Validation Log 2025-12-15 01:06:50.944676 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004324/mwtab/txt Study ID: ST002652 Analysis ID: AN004324 File format: txt Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 5 Number of Value Errors: 8 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The required property, "COLLECTION_SUMMARY", in the "COLLECTION" section is missing. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: The value, "0.4 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "50C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "mz" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "neutral_mass" column at position 4 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "formula" column at position 2 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 C51 H92 D7 N O6 2 C42 H75 D7 N O13 P 4 C38 H67 D7 N O8 P 5 C23 H39 D7 N O7 P 6 C41 H73 D7 N O8 P 7 C26 H45 D7 N O7 P 10 C39 H67 D7 N O10 P 12 C59 H95 N O4 13 C63 H117 N O6 14 C63 H119 N O6 15 C63 H105 N O6 16 C63 H105 N O6 17 C63 H105 N O6 18 C61 H103 N O6 19 C61 H103 N O6 20 C61 H105 N O6 21 C61 H105 N O6 22 C61 H105 N O6 23 C61 H105 N O6 24 C61 H107 N O6 25 C61 H107 N O6 26 C61 H109 N O6 27 C61 H109 N O6 28 C61 H109 N O6 29 C61 H109 N O6 30 C61 H109 N O6 31 C61 H111 N O6 32 C61 H113 N O6 33 C61 H115 N O6 34 C61 H117 N O6 35 C61 H99 N O6 36 C61 H99 N O6 37 C61 H101 N O6 38 C61 H101 N O6 39 C61 H119 N O6 40 C60 H111 N O6 41 C60 H113 N O6 42 C60 H115 N O6 43 C59 H101 N O6 44 C59 H101 N O6 45 C59 H101 N O6 46 C59 H103 N O6 47 C59 H103 N O6 48 C59 H103 N O6 49 C59 H103 N O6 50 C59 H105 N O6 51 C59 H105 N O6 52 C59 H107 N O6 53 C59 H107 N O6 54 C59 H107 N O6 55 C59 H107 N O6 56 C59 H109 N O6 57 C59 H109 N O6 58 C59 H109 N O6 59 C59 H111 N O6 60 C59 H113 N O6 61 C59 H97 N O6 62 C59 H115 N O6 63 C58 H105 N O6 64 C58 H107 N O6 65 C58 H109 N O6 66 C58 H113 N O6 67 C57 H97 N O6 68 C57 H99 N O6 69 C57 H99 N O6 71 C57 H101 N O6 72 C57 H101 N O6 73 C57 H101 N O6 74 C57 H101 N O6 75 C57 H103 N O6 76 C57 H103 N O6 78 C57 H103 N O6 79 C57 H105 N O6 80 C57 H105 N O6 82 C57 H105 N O6 83 C57 H107 N O6 84 C57 H107 N O6 85 C57 H107 N O6 86 C57 H107 N O6 87 C57 H109 N O6 88 C57 H111 N O6 89 C56 H101 N O6 90 C56 H103 N O6 91 C56 H103 N O6 92 C56 H105 N O6 93 C56 H105 N O6 94 C56 H105 N O6 95 C56 H107 N O6 96 C56 H107 N O6 97 C55 H97 N O6 98 C55 H97 N O6 99 C55 H99 N O6 100 C55 H99 N O6 101 C55 H99 N O6 103 C55 H101 N O6 104 C55 H103 N O6 107 C55 H107 N O6 108 C55 H109 N O6 109 C54 H99 N O6 110 C54 H101 N O6 111 C54 H103 N O6 112 C54 H103 N O6 113 C54 H105 N O6 114 C54 H107 N O6 115 C53 H95 N O6 116 C53 H97 N O6 117 C53 H97 N O6 118 C53 H99 N O6 120 C53 H101 N O6 121 C53 H101 N O6 123 C53 H105 N O6 124 C52 H97 N O6 125 C52 H99 N O6 126 C52 H101 N O6 127 C52 H103 N O6 128 C51 H93 N O6 129 C51 H93 N O6 130 C51 H95 N O6 131 C51 H97 N O6 132 C51 H99 N O6 133 C51 H101 N O6 134 C49 H91 N O6 135 C49 H93 N O6 136 C49 H95 N O6 137 C49 H97 N O6 138 C47 H87 N O6 139 C47 H87 N O6 140 C47 H89 N O6 141 C43 H79 N O6 142 C41 H77 N O6 143 C41 H79 N O6 144 C39 H73 N O6 145 C39 H75 N O6 146 C8 H20 N O6 P 183 C50 H78 N O10 P 184 C46 H78 N O10 P 185 C46 H78 N O10 P 186 C46 H80 N O10 P 187 C46 H82 N O10 P 188 C44 H78 N O10 P 189 C44 H80 N O10 P 190 C42 H78 N O10 P 197 C42 H78 O10 N P 198 C47 H84 N O7 P 199 C45 H76 N O7 P 200 C45 H78 N O7 P 201 C45 H78 N O7 P 202 C45 H78 N O7 P 203 C45 H78 N O7 P 204 C45 H80 N O7 P 205 C45 H80 N O7 P 206 C45 H80 N O7 P 207 C45 H82 N O7 P 208 C45 H82 N O7 P 209 C45 H84 N O7 P 210 C43 H74 N O7 P 211 C43 H76 N O7 P 212 C43 H76 N O7 P 213 C43 H78 N O7 P 214 C43 H78 N O7 P 215 C43 H78 N O7 P 216 C43 H78 N O7 P 217 C43 H80 N O7 P 218 C43 H84 N O7 P 219 C42 H76 N O7 P 220 C42 H76 N O7 P 221 C41 H78 N O7 P 222 C41 H76 N O7 P 223 C41 H80 N O7 P 224 C39 H76 N O7 P 225 C39 H78 N O7 P 226 C39 H78 N O7 P 227 C49 H78 N O8 P 228 C47 H78 N O8 P 229 C47 H78 N O8 P 230 C47 H74 N O8 P 231 C47 H74 N O8 P 232 C45 H74 N O8 P 233 C45 H76 N O8 P 234 C45 H78 N O8 P 235 C45 H78 N O8 P 236 C45 H78 N O8 P 237 C45 H80 N O8 P 238 C45 H80 N O8 P 239 C45 H80 N O8 P 240 C45 H80 N O8 P 241 C45 H80 N O8 P 242 C45 H82 N O8 P 243 C45 H82 N O8 P 244 C45 H82 N O8 P 245 C43 H74 N O8 P 246 C43 H74 N O8 P 247 C43 H74 N O8 P 248 C43 H76 N O8 P 249 C43 H76 N O8 P 250 C43 H76 N O8 P 251 C43 H76 N O8 P 252 C43 H76 N O8 P 253 C43 H78 N O8 P 254 C43 H78 N O8 P 255 C43 H80 N O8 P 256 C43 H80 N O8 P 257 C41 H72 N O8 P 258 C41 H74 N O8 P 259 C41 H74 N O8 P 260 C41 H74 N O8 P 261 C41 H76 N O8 P 262 C41 H78 N O8 P 263 C41 H80 N O8 P 264 C39 H74 N O8 P 265 C39 H76 N O8 P 266 C48 H84 N O7 P 267 C48 H84 N O7 P 268 C48 H86 N O7 P 269 C48 H86 N O7 P 270 C48 H86 N O7 P 271 C46 H80 N O7 P 272 C46 H80 N O7 P 273 C46 H80 N O7 P 274 C46 H80 N O7 P 275 C46 H82 N O7 P 276 C46 H82 N O7 P 277 C46 H82 N O7 P 278 C46 H84 N O7 P 279 C46 H84 N O7 P 280 C46 H84 N O7 P 281 C46 H86 N O7 P 282 C46 H86 N O7 P 283 C46 H86 N O7 P 284 C45 H82 N O7 P 285 C44 H80 N O7 P 286 C44 H82 N O7 P 287 C44 H84 N O7 P 288 C44 H84 N O7 P 289 C44 H84 N O7 P 290 C44 H86 N O7 P 291 C44 H88 N O7 P 292 C42 H82 N O7 P 293 C42 H82 N O7 P 294 C42 H84 N O7 P 295 C42 H84 N O7 P 296 C42 H86 N O7 P 297 C41 H84 N O7 P 298 C40 H80 N O7 P 299 C40 H80 N O7 P 300 C40 H82 N O7 P 301 C38 H78 N O7 P 302 C52 H94 N O8 P 303 C52 H96 N O8 P 304 C52 H80 N O8 P 305 C52 H84 N O8 P 306 C50 H82 N O8 P 307 C50 H82 N O8 P 308 C50 H82 N O8 P 309 C50 H84 N O8 P 310 C50 H86 N O8 P 311 C50 H86 N O8 P 312 C50 H88 N O8 P 313 C50 H88 N O8 P 314 C50 H90 N O8 P 315 C50 H90 N O8 P 316 C50 H92 N O8 P 317 C50 H92 N O8 P 318 C50 H94 N O8 P 319 C50 H96 N O8 P 320 C49 H84 N O8 P 321 C49 H86 N O8 P 322 C49 H86 N O8 P 323 C49 H86 N O8 P 324 C50 H80 N O8 P 325 C48 H80 N O8 P 326 C48 H82 N O8 P 327 C48 H82 N O8 P 328 C48 H84 N O8 P 329 C48 H86 N O8 P 330 C48 H86 N O8 P 331 C48 H86 N O8 P 332 C48 H88 N O8 P 333 C48 H88 N O8 P 334 C48 H92 N O8 P 335 C48 H94 N O8 P 336 C48 H96 N O8 P 337 C47 H82 N O8 P 338 C47 H82 N O8 P 339 C47 H84 N O8 P 340 C47 H84 N O8 P 341 C47 H84 N O8 P 342 C47 H86 N O8 P 343 C47 H86 N O8 P 344 C47 H92 N O8 P 345 C46 H78 N O8 P 346 C46 H78 N O8 P 347 C46 H78 N O8 P 348 C46 H80 N O8 P 349 C46 H80 N O8 P 350 C46 H82 N O8 P 351 C46 H82 N O8 P 352 C46 H82 N O8 P 353 C46 H82 N O8 P 354 C46 H84 N O8 P 355 C46 H84 N O8 P 356 C46 H86 N O8 P 357 C46 H88 N O8 P 358 C46 H90 N O8 P 359 C46 H92 N O8 P 360 C45 H78 N O8 P 361 C45 H78 N O8 P 362 C45 H82 N O8 P 363 C45 H82 N O8 P 364 C45 H84 N O8 P 365 C45 H84 N O8 P 366 C45 H84 N O8 P 367 C45 H86 N O8 P 368 C45 H86 N O8 P 369 C45 H88 N O8 P 370 C45 H88 N O8 P 371 C45 H90 N O8 P 372 C45 H90 N O8 P 373 C44 H76 N O8 P 374 C44 H78 N O8 P 375 C44 H78 N O8 P 376 C44 H78 N O8 P 377 C44 H78 N O8 P 378 C44 H78 N O8 P 379 C44 H80 N O8 P 380 C44 H80 N O8 P 381 C44 H80 N O8 P 382 C44 H82 N O8 P 383 C44 H82 N O8 P 384 C44 H84 N O8 P 385 C44 H84 N O8 P 386 C44 H86 N O8 P 387 C44 H88 N O8 P 388 C43 H78 N O8 P 389 C43 H78 N O8 P 390 C43 H80 N O8 P 391 C43 H82 N O8 P 392 C43 H84 N O8 P 393 C43 H86 N O8 P 394 C43 H86 N O8 P 395 C42 H76 N O8 P 396 C42 H78 N O8 P 397 C42 H78 N O8 P 398 C42 H80 N O8 P 399 C42 H82 N O8 P 400 C42 H84 N O8 P 401 C41 H80 N O8 P 402 C41 H82 N O8 P 403 C41 H82 N O8 P 404 C40 H76 N O8 P 405 C40 H78 N O8 P 406 C40 H78 N O8 P 407 C40 H80 N O8 P 408 C40 H80 N O8 P 409 C39 H78 N O8 P 410 C38 H76 N O8 P 413 C23 H48 N O7 P 414 C21 H44 N O7 P 415 C32 H66 N O7 P 416 C30 H50 N O7 P 417 C30 H52 N O7 P 418 C30 H62 N O7 P 419 C28 H50 N O7 P 420 C28 H56 N O7 P 421 C28 H58 N O7 P 422 C27 H56 N O7 P 423 C27 H56 N O7 P 424 C26 H50 N O7 P 425 C26 H52 N O7 P 426 C26 H52 N O7 P 427 C26 H54 N O7 P 428 C25 H52 N O7 P 429 C24 H48 N O7 P 430 C24 H50 N O7 P 431 C46 H89 N O8 433 C24 H49 N O2 434 C20 H41 N O2 435 C19 H39 N O2 436 C17 H35 N O2 437 C43 H73 N O5 439 C43 H79 N O5 440 C41 H71 N O5 443 C41 H75 N O5 444 C41 H77 N O5 447 C39 H73 N O5 448 C39 H75 N O5 449 C39 H75 N O5 450 C39 H77 N O5 451 C37 H71 N O5 453 C37 H75 N O5 458 C44 H85 N O3 459 C44 H87 N O3 460 C43 H85 N O3 461 C43 H85 N O3 462 C42 H79 N O3 463 C42 H81 N O3 464 C42 H81 N O3 465 C42 H83 N O3 466 C42 H85 N O3 467 C41 H79 N O3 468 C41 H81 N O3 469 C40 H77 N O3 470 C40 H79 N O3 471 C39 H77 N O3 472 C36 H71 N O3 473 C34 H67 N O3 474 C49 H79 N O2 476 C45 H79 N O2 477 C7 H15 N O3 478 C15 H29 N O4 479 C13 H25 N O4 480 C12 H23 N O4 481 C11 H21 N O5 482 C11 H21 N O4 483 C10 H19 N O4 484 C33 H63 N O4 485 C31 H59 N O4 486 C31 H61 N O4 487 C29 H49 N O4 488 C27 H45 N O4 489 C27 H49 N O4 490 C27 H51 N O4 491 C9 H17 N O4 492 C26 H51 N O4 493 C25 H43 N O4 494 C25 H45 N O4 495 C25 H47 N O5 496 C25 H47 N O4 497 C25 H49 N O5 498 C25 H49 N O4 499 C23 H39 N O4 500 C23 H41 N O5 501 C23 H41 N O4 502 C23 H43 N O4 503 C23 H43 N O4 504 C23 H45 N O5 505 C23 H45 N O4 506 C22 H43 N O4 507 C21 H37 N O5 508 C21 H37 N O4 509 C21 H39 N O5 510 C21 H39 N O4 511 C21 H41 N O5 512 C21 H41 N O4 513 C20 H39 N O4 514 C19 H35 N O4 515 C19 H37 N O5 516 C19 H37 N O4 517 C17 H33 N O5 518 C17 H33 N O4 Warning: The "refmet_name" column at position 5 in the METABOLITES table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "rt" column at position 6 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.