Validation Log 2025-12-15 01:08:59.575499 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004358/mwtab/json Study ID: ST002685 Analysis ID: AN004358 File format: json Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 5 Number of Value Errors: 8 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The required property, "COLLECTION_SUMMARY", in ["COLLECTION"] is missing. Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value, "0.4 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "50C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "mz" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "neutral_mass" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 C51 H92 D7 N O6 3 C38 H67 D7 N O8 P 4 C23 H39 D7 N O7 P 5 C41 H73 D7 N O8 P 6 C26 H45 D7 N O7 P 9 C45 H74 D7 N O2 10 C59 H95 N O4 11 C63 H117 N O6 14 C63 H119 N O6 15 C63 H105 N O6 16 C63 H105 N O6 17 C61 H103 N O6 19 C61 H103 N O6 21 C61 H105 N O6 22 C61 H105 N O6 23 C61 H107 N O6 25 C61 H107 N O6 26 C61 H107 N O6 27 C61 H107 N O6 28 C61 H109 N O6 29 C61 H109 N O6 31 C61 H109 N O6 32 C61 H109 N O6 33 C61 H111 N O6 34 C61 H111 N O6 36 C61 H113 N O6 37 C61 H113 N O6 38 C61 H113 N O6 39 C61 H113 N O6 40 C61 H115 N O6 42 C61 H117 N O6 43 C61 H99 N O6 44 C61 H99 N O6 46 C61 H119 N O6 47 C60 H111 N O6 48 C60 H111 N O6 49 C60 H113 N O6 50 C60 H115 N O6 51 C60 H117 N O6 52 C59 H99 N O6 55 C59 H101 N O6 56 C59 H103 N O6 57 C59 H103 N O6 58 C59 H103 N O6 59 C59 H103 N O6 60 C59 H105 N O6 61 C59 H105 N O6 62 C59 H105 N O6 63 C59 H105 N O6 66 C59 H107 N O6 67 C59 H109 N O6 68 C59 H109 N O6 69 C59 H109 N O6 70 C59 H109 N O6 71 C59 H111 N O6 73 C59 H97 N O6 75 C58 H101 N O6 76 C58 H101 N O6 77 C58 H105 N O6 79 C58 H107 N O6 80 C58 H109 N O6 81 C58 H109 N O6 82 C58 H109 N O6 84 C58 H113 N O6 85 C57 H97 N O6 86 C57 H97 N O6 87 C57 H99 N O6 89 C57 H99 N O6 90 C57 H99 N O6 91 C57 H101 N O6 92 C57 H101 N O6 96 C57 H103 N O6 97 C57 H103 N O6 98 C57 H103 N O6 99 C57 H105 N O6 100 C57 H105 N O6 101 C57 H105 N O6 102 C57 H105 N O6 103 C57 H107 N O6 105 C57 H107 N O6 107 C57 H109 N O6 108 C57 H111 N O6 109 C57 H111 N O6 110 C56 H99 N O6 111 C56 H99 N O6 112 C56 H99 N O6 115 C56 H103 N O6 116 C56 H105 N O6 118 C56 H105 N O6 119 C56 H107 N O6 121 C56 H109 N O6 122 C55 H95 N O6 125 C55 H99 N O6 126 C55 H99 N O6 127 C55 H99 N O6 128 C55 H101 N O6 131 C55 H103 N O6 132 C55 H103 N O6 134 C55 H105 N O6 136 C55 H105 N O6 137 C55 H107 N O6 138 C54 H97 N O6 140 C54 H101 N O6 142 C54 H103 N O6 143 C54 H105 N O6 144 C53 H89 N O6 145 C53 H91 N O6 146 C53 H93 N O6 147 C53 H93 N O6 148 C53 H93 N O6 150 C53 H97 N O6 151 C53 H97 N O6 152 C53 H99 N O6 153 C53 H99 N O6 157 C53 H103 N O6 158 C52 H95 N O6 159 C52 H97 N O6 160 C52 H99 N O6 162 C51 H89 N O6 163 C51 H91 N O6 164 C51 H93 N O6 165 C51 H93 N O6 166 C51 H93 N O6 167 C51 H95 N O6 168 C51 H95 N O6 170 C51 H97 N O6 173 C49 H85 N O6 174 C49 H85 N O6 175 C49 H87 N O6 176 C49 H89 N O6 177 C49 H91 N O6 179 C49 H95 N O6 181 C48 H89 N O6 182 C48 H91 N O6 183 C47 H85 N O6 185 C47 H89 N O6 187 C47 H91 N O6 188 C47 H91 N O6 189 C46 H87 N O6 191 C45 H79 N O6 192 C45 H81 N O6 193 C45 H83 N O6 194 C45 H85 N O6 195 C45 H87 N O6 196 C45 H87 N O6 197 C45 H89 N O6 198 C44 H81 N O6 199 C44 H83 N O6 200 C43 H75 N O6 202 C43 H79 N O6 203 C43 H81 N O6 205 C43 H81 N O6 206 C43 H83 N O6 207 C43 H83 N O6 209 C43 H85 N O6 210 C43 H85 N O6 211 C42 H79 N O6 212 C42 H81 N O6 213 C42 H81 N O6 217 C41 H77 N O6 220 C41 H81 N O6 221 C41 H81 N O6 222 C39 H71 N O6 224 C39 H73 N O6 225 C39 H75 N O6 227 C39 H77 N O6 228 C39 H77 N O6 229 C39 H77 N O6 230 C37 H73 N O6 231 C8 H20 N O6 P 266 C46 H76 N O10 P 267 C46 H78 N O10 P 268 C46 H78 N O10 P 269 C46 H78 N O10 P 270 C46 H80 N O10 P 271 C46 H80 N O10 P 272 C46 H82 N O10 P 273 C44 H78 N O10 P 274 C44 H78 N O10 P 275 C44 H80 N O10 P 276 C44 H80 N O10 P 277 C42 H78 N O10 P 278 C42 H78 N O10 P 279 C42 H80 N O10 P 286 C45 H76 N O7 P 287 C45 H78 N O7 P 288 C45 H78 N O7 P 289 C45 H78 N O7 P 290 C45 H80 N O7 P 291 C45 H80 N O7 P 292 C45 H80 N O7 P 293 C45 H82 N O7 P 294 C45 H82 N O7 P 295 C45 H84 N O7 P 296 C43 H74 N O7 P 297 C43 H76 N O7 P 298 C43 H76 N O7 P 299 C43 H78 N O7 P 300 C43 H78 N O7 P 301 C43 H78 N O7 P 302 C43 H80 N O7 P 303 C43 H80 N O7 P 304 C43 H84 N O7 P 305 C42 H76 N O7 P 306 C42 H76 N O7 P 307 C41 H74 N O7 P 308 C41 H74 N O7 P 309 C41 H78 N O7 P 310 C41 H78 N O7 P 311 C41 H76 N O7 P 312 C41 H80 N O7 P 313 C39 H76 N O7 P 314 C39 H78 N O7 P 315 C39 H78 N O7 P 316 C49 H74 N O8 P 317 C49 H74 N O8 P 318 C49 H78 N O8 P 319 C49 H78 N O8 P 320 C47 H78 N O8 P 321 C47 H78 N O8 P 322 C47 H74 N O8 P 323 C47 H74 N O8 P 324 C45 H74 N O8 P 325 C45 H76 N O8 P 326 C45 H76 N O8 P 327 C45 H78 N O8 P 328 C45 H78 N O8 P 329 C45 H78 N O8 P 330 C45 H80 N O8 P 331 C45 H80 N O8 P 332 C45 H80 N O8 P 333 C45 H80 N O8 P 334 C45 H80 N O8 P 335 C45 H82 N O8 P 336 C45 H82 N O8 P 337 C45 H82 N O8 P 338 C43 H74 N O8 P 339 C43 H74 N O8 P 340 C43 H74 N O8 P 341 C43 H76 N O8 P 342 C43 H76 N O8 P 343 C43 H76 N O8 P 344 C43 H76 N O8 P 345 C43 H78 N O8 P 346 C43 H78 N O8 P 347 C43 H80 N O8 P 348 C43 H80 N O8 P 349 C43 H80 N O8 P 350 C41 H72 N O8 P 351 C41 H72 N O8 P 352 C41 H72 N O8 P 353 C41 H72 N O8 P 354 C41 H74 N O8 P 355 C41 H74 N O8 P 356 C41 H74 N O8 P 357 C41 H76 N O8 P 358 C41 H78 N O8 P 359 C41 H78 N O8 P 360 C41 H80 N O8 P 361 C39 H74 N O8 P 362 C39 H76 N O8 P 363 C48 H84 N O7 P 364 C48 H84 N O7 P 365 C48 H84 N O7 P 366 C48 H86 N O7 P 367 C48 H86 N O7 P 368 C48 H90 N O7 P 369 C46 H80 N O7 P 370 C46 H80 N O7 P 371 C46 H82 N O7 P 372 C46 H82 N O7 P 373 C46 H82 N O7 P 374 C46 H84 N O7 P 375 C46 H84 N O7 P 376 C46 H84 N O7 P 377 C46 H86 N O7 P 378 C46 H86 N O7 P 379 C46 H86 N O7 P 380 C44 H80 N O7 P 382 C44 H82 N O7 P 383 C44 H84 N O7 P 384 C44 H86 N O7 P 385 C44 H86 N O7 P 386 C44 H88 N O7 P 387 C42 H82 N O7 P 388 C42 H86 N O7 P 389 C41 H84 N O7 P 390 C40 H80 N O7 P 391 C40 H80 N O7 P 392 C40 H82 N O7 P 393 C38 H78 N O7 P 394 C52 H94 N O8 P 395 C50 H82 N O8 P 396 C50 H82 N O8 P 397 C50 H84 N O8 P 398 C50 H86 N O8 P 399 C50 H88 N O8 P 400 C50 H90 N O8 P 401 C50 H92 N O8 P 402 C50 H98 N O8 P 403 C50 H80 N O8 P 404 C48 H80 N O8 P 405 C48 H82 N O8 P 406 C48 H82 N O8 P 407 C48 H84 N O8 P 408 C48 H86 N O8 P 409 C48 H86 N O8 P 410 C48 H86 N O8 P 411 C48 H88 N O8 P 412 C48 H88 N O8 P 413 C48 H92 N O8 P 414 C48 H94 N O8 P 415 C48 H96 N O8 P 416 C47 H82 N O8 P 417 C47 H82 N O8 P 418 C47 H82 N O8 P 419 C47 H84 N O8 P 420 C47 H84 N O8 P 421 C47 H84 N O8 P 422 C47 H84 N O8 P 423 C47 H86 N O8 P 424 C47 H88 N O8 P 425 C46 H78 N O8 P 426 C46 H78 N O8 P 427 C46 H80 N O8 P 428 C46 H80 N O8 P 429 C46 H82 N O8 P 430 C46 H82 N O8 P 431 C46 H84 N O8 P 432 C46 H86 N O8 P 433 C46 H86 N O8 P 434 C46 H88 N O8 P 435 C46 H90 N O8 P 436 C46 H92 N O8 P 437 C45 H78 N O8 P 438 C45 H82 N O8 P 439 C45 H82 N O8 P 440 C45 H84 N O8 P 441 C45 H86 N O8 P 442 C45 H86 N O8 P 443 C45 H88 N O8 P 444 C45 H88 N O8 P 445 C44 H78 N O8 P 446 C44 H78 N O8 P 447 C44 H78 N O8 P 448 C44 H80 N O8 P 449 C44 H80 N O8 P 450 C44 H82 N O8 P 451 C44 H82 N O8 P 452 C44 H82 N O8 P 453 C44 H84 N O8 P 454 C44 H84 N O8 P 455 C44 H86 N O8 P 456 C44 H88 N O8 P 457 C43 H78 N O8 P 458 C43 H78 N O8 P 459 C43 H80 N O8 P 460 C43 H82 N O8 P 461 C43 H82 N O8 P 462 C43 H84 N O8 P 463 C43 H86 N O8 P 464 C43 H86 N O8 P 465 C43 H86 N O8 P 466 C42 H76 N O8 P 467 C42 H78 N O8 P 468 C42 H78 N O8 P 469 C42 H78 N O8 P 470 C42 H80 N O8 P 471 C42 H82 N O8 P 472 C42 H84 N O8 P 473 C41 H78 N O8 P 474 C41 H80 N O8 P 475 C41 H82 N O8 P 476 C40 H76 N O8 P 477 C40 H78 N O8 P 478 C40 H78 N O8 P 479 C40 H80 N O8 P 480 C40 H80 N O8 P 481 C39 H78 N O8 P 482 C38 H76 N O8 P 483 C37 H74 N O8 P 484 C23 H46 N O6 P 485 C23 H46 N O7 P 486 C23 H48 N O7 P 487 C21 H44 N O7 P 488 C30 H50 N O7 P 489 C28 H50 N O7 P 490 C28 H56 N O7 P 491 C28 H58 N O7 P 492 C27 H56 N O7 P 493 C26 H50 N O7 P 494 C26 H52 N O7 P 495 C26 H54 N O7 P 496 C25 H52 N O7 P 497 C24 H48 N O7 P 498 C24 H50 N O7 P 499 C23 H48 N O7 P 500 C48 H91 N O8 501 C48 H93 N O9 502 C46 H87 N O8 503 C46 H89 N O8 504 C46 H89 N O8 505 C40 H77 N O8 506 C22 H43 N O 507 C43 H75 N O5 514 C41 H77 N O5 515 C39 H69 N O5 516 C39 H71 N O5 517 C39 H73 N O5 518 C39 H73 N O5 519 C39 H75 N O5 520 C39 H75 N O5 521 C39 H77 N O5 529 C34 H65 N O2 530 C44 H85 N O3 531 C43 H83 N O3 532 C43 H85 N O3 533 C42 H79 N O3 534 C42 H81 N O3 535 C42 H81 N O3 536 C42 H83 N O3 537 C41 H79 N O3 538 C41 H81 N O3 539 C40 H77 N O3 540 C36 H69 N O2 541 C34 H67 N O3 542 C34 H69 N O3 543 C7 H15 N O3 544 C15 H29 N O4 545 C13 H25 N O4 546 C11 H21 N O5 547 C11 H21 N O4 548 C10 H19 N O4 549 C29 H49 N O4 550 C28 H51 N O4 551 C27 H45 N O4 552 C27 H49 N O4 553 C27 H51 N O4 554 C9 H17 N O4 555 C25 H45 N O4 556 C25 H47 N O5 557 C25 H47 N O4 558 C25 H49 N O5 559 C25 H49 N O4 560 C23 H41 N O5 561 C23 H41 N O4 562 C23 H43 N O4 563 C23 H43 N O4 564 C23 H45 N O5 565 C23 H45 N O4 566 C21 H37 N O4 567 C21 H39 N O5 568 C21 H39 N O4 569 C21 H41 N O5 570 C21 H41 N O4 571 C19 H35 N O4 572 C19 H37 N O4 573 C17 H31 N O4 574 C17 H33 N O4 Warning: The "refmet_name" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "rt" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.