Validation Log 2025-12-15 01:05:45.096101 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004308/mwtab/txt Study ID: ST002636 Analysis ID: AN004308 File format: txt Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 5 Number of Value Errors: 8 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The required property, "COLLECTION_SUMMARY", in the "COLLECTION" section is missing. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: The value, "0.4 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "50C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "mz" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "neutral_mass" column at position 4 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "formula" column at position 2 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 2 C23 H39 D7 N O7 P 3 C42 H75 D7 N O10 P 4 C27 H47 D7 N O9 P 5 C38 H67 D7 N O8 P 6 C50 H95 N O11 S 7 C50 H97 N O11 S 8 C49 H93 N O11 S 9 C49 H95 N O11 S 10 C48 H91 N O12 S 11 C48 H91 N O11 S 12 C48 H93 N O12 S 13 C48 H93 N O11 S 14 C47 H91 N O12 S 15 C47 H91 N O11 S 16 C46 H87 N O11 S 17 C46 H89 N O12 S 18 C44 H85 N O11 S 19 C42 H81 N O11 S 20 C40 H77 N O11 S 35 C48 H82 N O9 P 36 C46 H78 N O9 P 37 C46 H78 N O9 P 38 C46 H80 N O9 P 39 C46 H82 N O9 P 40 C46 H84 N O9 P 41 C50 H74 N O10 P 42 C50 H78 N O10 P 43 C46 H78 N O10 P 44 C46 H80 N O10 P 45 C46 H82 N O10 P 46 C44 H76 N O10 P 47 C44 H78 N O10 P 48 C44 H78 N O10 P 49 C44 H82 N O10 P 50 C42 H78 N O10 P 51 C42 H80 N O10 P 52 C40 H76 N O10 P 63 C47 H84 N O7 P 64 C47 H82 N O7 P 65 C47 H84 N O7 P 66 C47 H86 N O7 P 67 C47 H90 N O7 P 68 C46 H88 N O7 P 69 C45 H76 N O7 P 70 C45 H78 N O7 P 71 C45 H78 N O7 P 72 C45 H78 N O7 P 73 C45 H80 N O7 P 74 C45 H80 N O7 P 75 C45 H80 N O7 P 76 C45 H82 N O7 P 77 C45 H82 N O7 P 78 C45 H84 N O7 P 79 C45 H88 N O7 P 80 C45 H88 N O7 P 81 C44 H76 N O7 P 82 C44 H80 N O7 P 83 C44 H84 N O7 P 84 C43 H74 N O7 P 85 C43 H74 N O7 P 86 C43 H76 N O7 P 87 C43 H76 N O7 P 88 C43 H78 N O7 P 89 C43 H78 N O7 P 90 C43 H78 N O7 P 91 C43 H78 N O7 P 92 C43 H80 N O7 P 93 C43 H80 N O7 P 94 C43 H80 N O7 P 95 C43 H82 N O7 P 96 C43 H84 N O7 P 97 C43 H84 N O7 P 98 C42 H80 N O7 P 99 C42 H82 N O7 P 100 C41 H74 N O7 P 101 C41 H80 N O7 P 102 C41 H76 N O7 P 103 C41 H76 N O7 P 104 C41 H76 N O7 P 105 C41 H82 N O7 P 106 C40 H76 N O7 P 107 C40 H78 N O7 P 108 C42 H76 N O7 P 109 C39 H74 N O7 P 110 C39 H76 N O7 P 111 C39 H76 N O7 P 112 C39 H78 N O7 P 113 C39 H78 N O7 P 114 C37 H72 N O7 P 115 C37 H74 N O7 P 116 C49 H74 N O8 P 117 C49 H78 N O8 P 118 C47 H78 N O8 P 119 C47 H84 N O8 P 120 C47 H74 N O8 P 121 C45 H74 N O8 P 122 C45 H76 N O8 P 123 C45 H78 N O8 P 124 C45 H80 N O8 P 125 C45 H82 N O8 P 126 C45 H82 N O8 P 127 C45 H86 N O8 P 128 C45 H88 N O8 P 129 C44 H76 N O8 P 130 C43 H72 N O8 P 131 C43 H74 N O8 P 132 C43 H74 N O8 P 133 C43 H76 N O8 P 134 C43 H78 N O8 P 135 C43 H78 N O8 P 136 C43 H80 N O8 P 137 C43 H84 N O8 P 138 C42 H76 N O8 P 139 C41 H72 N O8 P 140 C41 H74 N O8 P 141 C41 H76 N O8 P 142 C41 H76 N O8 P 143 C41 H78 N O8 P 144 C41 H80 N O8 P 145 C41 H80 N O8 P 146 C40 H78 N O8 P 147 C39 H74 N O8 P 148 C39 H76 N O8 P 149 C39 H78 N O8 P 150 C39 H78 N O8 P 151 C37 H72 N O8 P 152 C37 H74 N O8 P 153 C45 H82 N O9 P 154 C45 H90 N O9 P 155 C45 H88 N O9 P 156 C45 H88 N O9 P 157 C43 H86 N O9 P 158 C43 H86 N O9 P 159 C41 H82 N O9 P 160 C53 H102 N O10 P 161 C52 H102 N O10 P 162 C51 H94 N O10 P 163 C51 H82 N O10 P 164 C51 H100 N O10 P 165 C50 H96 N O10 P 166 C50 H98 N O10 P 167 C49 H86 N O10 P 168 C49 H88 N O10 P 169 C49 H90 N O10 P 170 C47 H82 N O10 P 171 C47 H82 N O10 P 172 C47 H84 N O10 P 173 C47 H86 N O10 P 174 C47 H88 N O10 P 175 C47 H90 N O10 P 176 C45 H80 N O10 P 177 C45 H82 N O10 P 178 C45 H84 N O10 P 179 C45 H86 N O10 P 180 C45 H88 N O10 P 181 C45 H90 N O10 P 182 C44 H86 N O10 P 183 C43 H82 N O10 P 184 C43 H84 N O10 P 185 C43 H86 N O10 P 186 C41 H80 N O10 P 187 C41 H82 N O10 P 188 C39 H78 N O10 P 193 C23 H46 N O6 P 194 C20 H44 N O6 P 195 C27 H44 N O7 P 196 C25 H44 N O7 P 197 C23 H48 N O7 P 198 C21 H44 N O7 P 199 C29 H52 N O9 P 200 C27 H54 N O9 P 201 C27 H56 N O9 P 203 C51 H97 N O10 204 C51 H99 N O10 205 C49 H93 N O9 206 C50 H95 N O10 207 C49 H95 N O9 208 C49 H91 N O10 209 C48 H91 N O9 210 C48 H91 N O8 211 C48 H93 N O9 212 C49 H95 N O10 213 C48 H93 N O8 214 C48 H95 N O9 215 C49 H97 N O10 216 C46 H87 N O7 217 C47 H89 N O9 218 C48 H91 N O10 219 C48 H91 N O10 220 C47 H91 N O9 221 C47 H91 N O8 222 C47 H89 N O11 223 C46 H87 N O9 224 C47 H89 N O10 225 C47 H89 N O10 226 C47 H89 N O10 227 C46 H89 N O9 228 C46 H89 N O8 229 C45 H87 N O9 230 C44 H85 N O9 231 C43 H83 N O6 232 C42 H81 N O8 233 C54 H99 N O13 234 C53 H97 N O13 235 C52 H95 N O13 236 C50 H91 N O13 240 C43 H83 N O5 241 C43 H85 N O5 242 C42 H81 N O5 243 C42 H83 N O5 244 C38 H75 N O3 245 C37 H71 N O5 246 C36 H71 N O3 247 C35 H69 N O5 Warning: The "refmet_name" column at position 5 in the METABOLITES table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "rt" column at position 6 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.