Validation Log
2025-12-15 00:52:19.626508
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004077/mwtab/txt
Study ID:      ST002476
Analysis ID:   AN004077
File format:   txt
Status: Contains Validation Issues
Number of Issues: 18

Number of Warnings: 10

Number of Value Errors: 15

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: The value, "none", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "none", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected for the subsection, "SOLVENT_A", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "SOLVENT_B", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"1_3-Diaminopropane"
	"2_3-Diaminopropionate"
	"2_4-Diaminobutyrate"
	"2_4-Dimethylaniline"
	"2^-Deoxycytidine"
	"2^-Deoxyguanosine"
	"2^-Deoxyinosine"
	"3_3^_5-Triiodothyronine"
	"3_5-Diiodo-tyrosine"
	"3-Aminopropane-1_2-diol"
	"5_6-Dimethylbenzimidazole"
	"5^-Deoxyadenosine"
	"5-Methyl-2^-deoxycytidine"
	"7_8-Dihydrobiopterin"
	"7_8-Dihydroneopterin"
	"N1_N12-Diacetylspermine"
	"N1_N8-Diacetylspermidine"
	"N6-Methyl-2^-deoxyadenosine"
	"N6_N6_N6-Trimethyllysine"
	"N-alpha_N-alpha-Dimethylhistidine"
	"N_N-Dimethylglycine"
	"Putrescine(1_4-Butanediamine)"
	"Pyridoxamine 5^-phosphate"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"1,3-Diaminopropane"
	"2,3-Diaminopropionate"
	"2,4-Diaminobutyrate"
	"2,4-Dimethylaniline"
	"2'-Deoxycytidine"
	"2'-Deoxyguanosine"
	"2'-Deoxyinosine"
	"3,3',5-Triiodothyronine"
	"3,5-Diiodo-tyrosine"
	"3-Aminopropane-1,2-diol"
	"5,6-Dimethylbenzimidazole"
	"5'-Deoxyadenosine"
	"5-Methyl-2'-deoxycytidine"
	"7,8-Dihydrobiopterin"
	"7,8-Dihydroneopterin"
	"N1,N12-Diacetylspermine"
	"N1,N8-Diacetylspermidine"
	"N6-Methyl-2'-deoxyadenosine"
	"N6,N6,N6-Trimethyllysine"
	"N-alpha,N-alpha-Dimethylhistidine"
	"N,N-Dimethylglycine"
	"Putrescine(1,4-Butanediamine)"
	"Pyridoxamine 5'-phosphate"
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri" column at position 7 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.