Validation Log 2025-12-15 00:53:40.013828 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004081/mwtab/json Study ID: ST002492 Analysis ID: AN004081 File format: json Status: Contains Validation Issues Number of Issues: 14 Number of Warnings: 10 Number of Value Errors: 10 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "65C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "2^-deoxyadenosine" "3^-CMP" "5^- GMP" "glutamate_ gamma-methyl ester" "glutathione_ oxidized (GSSG)" "glutathione_ reduced (GSH)" "N2_N2-dimethylguanosine" "N6_N6-dimethyllysine" "N6_N6_N6-trimethyllysine" "N_N-dimethylalanine" "N_N_N-trimethyl-alanylproline betaine (TMAP)" "trigonelline (N^-methylnicotinate)" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "2'-deoxyadenosine" "3'-CMP" "5'- GMP" "glutamate, gamma-methyl ester" "glutathione, oxidized (GSSG)" "glutathione, reduced (GSH)" "N2,N2-dimethylguanosine" "N6,N6-dimethyllysine" "N6,N6,N6-trimethyllysine" "N,N-dimethylalanine" "N,N,N-trimethyl-alanylproline betaine (TMAP)" "trigonelline (N'-methylnicotinate)" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.