Validation Log 2025-12-15 01:00:52.405411 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004211/mwtab/json Study ID: ST002556 Analysis ID: AN004211 File format: json Status: Contains Validation Issues Number of Issues: 17 Number of Warnings: 12 Number of Value Errors: 13 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "1 mL min-1", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "50-330", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "1_5-anhydroglucitol" "2_5-dihydroxypyrazine" "2_6-diaminopimelic acid" "2_8-dihydroxyquinoline" "2^-deoxyguanosine" "5_6-dihydrouracil" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "1,5-anhydroglucitol" "2,5-dihydroxypyrazine" "2,6-diaminopimelic acid" "2,8-dihydroxyquinoline" "2'-deoxyguanosine" "5,6-dihydrouracil" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "10318_Calving_Met" column at position 209 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "10251_Prepartum_Met" column at position 298 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "10260_Prepartum_Met" column at position 304 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.