Validation Log 2025-12-15 01:07:59.665011 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004342/mwtab/json Study ID: ST002670 Analysis ID: AN004342 File format: json Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 5 Number of Value Errors: 8 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The required property, "COLLECTION_SUMMARY", in ["COLLECTION"] is missing. Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value, "0.4 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "50C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "mz" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "neutral_mass" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 2 C38 H67 D7 N O8 P 3 C23 H39 D7 N O7 P 4 C42 H75 D7 N O10 P 5 C27 H47 D7 N O9 P 24 C48 H82 N O9 P 25 C46 H78 N O9 P 26 C46 H78 N O9 P 27 C46 H78 N O10 P 28 C46 H78 N O10 P 29 C46 H80 N O10 P 30 C46 H80 N O10 P 31 C46 H82 N O10 P 32 C44 H76 N O10 P 33 C44 H78 N O10 P 34 C44 H78 N O10 P 35 C44 H80 N O10 P 36 C44 H82 N O10 P 37 C42 H78 N O10 P 38 C42 H80 N O10 P 39 C40 H77 N Na O10 P 68 C47 H84 N O7 P 69 C47 H86 N O7 P 70 C45 H76 N O7 P 71 C45 H78 N O7 P 72 C45 H80 N O7 P 73 C45 H80 N O7 P 74 C45 H80 N O7 P 75 C45 H82 N O7 P 76 C45 H84 N O7 P 77 C44 H80 N O7 P 78 C44 H80 N O7 P 79 C44 H80 N O7 P 80 C44 H80 N O7 P 81 C43 H74 N O7 P 82 C43 H74 N O7 P 83 C43 H76 N O7 P 84 C43 H76 N O7 P 85 C43 H78 N O7 P 86 C43 H78 N O7 P 87 C43 H78 N O7 P 88 C43 H80 N O7 P 89 C43 H80 N O7 P 90 C43 H82 N O7 P 91 C43 H84 N O7 P 92 C41 H74 N O7 P 93 C41 H80 N O7 P 94 C41 H76 N O7 P 95 C41 H76 N O7 P 96 C41 H76 N O7 P 97 C41 H82 N O7 P 98 C41 H78 N O7 P 99 C40 H78 N O7 P 100 C40 H78 N O7 P 101 C42 H76 N O7 P 102 C42 H76 N O7 P 103 C39 H74 N O7 P 104 C39 H76 N O7 P 105 C39 H78 N O7 P 106 C37 H72 N O7 P 107 C37 H74 N O7 P 108 C47 H84 N O8 P 109 C47 H86 N O8 P 110 C45 H78 N O8 P 111 C45 H80 N O8 P 112 C45 H82 N O8 P 113 C45 H82 N O8 P 114 C45 H86 N O8 P 115 C45 H88 N O8 P 116 C43 H74 N O8 P 117 C43 H74 N O8 P 118 C43 H76 N O8 P 119 C43 H76 N O8 P 120 C43 H78 N O8 P 121 C43 H78 N O8 P 122 C43 H80 N O8 P 123 C43 H84 N O8 P 124 C42 H76 N O8 P 125 C41 H72 N O8 P 126 C41 H74 N O8 P 127 C41 H76 N O8 P 128 C41 H78 N O8 P 129 C41 H78 N O8 P 130 C41 H80 N O8 P 131 C41 H80 N O8 P 132 C39 H72 N O8 P 133 C39 H74 N O8 P 134 C39 H76 N O8 P 135 C39 H78 N O8 P 136 C37 H72 N O8 P 137 C47 H86 N O9 P 138 C45 H82 N O9 P 139 C45 H84 N O9 P 140 C43 H86 N O9 P 141 C43 H86 N O9 P 142 C41 H82 N O9 P 143 C41 H84 N O9 P 144 C51 H82 N O10 P 145 C51 H100 N O10 P 146 C49 H82 N O10 P 147 C49 H88 N O10 P 148 C49 H90 N O10 P 149 C49 H94 N O10 P 150 C49 H96 N O10 P 151 C47 H82 N O10 P 152 C47 H82 N O10 P 153 C47 H84 N O10 P 154 C47 H84 N O10 P 155 C47 H86 N O10 P 156 C47 H86 N O10 P 157 C47 H88 N O10 P 158 C47 H90 N O10 P 159 C47 H90 N O10 P 160 C46 H84 N O10 P 161 C45 H80 N O10 P 162 C45 H80 N O10 P 163 C45 H82 N O10 P 164 C45 H82 N O10 P 165 C45 H84 N O10 P 166 C45 H86 N O10 P 167 C45 H88 N O10 P 168 C45 H90 N O10 P 169 C44 H84 N O10 P 170 C43 H78 N O10 P 171 C43 H78 N O10 P 172 C43 H80 N O10 P 173 C43 H80 N O10 P 174 C43 H82 N O10 P 175 C43 H84 N O10 P 176 C43 H86 N O10 P 177 C41 H78 N O10 P 178 C41 H80 N O10 P 179 C41 H82 N O10 P 180 C39 H78 N O10 P 181 C23 H48 N O6 P 182 C20 H44 N O6 P 183 C25 H52 N O7 P 184 C23 H48 N O7 P 185 C21 H44 N O7 P 186 C27 H52 N O9 P 187 C49 H93 N O10 188 C49 H95 N O10 189 C47 H91 N O10 193 C45 H89 N O5 194 C42 H81 N O3 195 C43 H83 N O5 196 C43 H85 N O5 197 C42 H83 N O3 198 C43 H87 N O6 199 C43 H87 N O5 200 C42 H83 N O5 201 C41 H79 N O5 202 C40 H79 N O3 203 C39 H77 N O5 204 C35 H69 N O5 205 C29 H52 N O9 P 206 C27 H54 N O9 P 207 C27 H56 N O9 P 208 C26 H54 N O9 P 209 C25 H52 N O9 P Warning: The "refmet_name" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "rt" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.