Validation Log
2025-12-15 01:09:27.186854
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004366/mwtab/json
Study ID:      ST002693
Analysis ID:   AN004366
File format:   json
Status: Contains Validation Issues
Number of Issues: 10

Number of Warnings: 5

Number of Value Errors: 8

Number of Consistency Errors: 1

Number of Format Errors: 1

Issue Log:
Error: The required property, "COLLECTION_SUMMARY", in ["COLLECTION"] is missing.
Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key.
Error: The value, "0.45 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "55C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"alanine-13C3"
	"aspartate-13C4"
	"glutamate-13C5"
	"glutamine-13C5"
	"histidine-13C6"
	"serine-13C3"
	"lactate-13C3"
	"lysine-13C6"
	"malate-13C4"
	"threonine-13C4"
	"asparagine-15N2"
	"valine-13C5"
	"citric acid-13C6"
	"tyrosine-13C9"
	"isoleucine-13C6"
	"isoleucine-13C6+leucine-13C6"
	"leucine-13C6"
	"phenylalanine-13C9"
	"tryptophan-15N2"
	"anthranilic acid-15N"
	"gibberellic acid"
	"epibrassinolide+HCOOH"
Warning: The "mz" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "neutral_mass" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
3         C3 H7 N O3
6         C4 H9 N O3
7       C2 H7 N O3 S
11        C4 H7 N O4
14        C5 H9 N O4
17     C6 H11 N O2 S
18       C9 H11 N O2
22       C8 H15 N O3
25        C9 H9 N O3
26       C9 H11 N O3
28       C11 H9 N O2
31       C10 H7 N O3
32       C10 H9 N O3
37      C11 H11 N O3
38      C11 H13 N O3
76    C18 H38 N O5 P
85      C26 H43 N O5
86      C26 H43 N O5
87      C26 H43 N O6
88      C26 H43 N O6
89    C26 H45 N O7 S
90    C26 H45 N O7 S
91    C26 H45 N O7 S
92    C26 H45 N O7 S
Warning: The "refmet_name" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "rt" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.