Validation Log 2025-12-15 01:09:45.440265 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004372/mwtab/json Study ID: ST002698 Analysis ID: AN004372 File format: json Status: Contains Validation Issues Number of Issues: 27 Number of Warnings: 11 Number of Value Errors: 23 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "NA", in ["SUBJECT"]["AGE_OR_AGE_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: The value, "NA", in ["SUBJECT"]["WEIGHT_OR_WEIGHT_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['g', 'mg', 'kg', 'lbs']. Ignore this when more complicated descriptions are required. Error: The value, "NA", in ["SUBJECT"]["HEIGHT_OR_HEIGHT_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['cm', 'in']. Ignore this when more complicated descriptions are required. Error: The value, "Not applicable", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLE_RESUSPENSION"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLE_DERIVATIZATION"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: An empty value or a null value was detected in ["MS"]["COLLISION_ENERGY"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "NA", in ["MS"]["COLLISION_GAS"] should be one of "Nitrogen" or "Argon". Ignore this when more complicated descriptions are required. Error: The value, "50", in ["MS"]["DRY_GAS_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required. Error: The value, "120", in ["MS"]["DRY_GAS_TEMP"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "0.3 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "60 bar at starting conditions. 180 bar at %A", in ["CHROMATOGRAPHY"]["COLUMN_PRESSURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['psi', 'bar']. Ignore this when more complicated descriptions are required. Error: The value, "50% IPA", in ["CHROMATOGRAPHY"]["STRONG_WASH_VOLUME"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "1_6_8-trimethylallantoate" "(1R_2R)-2-amino-1-(4-aminophenyl)propane-1_3-diol" "2_3-Diaminosalicylic acid" "2_7-Anhydro-alpha-N-acetylneuraminic acid" "2-{[hydroxy(4-hydroxy-3_5-dimethoxyphenyl)methylidene]amino}acetic acid" "2^-hydroxypyridoxol" "3_4_5-trihydroxy-6-[(3-methoxy-3-oxopropanoyl)oxy]oxane-2-carboxylic acid" "5-Methyl-2^-deoxycytidine" "6-[4-(5_7-dihydroxy-6-{4-hydroxy-6-methyl-5-oxo-3-[(3_4_5-trihydroxy-6-methyloxan-2-yl)oxy]oxan-2-yl}-4-oxo-4H-chromen-2-yl)phenoxy]-3_4_5-trihydroxyoxane-2-carboxylic acid" "6-Acetyl-1_2_3_4-tetrahydropyridine" "(alpha-keto-dimethyl-delta-N_N-Dimethylguanidynol) valeric acid" "D_D-diaminopimelate" "N6_N6_N6-Trimethyl-L-lysine" "Ne_Ne dimethyllysine" "N_N^-Diacetylchitobiosyldiphosphodolichol" "p-nitroso-N_N-dimethylaniline" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "1,6,8-trimethylallantoate" "(1R,2R)-2-amino-1-(4-aminophenyl)propane-1,3-diol" "2,3-Diaminosalicylic acid" "2,7-Anhydro-alpha-N-acetylneuraminic acid" "2-{[hydroxy(4-hydroxy-3,5-dimethoxyphenyl)methylidene]amino}acetic acid" "2'-hydroxypyridoxol" "3,4,5-trihydroxy-6-[(3-methoxy-3-oxopropanoyl)oxy]oxane-2-carboxylic acid" "5-Methyl-2'-deoxycytidine" "6-[4-(5,7-dihydroxy-6-{4-hydroxy-6-methyl-5-oxo-3-[(3,4,5-trihydroxy-6-methyloxan-2-yl)oxy]oxan-2-yl}-4-oxo-4H-chromen-2-yl)phenoxy]-3,4,5-trihydroxyoxane-2-carboxylic acid" "6-Acetyl-1,2,3,4-tetrahydropyridine" "(alpha-keto-dimethyl-delta-N,N-Dimethylguanidynol) valeric acid" "D,D-diaminopimelate" "N6,N6,N6-Trimethyl-L-lysine" "Ne,Ne dimethyllysine" "N,N'-Diacetylchitobiosyldiphosphodolichol" "p-nitroso-N,N-dimethylaniline" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.