Validation Log
2025-12-15 01:05:23.989181
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004302/mwtab/json
Study ID:      ST002630
Analysis ID:   AN004302
File format:   json
Status: Contains Validation Issues
Number of Issues: 10

Number of Warnings: 5

Number of Value Errors: 8

Number of Consistency Errors: 1

Number of Format Errors: 1

Issue Log:
Error: The required property, "COLLECTION_SUMMARY", in ["COLLECTION"] is missing.
Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key.
Error: The value, "0.4 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "50C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"new_SM(d42:2)_M+H2CO2"
	"new_SM(d42:1)_M+H2CO2"
	"new_PE(O-42:5)>PE(O-20:1/22:4)"
	"new_PE(36:2)>PE(18:0_18:2)"
	"new_Cer(d43:1)_M+H2CO2"
Warning: The "mz" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "neutral_mass" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
2       C38 H67 D7 N O8 P
3       C23 H39 D7 N O7 P
4      C42 H75 D7 N O10 P
5       C27 H47 D7 N O9 P
6      C39 H67 D7 N O10 P
7      C42 H75 D7 N O13 P
8          C18 H38 N O5 P
25         C46 H78 N O9 P
26        C44 H78 N O10 P
37         C45 H82 N O7 P
38         C45 H84 N O7 P
39         C47 H86 N O7 P
40         C45 H78 N O7 P
41         C45 H82 N O7 P
42         C45 H84 N O7 P
43         C43 H74 N O7 P
44         C43 H76 N O7 P
45         C43 H78 N O7 P
46         C43 H78 N O7 P
47         C43 H80 N O7 P
48         C41 H74 N O7 P
49         C45 H78 N O8 P
50         C43 H74 N O8 P
51         C43 H76 N O8 P
52         C43 H78 N O8 P
53         C41 H74 N O8 P
54         C41 H78 N O8 P
55         C39 H74 N O8 P
56         C47 H86 N O9 P
57         C49 H92 N O9 P
58         C47 H88 N O9 P
59         C45 H82 N O9 P
60         C45 H84 N O9 P
61         C43 H86 N O9 P
62        C51 H82 N O10 P
63        C49 H82 N O10 P
64        C49 H84 N O10 P
65        C49 H86 N O10 P
66        C49 H88 N O10 P
67        C49 H88 N O10 P
68        C49 H90 N O10 P
69        C49 H90 N O10 P
70        C48 H88 N O10 P
71        C48 H88 N O10 P
72        C47 H82 N O10 P
73        C47 H82 N O10 P
74        C47 H84 N O10 P
75        C47 H84 N O10 P
76        C47 H86 N O10 P
77        C47 H88 N O10 P
78        C47 H90 N O10 P
79        C46 H84 N O10 P
80        C46 H84 N O10 P
81        C45 H80 N O10 P
82        C45 H80 N O10 P
83        C45 H82 N O10 P
84        C45 H84 N O10 P
85        C45 H84 N O10 P
86        C45 H86 N O10 P
87        C45 H88 N O10 P
88        C45 H90 N O10 P
89        C44 H80 N O10 P
90        C44 H84 N O10 P
91        C44 H84 N O10 P
92        C43 H78 N O10 P
93        C43 H80 N O10 P
94        C43 H80 N O10 P
95        C43 H82 N O10 P
96        C43 H84 N O10 P
97        C43 H86 N O10 P
98        C41 H78 N O10 P
99        C41 H80 N O10 P
101        C20 H44 N O6 P
102        C27 H44 N O7 P
103        C25 H44 N O7 P
104        C25 H52 N O7 P
105        C23 H48 N O7 P
106        C21 H44 N O7 P
107        C31 H52 N O9 P
108        C31 H54 N O9 P
109        C31 H64 N O9 P
110        C29 H50 N O9 P
111        C29 H52 N O9 P
112        C29 H54 N O9 P
113        C29 H56 N O9 P
114        C29 H58 N O9 P
115        C27 H52 N O9 P
116        C27 H54 N O9 P
117        C27 H56 N O9 P
118        C26 H54 N O9 P
119        C25 H50 N O9 P
122        C23 H48 N O9 P
123         C49 H93 N O10
124         C49 H97 N O11
125         C48 H93 N O10
126         C47 H91 N O10
134          C44 H87 N O5
135          C42 H81 N O3
136          C42 H83 N O3
137          C43 H87 N O6
138          C42 H83 N O5
139          C41 H81 N O5
140          C37 H73 N O5
141          C35 H69 N O5
Warning: The "refmet_name" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "rt" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.