Validation Log 2025-12-15 01:08:34.838705 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004351/mwtab/json Study ID: ST002679 Analysis ID: AN004351 File format: json Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 5 Number of Value Errors: 8 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The required property, "COLLECTION_SUMMARY", in ["COLLECTION"] is missing. Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value, "0.45 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "55C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "mz" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "neutral_mass" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 3 C3 H7 N O3 6 C4 H9 N O3 7 C2 H7 N O3 S 11 C4 H7 N O4 16 C5 H9 N O4 17 C5 H9 N O4 22 C6 H11 N O2 S 23 C9 H11 N O2 26 C8 H15 N O3 29 C9 H9 N O3 30 C9 H11 N O3 32 C11 H9 N O2 35 C10 H7 N O3 41 C11 H11 N O3 42 C11 H13 N O3 82 C18 H38 N O5 P 91 C26 H43 N O5 92 C26 H43 N O5 93 C26 H43 N O5 94 C26 H43 N O5 95 C26 H43 N O6 96 C26 H43 N O6 97 C26 H45 N O6 S 98 C26 H45 N O6 S 99 C26 H45 N O6 S 100 C26 H45 N O6 S 101 C26 H45 N O7 S 102 C26 H45 N O7 S 103 C26 H45 N O7 S 104 C26 H45 N O7 S 105 C26 H45 N O7 S Warning: The "refmet_name" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "rt" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.