Validation Log 2025-12-15 00:57:41.574138 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004145/mwtab/txt Study ID: ST002517 Analysis ID: AN004145 File format: txt Status: Contains Validation Issues Number of Issues: 139 Number of Warnings: 135 Number of Value Errors: 136 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "400 μL per minute", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "40", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #41 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #42 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #43 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #44 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #45 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #46 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #47 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #48 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #49 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #50 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #51 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #52 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #53 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #54 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #55 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #56 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #57 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #58 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #59 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #60 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #61 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #62 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #63 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #64 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #65 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #66 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #67 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #68 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #69 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #70 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #71 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #72 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #73 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #74 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #75 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #76 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #77 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #78 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #79 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #80 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #81 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #82 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #83 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #84 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #85 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #86 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #87 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #88 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #89 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #90 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #91 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #92 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #93 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #94 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #95 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #96 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #97 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #98 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #99 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #100 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #101 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #102 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #103 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #104 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #105 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #106 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #107 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #108 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #109 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #110 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #111 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #112 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #113 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #114 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #115 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #116 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #117 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #118 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #119 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #120 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #121 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #122 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #123 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "Pos_1-Methyl-1_3-dihydro-2H-benzimidazole-2-thione_164.04082_165.048_1.195_ExRate0" "Pos_1-Methyl-1_3-dihydro-2H-benzimidazole-2-thione_164.04082_165.048_1.195_ExRate1" "Pos_1-Methyl-1_3-dihydro-2H-benzimidazole-2-thione_164.04082_165.048_1.195_ExRate2" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1_2-a]pyrazine-1_4-dione_210.13683_211.144_6.261_ExRate0" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1_2-a]pyrazine-1_4-dione_210.13683_211.144_6.261_ExRate10" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1_2-a]pyrazine-1_4-dione_210.13683_211.144_6.261_ExRate2" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1_2-a]pyrazine-1_4-dione_210.13683_211.144_6.261_ExRate3" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1_2-a]pyrazine-1_4-dione_210.13683_211.144_6.261_ExRate4" "Pos_N3_N4-Dimethyl-L-arginine_202.14298_203.1501_8.98_ExRate0" "Pos_N3_N4-Dimethyl-L-arginine_202.14298_203.1501_8.98_ExRate2" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "Pos_1-Methyl-1,3-dihydro-2H-benzimidazole-2-thione_164.04082_165.048_1.195_ExRate0" "Pos_1-Methyl-1,3-dihydro-2H-benzimidazole-2-thione_164.04082_165.048_1.195_ExRate1" "Pos_1-Methyl-1,3-dihydro-2H-benzimidazole-2-thione_164.04082_165.048_1.195_ExRate2" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1,2-a]pyrazine-1,4-dione_210.13683_211.144_6.261_ExRate0" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1,2-a]pyrazine-1,4-dione_210.13683_211.144_6.261_ExRate10" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1,2-a]pyrazine-1,4-dione_210.13683_211.144_6.261_ExRate2" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1,2-a]pyrazine-1,4-dione_210.13683_211.144_6.261_ExRate3" "Pos_3-(2-methylpropyl)-octahydropyrrolo[1,2-a]pyrazine-1,4-dione_210.13683_211.144_6.261_ExRate4" "Pos_N3,N4-Dimethyl-L-arginine_202.14298_203.1501_8.98_ExRate0" "Pos_N3,N4-Dimethyl-L-arginine_202.14298_203.1501_8.98_ExRate2" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "Intra_BK_2" column at position 62 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values. Warning: The "other_id" column at position 5 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.