Validation Log
2025-12-15 00:53:57.173188
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004087/mwtab/txt
Study ID:      ST002493
Analysis ID:   AN004087
File format:   txt
Status: Contains Validation Issues
Number of Issues: 14

Number of Warnings: 11

Number of Value Errors: 10

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: The value, "40C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"1_3-Cyclohexanedicarboxylic acid"
	"1_3 Cyclohexanedione"
	"1_5-Anhydro-D-sorbitol"
	"1_6-Anhydro-.beta.-D-glucose"
	"1_7-Dimethyluric acid"
	"1-Pentanone_ 1-(4-hydroxy-3-methoxyphenyl)-2-(1-pyrrolidinyl)-"
	"2_4-Dichlorobenzoic acid"
	"2_6-Dihydroxybenzoic acid"
	"2-Furanpropanoic acid_ 3-carboxy-4-methyl-5-propyl-"
	"2^-O-Methylguanosine"
	"2^-O-Methyluridine"
	"(3_4-Dihydroxyphenyl)ethanol"
	"5_3^-Dihydroxy-6_7_4^-trimethoxyflavone"
	"5.alpha.-Pregnan-3.alpha._17-diol-20-one 3-sulfate"
	"6-[5_7-dihydroxy-2-(4-hydroxy-3-methoxyphenyl)-4-oxochromen-3-yl]oxy-3_4_5-trihydroxyoxane-2-carboxylic acid"
	"6_7-Dihydroxycoumarin"
	"9-Hydroperoxy-10E_12Z_15Z-octadecatrienoic acid"
	"9S-Hydroperoxy-10E_12Z-octadecadienoic acid"
	"Acetic acid_ 2_2^-[oxybis(2_1-ethanediyloxy)]bis-"
	"Adenosine 5^-monophosphate"
	"Cyanidin-3-O-(2^^-O-beta-xylopyranosyl-beta-glucopyranoside)"
	"Cytidine-5^-monophosphate"
	"Dihydro-4_4-dimethyl-2_3-furandione"
	"Guanosine-3^_5^-cyclic monophosphate"
	"Guanosine-5^-monophosphate"
	"L-Gulono-1_4-lactone"
	"N2_N2-Dimethylguanosine"
	"N_N-Dimethylarginine"
	"O_O-Dimethyl dithiophosphate"
	"trans-3_5-Dimethoxy-4-hydroxycinnamaldehyde"
	"Uridine 5^-monophosphate"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"1,3-Cyclohexanedicarboxylic acid"
	"1,3 Cyclohexanedione"
	"1,5-Anhydro-D-sorbitol"
	"1,6-Anhydro-.beta.-D-glucose"
	"1,7-Dimethyluric acid"
	"1-Pentanone, 1-(4-hydroxy-3-methoxyphenyl)-2-(1-pyrrolidinyl)-"
	"2,4-Dichlorobenzoic acid"
	"2,6-Dihydroxybenzoic acid"
	"2-Furanpropanoic acid, 3-carboxy-4-methyl-5-propyl-"
	"2'-O-Methylguanosine"
	"2'-O-Methyluridine"
	"(3,4-Dihydroxyphenyl)ethanol"
	"5,3'-Dihydroxy-6,7,4'-trimethoxyflavone"
	"5.alpha.-Pregnan-3.alpha.,17-diol-20-one 3-sulfate"
	"6-[5,7-dihydroxy-2-(4-hydroxy-3-methoxyphenyl)-4-oxochromen-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid"
	"6,7-Dihydroxycoumarin"
	"9-Hydroperoxy-10E,12Z,15Z-octadecatrienoic acid"
	"9S-Hydroperoxy-10E,12Z-octadecadienoic acid"
	"Acetic acid, 2,2'-[oxybis(2,1-ethanediyloxy)]bis-"
	"Adenosine 5'-monophosphate"
	"Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)"
	"Cytidine-5'-monophosphate"
	"Dihydro-4,4-dimethyl-2,3-furandione"
	"Guanosine-3',5'-cyclic monophosphate"
	"Guanosine-5'-monophosphate"
	"L-Gulono-1,4-lactone"
	"N2,N2-Dimethylguanosine"
	"N,N-Dimethylarginine"
	"O,O-Dimethyl dithiophosphate"
	"trans-3,5-Dimethoxy-4-hydroxycinnamaldehyde"
	"Uridine 5'-monophosphate"
Warning: The "moverz_quant" column at position 9 in the METABOLITES table, matches a standard column name, "moverz_quant", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
10    ESI (-)
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.