 86:245.0 88:342.0 89:880.0 90:108.0 ... 5 86:4905.0 87:90.0 88:301.0 91:62.0 94:20.0 98:... 6 85:168.0 86:172.0 87:115.0 93:14.0 97:710.0 98... 7 85:2349.0 86:7340.0 87:2626.0 88:1175.0 89:967... 8 86:46.0 88:28.0 89:367.0 90:3.0 95:6.0 98:2.0 ... 9 85:3678.0 86:419.0 87:1070.0 88:693.0 89:3868.... 10 86:245.0 87:1207.0 89:112.0 95:545.0 97:102.0 ... 11 85:987.0 86:115.0 99:30.0 101:119.0 103:121.0 ... 12 85:2528.0 86:217.0 89:1183.0 91:1239.0 92:10.0... 13 85:783.0 86:12.0 89:96.0 95:343.0 99:185.0 101... 14 85:164.0 86:435.0 91:1392.0 92:56.0 93:44.0 94... 15 85:1118.0 86:3469.0 89:26799.0 90:2045.0 91:99... 16 85:2398.0 86:3456.0 87:2125.0 88:2450.0 91:675... 17 85:468.0 86:410.0 90:4.0 99:95.0 100:150.0 101... 18 85:232.0 87:211.0 88:58.0 89:445.0 91:823.0 92... 19 89:291.0 93:40.0 95:377.0 96:195.0 98:245.0 12... 20 89:294.0 91:134.0 93:177.0 95:84.0 99:23.0 101... 21 85:576.0 87:354.0 88:431.0 89:1639.0 90:679.0 ... 22 85:192.0 86:135.0 87:64.0 88:217.0 89:4369.0 9... 23 87:158.0 88:65.0 89:1516.0 90:603.0 91:5819.0 ... 24 85:450.0 87:771.0 88:5166.0 89:671.0 90:145.0 ... 25 85:352.0 87:92.0 88:53.0 91:242.0 93:193.0 95:... 26 88:403.0 89:1968.0 90:785.0 91:466.0 92:69.0 9... 27 85:317.0 87:1774.0 88:555.0 89:599.0 90:145.0 ... 28 90:151.0 91:4047.0 92:276.0 93:36.0 101:283.0 ... 29 85:3431.0 86:914.0 87:3880.0 88:915.0 89:5026.... 30 85:2931.0 86:36127.0 88:1868.0 89:824.0 90:367... 31 85:234.0 86:343.0 87:138.0 88:10.0 89:445.0 90... 32 85:1473.0 86:1030.0 88:1141.0 90:78.0 97:88.0 ... 33 85:74.0 89:848.0 90:484.0 91:340.0 93:30.0 95:... 34 85:189.0 86:2159.0 87:251.0 97:75.0 98:42.0 99... 35 85:99.0 86:132.0 94:26.0 96:62.0 99:123.0 100:... 36 92:69.0 93:77.0 94:32.0 95:395.0 96:128.0 97:1... 37 88:4.0 89:7.0 103:11.0 106:38.0 108:4.0 111:28... 38 85:700.0 86:543.0 87:861.0 88:477.0 89:2187.0 ... 39 85:1382.0 86:894.0 87:839.0 88:367.0 89:5317.0... 40 85:823.0 86:194.0 87:662.0 88:337.0 89:711.0 9... 41 85:54.0 86:321.0 89:1488.0 90:133.0 93:347.0 9... 42 85:353.0 86:112.0 89:208.0 95:41.0 98:54.0 99:... 43 89:44.0 90:17.0 95:28.0 99:134.0 100:1.0 101:1... 44 85:2037.0 86:2852.0 87:703.0 88:641.0 89:904.0... 45 100:20.0 102:35.0 103:7.0 105:393.0 107:20.0 1... 46 86:1375.0 87:176.0 88:157.0 89:45.0 97:43.0 98... 47 85:208.0 87:154.0 89:4657.0 90:84.0 91:201.0 9... 48 86:196.0 89:2673.0 90:148.0 94:55.0 96:34.0 98... 49 85:167.0 89:444.0 90:10.0 92:58.0 93:400.0 94:... 50 87:91.0 96:51.0 97:57.0 98:86.0 99:100.0 100:3... 51 89:63.0 90:3.0 96:62.0 98:113.0 116:141.0 117:... 52 85:228.0 86:3117.0 87:240.0 90:32.0 93:32.0 95... 53 85:70.0 89:982.0 90:77.0 91:136.0 95:34.0 96:8... 54 85:37.0 101:553.0 102:50.0 103:684.0 106:24.0 ... 55 85:3484.0 86:551.0 87:1694.0 88:496.0 89:823.0... 56 85:2766.0 86:101.0 87:57.0 89:458.0 91:5648.0 ... 57 85:464.0 87:35.0 89:33.0 96:1005.0 97:67.0 98:... 58 85:20.0 86:58.0 88:236.0 89:101.0 99:89.0 100:... 59 86:58.0 95:73.0 100:128.0 115:203.0 116:59.0 1... 60 85:1295.0 86:158.0 88:1.0 89:242.0 91:67.0 93:... 61 85:1091.0 86:111.0 98:257.0 99:18.0 100:60.0 1... 62 85:2393.0 86:978.0 87:2429.0 88:1804.0 89:1356... 63 85:138.0 86:318.0 89:143.0 90:82.0 91:114.0 92... 64 85:36.0 86:264.0 87:119.0 89:71.0 90:3.0 96:4.... 65 85:144.0 86:125.0 87:68.0 95:74.0 97:27.0 99:1... 66 85:305.0 86:945.0 88:631.0 89:66.0 91:93.0 92:... 67 100:421.0 114:218.0 116:303.0 128:133.0 129:31... 68 85:302.0 86:95.0 87:104.0 88:78.0 89:125.0 91:... 69 89:188.0 90:31.0 91:2375.0 92:171.0 93:1666.0 ... 70 85:102.0 86:274.0 87:196.0 88:324.0 89:5685.0 ... 71 85:264.0 86:22410.0 87:2464.0 88:1167.0 89:864... 72 85:35.0 86:52.0 87:36.0 88:252.0 89:926.0 90:1... 73 85:1065.0 86:372.0 87:1570.0 88:1347.0 89:1188... 74 85:175.0 86:55.0 87:366.0 88:157.0 89:2236.0 9... 75 85:191.0 89:328.0 91:5.0 98:6.0 100:250.0 101:... 76 85:387.0 86:38.0 87:9.0 88:13.0 89:36.0 91:8.0... 77 85:918.0 86:238.0 87:865.0 88:630.0 89:3376.0 ... 78 86:108.0 88:33.0 98:14.0 103:1972.0 104:148.0 ... 79 87:39.0 89:155.0 99:15.0 100:306.0 101:268.0 1... 80 87:376.0 89:418.0 91:200.0 93:213.0 94:7.0 95:... 81 85:8086.0 86:11427.0 87:11651.0 88:7928.0 89:1... 82 85:385.0 86:98.0 87:248.0 88:286.0 89:468.0 90... 83 85:5245.0 86:2200.0 88:676.0 89:23781.0 90:237... 84 85:1143.0 86:983.0 87:725.0 88:453.0 89:313.0 ... 85 86:1008.0 87:256.0 88:222.0 90:245.0 94:189.0 ... 86 85:4857.0 86:408.0 87:632.0 88:1429.0 89:752.0... 87 87:199.0 89:698.0 90:111.0 93:56.0 98:33.0 99:... 88 85:750.0 87:846.0 88:468.0 89:1193.0 90:82.0 9... 89 85:2882.0 86:87494.0 87:10917.0 88:4018.0 89:8... 90 86:321.0 87:877.0 88:2215.0 89:1177.0 90:166.0... 91 85:485.0 86:288.0 87:42.0 89:317.0 95:86.0 98:... 92 86:84.0 89:126.0 93:146.0 95:297.0 97:364.0 98... 93 85:8744.0 86:578.0 87:1216.0 88:1214.0 89:4931... 94 85:688.0 86:1894.0 87:3450.0 88:2514.0 89:1013... 95 87:151.0 88:97.0 89:407.0 90:38.0 91:5899.0 92... 96 106:2.0 109:94.0 110:4.0 116:147.0 117:3332.0 ... 97 85:1549.0 86:3001.0 87:645.0 88:285.0 89:271.0... 98 88:64.0 89:228.0 90:112.0 93:421.0 94:37.0 95:... 99 85:8684.0 86:6573.0 87:72227.0 88:111565.0 89:... 100 85:168.0 86:141.0 87:101.0 89:291.0 93:60.0 95... 101 85:2866.0 86:48433.0 87:4176.0 89:655.0 91:104... 102 85:2380.0 86:760.0 89:854.0 91:551.0 92:193.0 ... 103 85:2755.0 86:29130.0 87:3786.0 88:12077.0 89:1... 104 85:294.0 86:375.0 87:61.0 88:60.0 92:7.0 93:18... 105 85:66.0 87:316.0 88:106.0 89:148.0 90:42.0 95:... 106 85:280.0 86:2716.0 87:721.0 88:266.0 89:1849.0... 107 85:142.0 89:1499.0 90:197.0 97:127.0 100:159.0... 108 86:209.0 87:157.0 88:89.0 92:28.0 96:49.0 98:1... 109 85:565.0 86:54.0 87:44.0 89:121.0 91:64.0 93:9... 110 85:113.0 86:491.0 87:31.0 88:19.0 89:298.0 90:... 111 85:1672.0 86:922.0 87:259.0 88:617.0 89:2301.0... 112 85:448.0 86:230.0 88:655.0 89:9641.0 90:778.0 ... 113 85:246.0 86:220.0 87:8180.0 88:498.0 89:1937.0... 114 85:10584.0 86:6609.0 87:242272.0 88:32118.0 89... 115 85:29.0 86:114.0 97:39.0 100:114.0 116:34.0 14... 116 86:209.0 89:162.0 90:198.0 92:127.0 93:263.0 9... 117 85:402.0 86:47.0 87:81.0 90:191.0 91:76.0 94:4... 118 85:3812.0 86:224.0 87:853.0 88:401.0 89:7207.0... 119 85:2268.0 86:703.0 87:608.0 88:472.0 89:1302.0... 120 86:646.0 87:249.0 88:784.0 90:47.0 91:288.0 95... 121 86:2512.0 87:360.0 90:9.0 94:31.0 97:64.0 98:2... 122 85:642.0 86:564.0 88:852.0 89:2725.0 90:394.0 ... 123 85:3305.0 86:3646.0 88:224.0 89:349.0 92:90.0 ... 124 85:279.0 86:116.0 87:62.0 88:11.0 89:77.0 91:3... 125 85:405.0 86:127.0 87:100.0 88:106.0 89:342.0 9... 126 86:142.0 87:115.0 88:61.0 89:123.0 91:147.0 93... 127 85:95.0 86:236.0 88:109.0 89:242.0 90:68.0 94:... 128 85:1079.0 86:936.0 87:668.0 88:311.0 89:1235.0... 129 85:15.0 86:1825.0 87:567.0 88:240.0 89:6578.0 ... 130 85:116.0 86:960.0 87:386.0 88:130.0 89:524.0 9... 131 86:5896.0 87:600.0 88:548.0 90:188.0 91:2636.0... 132 85:21470.0 86:739.0 87:25996.0 88:12812.0 89:3... 133 85:722.0 87:475.0 88:135.0 89:540.0 91:470.0 9... 134 85:4482.0 86:63617.0 87:12014.0 88:3644.0 89:3... 135 85:2215.0 86:1344.0 87:2899.0 88:519.0 89:1313... 136 85:280.0 86:163.0 89:149.0 91:71.0 93:128.0 95... 137 85:289.0 86:126.0 88:244.0 89:421.0 93:8.0 95:... 138 87:397.0 88:730.0 89:874.0 91:987.0 93:161.0 9... 139 85:401.0 86:767.0 87:6.0 88:84.0 93:6.0 95:185... 140 85:9395.0 86:1247.0 87:3795.0 88:1582.0 89:101... 141 85:187.0 88:116.0 99:41.0 100:66.0 101:16.0 10... 142 85:313.0 86:2133.0 87:100.0 89:10.0 91:1.0 92:... 143 85:1055.0 86:1908.0 87:916.0 88:634.0 95:165.0... 144 86:237.0 88:11.0 89:59.0 98:89.0 99:253.0 100:... 145 85:59.0 86:424.0 88:3996.0 89:1099.0 90:521.0 ... 146 85:2409.0 86:555.0 87:2017.0 88:587.0 89:1610.... 147 86:256.0 88:77.0 89:2341.0 90:204.0 100:1244.0... 148 85:1631.0 86:589.0 87:1362.0 88:598.0 89:8723.... 149 85:312.0 86:310.0 87:77.0 88:272.0 89:2115.0 9... 150 85:1107.0 86:1626.0 87:1747.0 88:1150.0 89:334... 151 85:536.0 86:1604.0 87:945.0 88:1874.0 89:1384.... 152 85:588.0 86:704.0 88:1768.0 89:8743.0 90:652.0... 153 85:4191.0 86:1569.0 87:1271.0 88:840.0 89:3341... 154 85:2046.0 86:2010.0 87:22.0 88:95.0 89:5734.0 ... 155 85:303.0 87:764.0 88:359.0 89:340.0 91:55.0 92... 156 85:23797.0 86:3499.0 87:23892.0 88:12950.0 89:... 157 85:32.0 86:79.0 89:154.0 91:278.0 95:11.0 98:4... 158 85:235.0 87:47.0 88:246.0 89:1335.0 90:112.0 9... 159 85:786.0 86:260.0 87:1086.0 88:349.0 89:901.0 ... 160 85:123.0 86:39.0 87:235.0 88:92.0 89:794.0 91:... 161 86:78.0 87:500.0 88:136.0 89:1131.0 90:139.0 9... 162 85:3292.0 86:8314.0 87:9239.0 88:2146.0 89:138... 163 85:2128.0 86:315.0 87:993.0 88:296.0 89:761.0 ... 164 87:88.0 97:77.0 99:95.0 103:187.0 104:233.0 11... 165 85:666.0 86:403.0 87:19.0 88:154.0 89:59.0 93:... 166 90:27.0 92:61.0 94:13.0 95:202.0 97:63.0 98:7.... 167 85:7.0 86:92.0 88:26.0 91:52.0 94:33.0 95:97.0... 168 85:94.0 98:34.0 99:34.0 103:3530.0 104:205.0 1... 169 85:393.0 87:223.0 89:142.0 94:67.0 95:79.0 96:... 170 86:650.0 87:425.0 89:261.0 100:3562.0 101:1584... 171 85:101.0 86:1059.0 87:458.0 89:659.0 90:823.0 ... 172 85:805.0 86:240.0 87:781.0 88:1255.0 89:4759.0... 173 85:23877.0 86:6864.0 87:3486.0 88:1560.0 89:15... 174 88:414.0 89:400.0 90:639.0 91:187.0 92:44.0 94... 175 85:181.0 86:102.0 89:98.0 91:27.0 92:64.0 95:1... 176 85:2124.0 86:7630.0 87:1944.0 88:1239.0 89:198... 177 85:131.0 89:849.0 90:76.0 91:619.0 92:175.0 93... 178 85:2517.0 86:3710.0 87:2079.0 88:382.0 89:398.... 179 86:6.0 88:17.0 89:5.0 101:53.0 103:590.0 104:3... 180 85:303.0 86:445.0 87:365.0 88:302.0 89:3272.0 ... 181 85:1861.0 86:702.0 87:1148.0 88:324.0 89:10095... 182 85:177.0 89:568.0 91:6448.0 92:1105.0 93:4713.... Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "other_id" column at position 5 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.