Validation Log
2025-12-15 00:49:02.341918
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003982/mwtab/txt
Study ID:      ST002444
Analysis ID:   AN003982
File format:   txt
Status: Contains Validation Issues
Number of Issues: 15

Number of Warnings: 11

Number of Value Errors: 12

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: The value, "Male and female", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required.
Error: The value, "0.5 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"1_2_3_4_7_8-hexachlorobenzofuran"
	"1_3-Nonanediol acetate"
	"1-(5_6-Dihydro-7H-[1_3]benzodioxolo[6_5_4-de]benzo[g]quinolin-7-yl)ethanone"
	"(1R_2S)-1-(7_8-Dihydro-6-pteridinyl)-1_2-propanediol"
	"(1R_5S_6R_7R_9S_11S_12S_13S_14S)-3-Amino-14-methyl-8_10-dioxa-2_4-diazatetracyclo[7.3.1.1~7_11~.0~1_6~]tetradec-2-ene-5_9_12_13_14-pentol"
	"2_2^-Iminodipropanoate"
	"2_3_4_5-Tetrahydroxy-8-(3_5_7-trihydroxy-3_4-dihydro-2H-chromen-2-yl)-6H-benzo[7]annulen-6-one"
	"(+)-2_7-Dideoxypancratistatin"
	"2^-Deoxyinosine"
	"2-Dimethylamino-5_6-dimethyl-4-hydroxypyrimidine"
	"2-(Hydroxymethyl)-1-methyl-3_4_5-piperidinetriol"
	"3-(2-hydroxyethyl)-1_2_3_4-tetrahydrothieno[3_2-d]pyrimidine-2_4-dione"
	"3_4-DHPEA-EA"
	"3_4-Dimethyl-5-pentyl-2-furanpropanoic acid"
	"3_8-Dimethyl-7-decen-1-yl dihydrogen phosphate"
	"5^-dehydroadenosine"
	"5^-S-Ethyl-5^-thioadenosine"
	"7_8-dihydro-D-neopterin 2^_3^-cyclic phosphate"
	"8-{[2-Hydroxy-2-(4-hydroxyphenyl)ethyl](methyl)amino}-1_3_7-trimethyl-3_7-dihydro-1H-purine-2_6-dione"
	"C1^-C9-Glycosylated UWM6"
	"L-Serine_ anhydride with 5′-adenylic acid (1:1)"
	"Methyl 2-{[(1H-benzimidazol-2-ylsulfanyl)acetyl]amino}-1_3-benzothiazole-6-carboxylate"
	"N~2~_N~6~-Bis(2_3-dihydroxybenzoyl)-L-lysine"
	"N_N-Dihydroxy-L-valine"
	"Uridine 5^-diphosphogalactose"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"1,2,3,4,7,8-hexachlorobenzofuran"
	"1,3-Nonanediol acetate"
	"1-(5,6-Dihydro-7H-[1,3]benzodioxolo[6,5,4-de]benzo[g]quinolin-7-yl)ethanone"
	"(1R,2S)-1-(7,8-Dihydro-6-pteridinyl)-1,2-propanediol"
	"(1R,5S,6R,7R,9S,11S,12S,13S,14S)-3-Amino-14-methyl-8,10-dioxa-2,4-diazatetracyclo[7.3.1.1~7,11~.0~1,6~]tetradec-2-ene-5,9,12,13,14-pentol"
	"2_2'-Iminodipropanoate"
	"2,3,4,5-Tetrahydroxy-8-(3,5,7-trihydroxy-3,4-dihydro-2H-chromen-2-yl)-6H-benzo[7]annulen-6-one"
	"(+)-2,7-Dideoxypancratistatin"
	"2'-Deoxyinosine"
	"2-Dimethylamino-5,6-dimethyl-4-hydroxypyrimidine"
	"2-(Hydroxymethyl)-1-methyl-3,4,5-piperidinetriol"
	"3-(2-hydroxyethyl)-1,2,3,4-tetrahydrothieno[3,2-d]pyrimidine-2,4-dione"
	"3,4-DHPEA-EA"
	"3,4-Dimethyl-5-pentyl-2-furanpropanoic acid"
	"3,8-Dimethyl-7-decen-1-yl dihydrogen phosphate"
	"5'-dehydroadenosine"
	"5'-S-Ethyl-5'-thioadenosine"
	"7,8-dihydro-D-neopterin 2',3'-cyclic phosphate"
	"8-{[2-Hydroxy-2-(4-hydroxyphenyl)ethyl](methyl)amino}-1,3,7-trimethyl-3,7-dihydro-1H-purine-2,6-dione"
	"C1'-C9-Glycosylated UWM6"
	"L-Serine, anhydride with 5′-adenylic acid (1:1)"
	"Methyl 2-{[(1H-benzimidazol-2-ylsulfanyl)acetyl]amino}-1,3-benzothiazole-6-carboxylate"
	"N~2~,N~6~-Bis(2,3-dihydroxybenzoyl)-L-lysine"
	"N,N-Dihydroxy-L-valine"
	"Uridine 5'-diphosphogalactose"
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri" column at position 7 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.
Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.