Validation Log 2025-12-15 01:09:13.512815 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004362/mwtab/json Study ID: ST002689 Analysis ID: AN004362 File format: json Status: Contains Validation Issues Number of Issues: 13 Number of Warnings: 9 Number of Value Errors: 12 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The required property, "COLLECTION_SUMMARY", in ["COLLECTION"] is missing. Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value, "0.25 ml/min; 0.4 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "35C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "mz" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "neutral_mass" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 C3 H7 N O2 3 C3 H7 N O3 4 C5 H9 N O2 6 C5 H11 N O2 8 C4 H9 N O3 9 C2 H7 N O3 S 11 C6 H13 N O2 12 C6 H13 N O2 13 C6 H13 N O2 16 C4 H7 N O4 20 C5 H9 N O4 21 C5 H11 N O2 S 24 C9 H11 N O2 31 C9 H11 N O3 37 C9 H17 N O5 47 C8 H16 N O9 P Warning: The "refmet_name" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "rt" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CS00000SB-02" column at position 65 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "CS00000SB-03" column at position 66 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "CS00000SB-04" column at position 67 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "CS00000SB-05" column at position 68 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.