Validation Log
2025-12-15 00:57:13.122874
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004138/mwtab/json
Study ID:      ST002513
Analysis ID:   AN004138
File format:   json
Status: Contains Validation Issues
Number of Issues: 37

Number of Warnings: 32

Number of Value Errors: 34

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: The value, "400 μL per minute", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "40", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][10] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][11] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][12] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][13] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][14] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][15] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][16] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][17] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][18] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][19] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][20] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"1_2-Diarachidonoyl-sn-glycero-3-phosphocholine"
	"1_2-Dilinoleoyl-sn-glycero-3-phosphocholine"
	"15-Hydroperoxy-5Z_8Z_11Z_13E-eicosatetraenoic acid"
	"1-Hexadecyl-2-(5Z_8Z_11Z_14Z-eicosatetraenoyl)-sn-glycero-3-phosphocholine"
	"1-Hexadecyl-2-(8Z_11Z_14Z-eicosatrienoyl)-sn-glycero-3-phosphocholine"
	"1-O-Hexadecyl-2-O-(4Z_7Z_10Z_13Z_16Z_19Z-docosahexaenoyl)-sn-glyceryl-3-phosphorylcholine"
	"1-O-Hexadecyl-2-O-(5Z_8Z_11Z_14Z_17Z-eicosapentaenoyl)-sn-glyceryl-3-phosphorylcholine"
	"5_8_11-Eicosatriynoic acid"
	"5-Hydroxy-6E_8Z_11Z_14Z-eicosatetraenoic acid_ 1_5-lactone"
	"5^-Methylthioadenosine"
	"7_8-Dihydrobiopterin"
	"Arginine_ methyl ester"
	"CAR 4:0;OH_Me"
	"Leucine_ methyl ester"
	"N(6)_N(6)-Dimethyl-lysine"
	"N_N-Diethyl-2-aminoethanol"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"1,2-Diarachidonoyl-sn-glycero-3-phosphocholine"
	"1,2-Dilinoleoyl-sn-glycero-3-phosphocholine"
	"15-Hydroperoxy-5Z,8Z,11Z,13E-eicosatetraenoic acid"
	"1-Hexadecyl-2-(5Z,8Z,11Z,14Z-eicosatetraenoyl)-sn-glycero-3-phosphocholine"
	"1-Hexadecyl-2-(8Z,11Z,14Z-eicosatrienoyl)-sn-glycero-3-phosphocholine"
	"1-O-Hexadecyl-2-O-(4Z,7Z,10Z,13Z,16Z,19Z-docosahexaenoyl)-sn-glyceryl-3-phosphorylcholine"
	"1-O-Hexadecyl-2-O-(5Z,8Z,11Z,14Z,17Z-eicosapentaenoyl)-sn-glyceryl-3-phosphorylcholine"
	"5,8,11-Eicosatriynoic acid"
	"5-Hydroxy-6E,8Z,11Z,14Z-eicosatetraenoic acid, 1,5-lactone"
	"5'-Methylthioadenosine"
	"7,8-Dihydrobiopterin"
	"Arginine, methyl ester"
	"CAR 4:0;OH,Me"
	"Leucine, methyl ester"
	"N(6),N(6)-Dimethyl-lysine"
	"N,N-Diethyl-2-aminoethanol"
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table.
Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.