Validation Log
2025-12-15 01:05:27.776148
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004303/mwtab/json
Study ID:      ST002631
Analysis ID:   AN004303
File format:   json
Status: Contains Validation Issues
Number of Issues: 18

Number of Warnings: 11

Number of Value Errors: 13

Number of Consistency Errors: 2

Number of Format Errors: 1

Issue Log:
Error: The required property, "COLLECTION_SUMMARY", in ["COLLECTION"] is missing.
Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key.
Error: The value, "0.4 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "50C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"5-henicosylbenzene-1_3-diol_feature1"
	"GTInternalStandard_CE(18:1(9z_d7))_M+NH3_feature1"
	"GTInternalStandard_PC(18:1(d7))>PC(18:1(9z_d7)/0:0)_and_PC(18:1(d7))>PC(0:0/18:1(9z_d7))_feature1"
	"GTInternalStandard_PC(33:1(d7))>PC(15:0/18:1(9z_d7))_feature1"
	"GTInternalStandard_PE(18:1(d7))>PE(18:1(9z_d7)/0:0)_and_PE(18:1(d7))>PE(0:0/18:1(9z_d7))_feature1"
	"GTInternalStandard_PE(33:1(d7))>PE(15:0/18:1(9z_d7))_feature1"
	"GTInternalStandard_PI(33:1(d7))>PI(15:0/18:1(9z_d7))_feature1"
	"GTInternalStandard_PS(33:1(d7))>PS(15:0/18:1(9z_d7))_feature1"
	"GTInternalStandard_SM(d36:2(d9))>SM(d18:1/18:1(9z_d9))_feature1"
	"GTInternalStandard_TG(48:1(d7))>TG(15:0/18:1(9z_d7)/15:0)_feature1"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"5-henicosylbenzene-1,3-diol_feature1"
	"GTInternalStandard_CE(18:1(9z,d7))_M+NH3_feature1"
	"GTInternalStandard_PC(18:1(d7))>PC(18:1(9z,d7)/0:0)_and_PC(18:1(d7))>PC(0:0/18:1(9z,d7))_feature1"
	"GTInternalStandard_PC(33:1(d7))>PC(15:0/18:1(9z,d7))_feature1"
	"GTInternalStandard_PE(18:1(d7))>PE(18:1(9z,d7)/0:0)_and_PE(18:1(d7))>PE(0:0/18:1(9z,d7))_feature1"
	"GTInternalStandard_PE(33:1(d7))>PE(15:0/18:1(9z,d7))_feature1"
	"GTInternalStandard_PI(33:1(d7))>PI(15:0/18:1(9z,d7))_feature1"
	"GTInternalStandard_PS(33:1(d7))>PS(15:0/18:1(9z,d7))_feature1"
	"GTInternalStandard_SM(d36:2(d9))>SM(d18:1/18:1(9z,d9))_feature1"
	"GTInternalStandard_TG(48:1(d7))>TG(15:0/18:1(9z,d7)/15:0)_feature1"
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table.
Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.