Validation Log 2025-12-15 01:08:29.478522 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004350/mwtab/txt Study ID: ST002678 Analysis ID: AN004350 File format: txt Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 5 Number of Value Errors: 8 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The required property, "COLLECTION_SUMMARY", in the "COLLECTION" section is missing. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: The value, "0.4 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "50C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "mz" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "neutral_mass" column at position 4 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "formula" column at position 2 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 C51 H92 D7 N O6 2 C42 H75 D7 N O13 P 4 C38 H67 D7 N O8 P 5 C23 H39 D7 N O7 P 6 C41 H73 D7 N O8 P 7 C26 H45 D7 N O7 P 11 C59 H95 N O4 12 C63 H117 N O6 13 C63 H119 N O6 14 C63 H105 N O6 15 C63 H105 N O6 16 C63 H105 N O6 17 C63 H105 N O6 18 C61 H103 N O6 19 C61 H103 N O6 20 C61 H103 N O6 21 C61 H105 N O6 22 C61 H105 N O6 23 C61 H105 N O6 24 C61 H105 N O6 25 C61 H107 N O6 26 C61 H107 N O6 27 C61 H109 N O6 28 C61 H109 N O6 29 C61 H111 N O6 30 C61 H111 N O6 31 C61 H111 N O6 32 C61 H111 N O6 33 C61 H113 N O6 34 C61 H115 N O6 35 C61 H117 N O6 36 C61 H99 N O6 37 C61 H99 N O6 38 C61 H101 N O6 39 C61 H101 N O6 40 C61 H101 N O6 41 C61 H119 N O6 42 C60 H111 N O6 44 C59 H101 N O6 45 C59 H101 N O6 46 C59 H103 N O6 47 C59 H103 N O6 48 C59 H103 N O6 49 C59 H103 N O6 50 C59 H105 N O6 51 C59 H105 N O6 52 C59 H105 N O6 54 C59 H107 N O6 55 C59 H107 N O6 56 C59 H107 N O6 57 C59 H109 N O6 58 C59 H109 N O6 59 C59 H109 N O6 60 C59 H109 N O6 61 C59 H109 N O6 62 C59 H109 N O6 63 C59 H111 N O6 64 C59 H113 N O6 65 C59 H113 N O6 66 C59 H97 N O6 67 C59 H115 N O6 68 C59 H115 N O6 69 C58 H101 N O6 70 C58 H103 N O6 71 C58 H103 N O6 72 C58 H105 N O6 73 C58 H105 N O6 74 C58 H105 N O6 75 C58 H107 N O6 76 C58 H107 N O6 77 C58 H109 N O6 78 C58 H111 N O6 79 C58 H111 N O6 80 C58 H113 N O6 81 C57 H97 N O6 82 C57 H97 N O6 83 C57 H99 N O6 84 C57 H99 N O6 85 C57 H99 N O6 86 C57 H99 N O6 87 C57 H101 N O6 89 C57 H101 N O6 90 C57 H101 N O6 91 C57 H101 N O6 92 C57 H103 N O6 94 C57 H103 N O6 95 C57 H103 N O6 96 C57 H105 N O6 98 C57 H105 N O6 99 C57 H105 N O6 100 C57 H107 N O6 101 C57 H107 N O6 102 C57 H107 N O6 103 C57 H107 N O6 105 C57 H109 N O6 106 C57 H111 N O6 107 C57 H111 N O6 108 C56 H99 N O6 109 C56 H101 N O6 110 C56 H101 N O6 111 C56 H103 N O6 112 C56 H103 N O6 113 C56 H105 N O6 114 C56 H105 N O6 115 C56 H107 N O6 116 C56 H107 N O6 117 C56 H107 N O6 118 C56 H109 N O6 119 C55 H95 N O6 120 C55 H97 N O6 121 C55 H99 N O6 123 C55 H101 N O6 124 C55 H101 N O6 125 C55 H103 N O6 126 C55 H103 N O6 129 C55 H109 N O6 130 C54 H97 N O6 131 C54 H99 N O6 132 C54 H101 N O6 133 C54 H103 N O6 134 C54 H105 N O6 135 C54 H107 N O6 136 C53 H93 N O6 137 C53 H95 N O6 138 C53 H97 N O6 139 C53 H97 N O6 145 C53 H105 N O6 146 C52 H97 N O6 147 C52 H99 N O6 148 C52 H99 N O6 149 C52 H101 N O6 150 C52 H103 N O6 151 C51 H95 N O6 152 C51 H97 N O6 153 C51 H99 N O6 154 C51 H101 N O6 155 C49 H93 N O6 156 C49 H95 N O6 157 C49 H97 N O6 158 C47 H89 N O6 159 C47 H91 N O6 160 C43 H79 N O6 161 C41 H77 N O6 162 C41 H79 N O6 163 C26 H45 N O6 S 164 C18 H37 N O2 165 C8 H20 N O6 P 199 C49 H83 N O2 200 C46 H76 N O10 P 201 C46 H78 N O10 P 202 C46 H78 N O10 P 203 C46 H80 N O10 P 204 C46 H82 N O10 P 205 C44 H78 N O10 P 206 C44 H80 N O10 P 207 C44 H80 N O10 P 208 C42 H78 N O10 P 209 C42 H80 N O10 P 212 C49 H88 N O13 P 219 C9 H11 N O2 221 C45 H76 N O7 P 222 C45 H78 N O7 P 223 C45 H78 N O7 P 224 C45 H78 N O7 P 225 C45 H78 N O7 P 226 C45 H78 N O7 P 227 C45 H80 N O7 P 228 C45 H80 N O7 P 229 C45 H80 N O7 P 230 C45 H82 N O7 P 231 C45 H82 N O7 P 232 C45 H84 N O7 P 233 C45 H84 N O7 P 234 C43 H74 N O7 P 235 C43 H76 N O7 P 236 C43 H78 N O7 P 237 C43 H78 N O7 P 238 C43 H78 N O7 P 239 C43 H78 N O7 P 240 C43 H80 N O7 P 241 C43 H80 N O7 P 242 C42 H76 N O7 P 243 C42 H76 N O7 P 244 C41 H74 N O7 P 245 C41 H74 N O7 P 246 C41 H76 N O7 P 247 C41 H78 N O7 P 248 C41 H76 N O7 P 249 C41 H80 N O7 P 250 C39 H76 N O7 P 251 C47 H78 N O8 P 252 C47 H78 N O8 P 253 C47 H78 N O8 P 254 C45 H74 N O8 P 255 C45 H76 N O8 P 256 C45 H76 N O8 P 257 C45 H76 N O8 P 258 C45 H76 N O8 P 259 C45 H78 N O8 P 260 C45 H78 N O8 P 261 C45 H80 N O8 P 262 C45 H80 N O8 P 263 C45 H80 N O8 P 264 C45 H80 N O8 P 265 C45 H80 N O8 P 266 C45 H82 N O8 P 267 C45 H82 N O8 P 268 C43 H74 N O8 P 269 C43 H74 N O8 P 270 C43 H74 N O8 P 271 C43 H76 N O8 P 272 C43 H76 N O8 P 273 C43 H78 N O8 P 274 C43 H78 N O8 P 275 C43 H78 N O8 P 276 C43 H80 N O8 P 277 C43 H80 N O8 P 278 C41 H72 N O8 P 279 C41 H72 N O8 P 280 C41 H72 N O8 P 281 C41 H72 N O8 P 282 C41 H74 N O8 P 283 C41 H74 N O8 P 284 C41 H74 N O8 P 285 C41 H76 N O8 P 286 C41 H78 N O8 P 287 C41 H78 N O8 P 288 C41 H80 N O8 P 289 C39 H74 N O8 P 290 C39 H76 N O8 P 291 C48 H84 N O7 P 292 C48 H86 N O7 P 293 C48 H86 N O7 P 294 C48 H86 N O7 P 295 C48 H90 N O7 P 296 C48 H90 N O7 P 297 C46 H82 N O7 P 298 C46 H82 N O7 P 299 C46 H84 N O7 P 300 C46 H84 N O7 P 301 C46 H86 N O7 P 302 C46 H86 N O7 P 303 C46 H86 N O7 P 304 C46 H86 N O7 P 305 C46 H90 N O7 P 306 C45 H82 N O7 P 307 C44 H80 N O7 P 309 C44 H82 N O7 P 310 C44 H82 N O7 P 311 C44 H84 N O7 P 312 C44 H86 N O7 P 313 C44 H88 N O7 P 314 C44 H90 N O7 P 315 C42 H82 N O7 P 316 C42 H84 N O7 P 317 C42 H84 N O7 P 318 C42 H86 N O7 P 319 C41 H84 N O7 P 320 C40 H82 N O7 P 321 C38 H78 N O7 P 322 C52 H88 N O8 P 323 C52 H94 N O8 P 324 C52 H96 N O8 P 325 C52 H80 N O8 P 326 C52 H84 N O8 P 327 C50 H82 N O8 P 328 C50 H82 N O8 P 329 C50 H84 N O8 P 330 C50 H86 N O8 P 331 C50 H86 N O8 P 332 C50 H88 N O8 P 333 C50 H88 N O8 P 334 C50 H88 N O8 P 335 C50 H88 N O8 P 336 C50 H90 N O8 P 337 C50 H90 N O8 P 338 C50 H90 N O8 P 339 C50 H92 N O8 P 340 C50 H92 N O8 P 341 C49 H84 N O8 P 342 C49 H86 N O8 P 343 C49 H86 N O8 P 344 C49 H86 N O8 P 345 C50 H80 N O8 P 346 C48 H80 N O8 P 347 C48 H82 N O8 P 348 C48 H82 N O8 P 349 C48 H84 N O8 P 350 C48 H86 N O8 P 351 C48 H86 N O8 P 352 C48 H86 N O8 P 353 C48 H86 N O8 P 354 C48 H88 N O8 P 355 C48 H88 N O8 P 356 C48 H88 N O8 P 357 C48 H92 N O8 P 358 C48 H92 N O8 P 359 C48 H94 N O8 P 360 C47 H82 N O8 P 361 C47 H82 N O8 P 362 C47 H82 N O8 P 363 C47 H82 N O8 P 364 C47 H82 N O8 P 365 C47 H82 N O8 P 366 C47 H84 N O8 P 367 C47 H84 N O8 P 368 C47 H84 N O8 P 369 C47 H86 N O8 P 370 C47 H86 N O8 P 371 C47 H88 N O8 P 372 C46 H78 N O8 P 373 C46 H80 N O8 P 374 C46 H80 N O8 P 375 C46 H82 N O8 P 376 C46 H82 N O8 P 377 C46 H82 N O8 P 378 C46 H82 N O8 P 379 C46 H82 N O8 P 380 C46 H84 N O8 P 381 C46 H84 N O8 P 382 C46 H84 N O8 P 383 C46 H86 N O8 P 384 C46 H86 N O8 P 385 C46 H88 N O8 P 386 C46 H90 N O8 P 387 C46 H92 N O8 P 388 C45 H78 N O8 P 389 C45 H78 N O8 P 390 C45 H78 N O8 P 391 C45 H82 N O8 P 392 C45 H82 N O8 P 393 C45 H84 N O8 P 394 C45 H84 N O8 P 395 C45 H84 N O8 P 396 C45 H86 N O8 P 397 C45 H86 N O8 P 398 C45 H88 N O8 P 399 C45 H88 N O8 P 400 C44 H76 N O8 P 401 C44 H76 N O8 P 402 C44 H78 N O8 P 403 C44 H78 N O8 P 404 C44 H78 N O8 P 405 C44 H78 N O8 P 406 C44 H78 N O8 P 407 C44 H80 N O8 P 408 C44 H80 N O8 P 409 C44 H82 N O8 P 410 C44 H82 N O8 P 411 C44 H82 N O8 P 412 C44 H84 N O8 P 413 C44 H84 N O8 P 414 C44 H86 N O8 P 415 C44 H88 N O8 P 416 C43 H78 N O8 P 417 C43 H78 N O8 P 418 C43 H80 N O8 P 419 C43 H82 N O8 P 420 C43 H84 N O8 P 421 C43 H86 N O8 P 422 C43 H86 N O8 P 423 C42 H76 N O8 P 424 C42 H76 N O8 P 425 C42 H78 N O8 P 426 C42 H78 N O8 P 427 C42 H80 N O8 P 428 C42 H82 N O8 P 429 C42 H84 N O8 P 430 C41 H76 N O8 P 431 C41 H80 N O8 P 432 C41 H82 N O8 P 433 C41 H82 N O8 P 434 C40 H74 N O8 P 435 C40 H74 N O8 P 436 C40 H76 N O8 P 437 C40 H78 N O8 P 438 C40 H78 N O8 P 439 C40 H80 N O8 P 440 C40 H80 N O8 P 441 C39 H76 N O8 P 442 C39 H78 N O8 P 443 C39 H78 N O8 P 444 C38 H74 N O8 P 445 C38 H76 N O8 P 446 C37 H74 N O8 P 448 C23 H46 N O7 P 449 C23 H48 N O7 P 450 C21 H44 N O7 P 451 C32 H66 N O7 P 452 C30 H50 N O7 P 453 C30 H62 N O7 P 454 C28 H50 N O7 P 455 C28 H56 N O7 P 456 C28 H58 N O7 P 457 C27 H56 N O7 P 458 C27 H56 N O7 P 459 C26 H50 N O7 P 460 C26 H52 N O7 P 461 C26 H54 N O7 P 462 C25 H52 N O7 P 463 C24 H48 N O7 P 464 C24 H50 N O7 P 465 C23 H48 N O7 P 466 C48 H93 N O8 467 C46 H89 N O8 468 C40 H77 N O8 469 C26 H43 N O6 471 C24 H49 N O2 472 C20 H41 N O2 473 C19 H39 N O2 474 C17 H35 N O2 475 C43 H73 N O5 478 C41 H71 N O5 480 C41 H75 N O5 481 C41 H77 N O5 485 C39 H73 N O5 487 C39 H75 N O5 488 C39 H77 N O5 489 C39 H77 N O5 490 C37 H71 N O5 491 C37 H73 N O5 492 C37 H75 N O5 493 C35 H69 N O5 497 C42 H83 N O4 498 C44 H83 N O3 499 C44 H85 N O3 500 C44 H87 N O3 501 C43 H83 N O3 502 C43 H85 N O3 503 C43 H85 N O3 504 C42 H79 N O3 505 C42 H81 N O3 506 C42 H81 N O3 507 C42 H83 N O3 508 C42 H83 N O3 509 C42 H85 N O3 510 C41 H79 N O3 511 C41 H81 N O3 512 C41 H83 N O3 513 C40 H77 N O3 514 C40 H77 N O3 515 C40 H79 N O3 516 C40 H81 N O3 517 C39 H77 N O3 518 C36 H71 N O3 519 C34 H67 N O3 520 C34 H69 N O3 521 C49 H79 N O2 522 C47 H77 N O2 523 C47 H79 N O2 526 C7 H15 N O3 527 C15 H29 N O4 528 C13 H25 N O4 529 C12 H23 N O4 530 C11 H21 N O5 531 C11 H21 N O4 532 C10 H19 N O4 533 C33 H63 N O4 534 C31 H59 N O4 535 C31 H61 N O4 536 C28 H51 N O4 537 C27 H45 N O4 538 C27 H49 N O4 539 C27 H51 N O4 540 C9 H17 N O4 541 C26 H51 N O4 542 C25 H43 N O4 543 C25 H45 N O4 544 C25 H47 N O5 545 C25 H47 N O4 546 C25 H49 N O5 547 C25 H49 N O4 548 C24 H45 N O4 549 C24 H47 N O4 550 C23 H41 N O4 551 C23 H43 N O4 552 C23 H45 N O4 553 C22 H43 N O4 554 C21 H37 N O4 555 C21 H39 N O4 556 C21 H41 N O4 557 C20 H37 N O4 558 C20 H39 N O4 559 C19 H35 N O4 560 C19 H37 N O4 561 C19 H37 N O4 562 C17 H33 N O4 Warning: The "refmet_name" column at position 5 in the METABOLITES table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "rt" column at position 6 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.