Validation Log 2025-12-15 00:53:58.642490 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004087/mwtab/json Study ID: ST002493 Analysis ID: AN004087 File format: json Status: Contains Validation Issues Number of Issues: 16 Number of Warnings: 12 Number of Value Errors: 12 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "40C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "1_3-Cyclohexanedicarboxylic acid" "1_3 Cyclohexanedione" "1_5-Anhydro-D-sorbitol" "1_6-Anhydro-.beta.-D-glucose" "1_7-Dimethyluric acid" "1-Pentanone_ 1-(4-hydroxy-3-methoxyphenyl)-2-(1-pyrrolidinyl)-" "2_4-Dichlorobenzoic acid" "2_6-Dihydroxybenzoic acid" "2-Furanpropanoic acid_ 3-carboxy-4-methyl-5-propyl-" "2^-O-Methylguanosine" "2^-O-Methyluridine" "(3_4-Dihydroxyphenyl)ethanol" "5_3^-Dihydroxy-6_7_4^-trimethoxyflavone" "5.alpha.-Pregnan-3.alpha._17-diol-20-one 3-sulfate" "6-[5_7-dihydroxy-2-(4-hydroxy-3-methoxyphenyl)-4-oxochromen-3-yl]oxy-3_4_5-trihydroxyoxane-2-carboxylic acid" "6_7-Dihydroxycoumarin" "9-Hydroperoxy-10E_12Z_15Z-octadecatrienoic acid" "9S-Hydroperoxy-10E_12Z-octadecadienoic acid" "Acetic acid_ 2_2^-[oxybis(2_1-ethanediyloxy)]bis-" "Adenosine 5^-monophosphate" "Cyanidin-3-O-(2^^-O-beta-xylopyranosyl-beta-glucopyranoside)" "Cytidine-5^-monophosphate" "Dihydro-4_4-dimethyl-2_3-furandione" "Guanosine-3^_5^-cyclic monophosphate" "Guanosine-5^-monophosphate" "L-Gulono-1_4-lactone" "N2_N2-Dimethylguanosine" "N_N-Dimethylarginine" "O_O-Dimethyl dithiophosphate" "trans-3_5-Dimethoxy-4-hydroxycinnamaldehyde" "Uridine 5^-monophosphate" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "1,3-Cyclohexanedicarboxylic acid" "1,3 Cyclohexanedione" "1,5-Anhydro-D-sorbitol" "1,6-Anhydro-.beta.-D-glucose" "1,7-Dimethyluric acid" "1-Pentanone, 1-(4-hydroxy-3-methoxyphenyl)-2-(1-pyrrolidinyl)-" "2,4-Dichlorobenzoic acid" "2,6-Dihydroxybenzoic acid" "2-Furanpropanoic acid, 3-carboxy-4-methyl-5-propyl-" "2'-O-Methylguanosine" "2'-O-Methyluridine" "(3,4-Dihydroxyphenyl)ethanol" "5,3'-Dihydroxy-6,7,4'-trimethoxyflavone" "5.alpha.-Pregnan-3.alpha.,17-diol-20-one 3-sulfate" "6-[5,7-dihydroxy-2-(4-hydroxy-3-methoxyphenyl)-4-oxochromen-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid" "6,7-Dihydroxycoumarin" "9-Hydroperoxy-10E,12Z,15Z-octadecatrienoic acid" "9S-Hydroperoxy-10E,12Z-octadecadienoic acid" "Acetic acid, 2,2'-[oxybis(2,1-ethanediyloxy)]bis-" "Adenosine 5'-monophosphate" "Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)" "Cytidine-5'-monophosphate" "Dihydro-4,4-dimethyl-2,3-furandione" "Guanosine-3',5'-cyclic monophosphate" "Guanosine-5'-monophosphate" "L-Gulono-1,4-lactone" "N2,N2-Dimethylguanosine" "N,N-Dimethylarginine" "O,O-Dimethyl dithiophosphate" "trans-3,5-Dimethoxy-4-hydroxycinnamaldehyde" "Uridine 5'-monophosphate" Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 10 ESI (-) Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.