Validation Log 2025-12-15 01:25:38.471690 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004599/mwtab/json Study ID: ST002822 Analysis ID: AN004599 File format: json Status: Contains Validation Issues Number of Issues: 15 Number of Warnings: 10 Number of Value Errors: 15 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["FLOW_GRADIENT"]. A legitimate value should be provided for this required key. Error: The value, "-", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "-", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_A"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_B"]. A legitimate value should be provided for this required key. Warning: The "INCHIKEY" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "inchi_key". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "INCHIKEY" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "inchi_key", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 3 ZHCKPJGJQOPTLB-UHFFFAOYAW 4 UJCGYTCAMOHYCG-UHFFFAOYAA 5 VJQCNCOGZPSOQZ-UHFFFAOYAR 6 FHQDWPCFSJMNCT-UHFFFAOYAR 7 LDHMAVIPBRSVRG-UHFFFAOYAE 8 AHPWEWASPTZMEK-UHFFFAOYAY 9 RDFMDVXONNIGBC-UHFFFAOYAG 10 OLXZPDWKRNYJJZ-RRKCRQDMBK 11 CKTSBUTUHBMZGZ-SHYZEUOFBO 12 IHCPDBBYTYJYIL-UHFFFAOYAT 13 XROYFEWIXXCPAW-UHFFFAOYAB 14 ARBHXJXXVVHMET-UHFFFAOYAC 15 YCCMTCQQDULIFE-UHFFFAOYAX 16 QCHPKSFMDHPSNR-UHFFFAOYAN 17 OLNJUISKUQQNIM-UHFFFAOYAL 22 JSJWCHRYRHKBBW-UHFFFAOYAH 23 TUHVEAJXIMEOSA-UHFFFAOYAM 24 HBDWQSHEVMSFGY-SCQFTWEKBW 25 PRJKNHOMHKJCEJ-UHFFFAOYAF 26 JJMDCOVWQOJGCB-UHFFFAOYAD 27 YSMODUONRAFBET-UHFFFAOYAX 28 WUUGFSXJNOTRMR-IOSLPCCCBD 29 RDHQFKQIGNGIED-MRVPVSSYBU 31 GFFGJBXGBJISGV-UHFFFAOYAT 32 OIRDTQYFTABQOQ-KQYNXXCUBX 33 UDMBCSSLTHHNCD-RWLQFSFNBF 34 4000 35 QNAYBMKLOCPYGJ-REOHCLBHBS 36 RDIKFPRVLJLMER-UHFFFAOYAD 37 MYYIAHXIVFADCU-QMMMGPOBBJ 38 ODKSFYDXXFIFQN-UHFFFAOYAT 39 CIWBSHSKHKDKBQ-JLAZNSOCBT 40 DCXYFEDJOCDNAF-REOHCLBHBD 41 CKLJMWTZIZZHCS-REOHCLBHBW 43 UCMIRNVEIXFBKS-UHFFFAOYAL 44 IGLHHSKNBDXCEY-UHFFFAOYAG 45 KWIUHFFTVRNATP-UHFFFAOYAI 47 QWYFHHGCZUCMBN-SECBINFHBA 48 PHIQHXFUZVPYII-ZCFIWIBFBS 49 CQOVPNPJLQNMDC-ZETCQYMHBX 50 CPXSBHKDEPPWIX-RAYCSJGIBM 51 CRBHXDCYXIISFC-UHFFFAOYAW 52 YHHSONZFOIEMCP-UHFFFAOYAD 53 RHGKLRLOHDJJDR-UHFFFAOYAQ 54 CVSVTCORWBXHQV-UHFFFAOYAV 55 DDRJAANPRJIHGJ-UHFFFAOYAV 56 ILRYLPWNYFXEMH-UHFFFAOYAH 57 XUJNEKJLAYXESH-REOHCLBHBU 58 BNRXZEPOHPEEAS-UHFFFAOYAL 59 ZUKPVRWZDMRIEO-UHFFFAOYAS 60 UHDGCWIWMRVCDJ-XVFCMESIBD 61 IERHLVCPSMICTF-FHLVPPQOBD 62 OPTASPLRGRRNAP-UHFFFAOYAY 63 JHPNVNIEXXLNTR-UHFFFAOYAL 64 GNGACRATGGDKBX-NUQVWONBAJ 65 HHVIBTZHLRERCL-UHFFFAOYAG 66 YDGMGEXADBMOMJ-LURJTMIEBT 67 FFDGPVCHZBVARC-UHFFFAOYAX 68 SSISHJJTAXXQAX-UHFFFAOYAO 69 BFSYFTQDGRDJNV-QCNRFFRDBO 70 LNLLNTMHVMIMOG-YUMQZZPRBS 71 JPKNLFVGUZRHOB-YUMQZZPRBM 72 OWQDWQKWSLFFFR-WDSKDSINBR 73 JBFYFLXEJFQWMU-WDSKDSINBP 74 MYFMARDICOWMQP-YUMQZZPRBM 75 GWNXFCYUJXASDX-JUZNGCLZBW 76 SITLTJHOQZFJGG-UUEFVBAFBQ 77 WHUUTDBJXJRKMK-UHFFFAOYAD 78 ZGEYCCHDTIDZAE-UHFFFAOYAN 79 ZDXPYRJPNDTMRX-VKHMYHEABV 80 YPZRWBKMTBYPTK-BJDJZHNGBD 81 RWSXRVCMGQZWBV-WDSKDSINBK 82 SUHOQUVVVLNYQR-MRVPVSSYBR 83 ZWZWYGMENQVNFU-AKGZTFGVBY 84 DHMQDGOQFOQNFH-UHFFFAOYAW 85 DKEXFJVMVGETOO-LURJTMIEBJ 86 STKYPAFSDFAEPH-LURJTMIEBB 87 BPMFZUMJYQTVII-UHFFFAOYAQ 88 UYTPUPDQBNUYGX-UHFFFAOYAE 89 NYHBQMYGNKIUIF-UUOKFMHZBU 90 NTYJJOPFIAHURM-UHFFFAOYAP 91 GPPYTCRVKHULJH-UHFFFAOYAG 92 BXRMEWOQUXOLDH-LURJTMIEBZ 93 XULZWQRXYTVUTE-ZETCQYMHBF 95 ACZFBYCNAVEFLC-YFKPBYRVBI 96 ZCKYOWGFRHAZIQ-UHFFFAOYAI 97 GRSZFWQUAKGDAV-RWLQFSFNBK 99 AGPKZVBTJJNPAG-UHFFFAOYAW 100 YGPSJZOEDVAXAB-QMMMGPOBBJ 102 HSQGMTRYSIHDAC-UHFFFAOYAG 103 JYOAXOMPIXKMKK-UHFFFAOYAJ 104 LESXFEZIFXFIQR-UHFFFAOYAD 105 KDXKERNSBIXSRK-YFKPBYRVBE 106 ZGNBLKBZJBJFDG-UHFFFAOYAY 107 FFEARJCKVFRZRR-BYPYZUCNBW 108 QEFRNWWLZKMPFJ-YGVKFDHGBW 109 CDLVFVFTRQPQFU-UHFFFAOYAF 111 QCYOIFVBYZNUNW-BYPYZUCNBG 113 QQBGTSSELNKRID-IOSLPCCCBM 114 MXNRLFUSFKVQSK-UHFFFAOYAO 115 XXEWFEBMSGLYBY-ZETCQYMHBT 116 NUXSIDPKKIEIMI-UHFFFAOYAH 117 PQNASZJZHFPQLE-LURJTMIEBL 118 SNEIUMQYRCDYCH-LURJTMIEBE 119 HXFOXFJUNFFYMO-BYPYZUCNBZ 120 OPVPGKGADVGKTG-UHFFFAOYAF 121 YTTRPBWEMMPYSW-VFFCQLMOBE 122 KSMRODHGGIIXDV-YFKPBYRVBV 123 KBOJOGQFRVVWBH-ZETCQYMHBN 124 NPIMMZJBURSMON-UHFFFAOYAA 125 KBGAYAKRZNYFFG-BOHATCBPBL 126 KLZGKIDSEJWEDW-UHFFFAOYAE 127 JJIHLJJYMXLCOY-BYPYZUCNBM 128 DFPAKSUCGFBDDF-UHFFFAOYAZ 129 USSFUVKEHXDAPM-UHFFFAOYAT 130 DAYLJWODMCOQEW-TURQNECABR 132 CWLQUGTUXBXTLF-UHFFFAOYAJ 133 NTNWOCRCBQPEKQ-YFKPBYRVBT 134 MWZPENIJLUWBSY-UHFFFAOYAX 135 JCMUOFQHZLPHQP-UHFFFAOYAD 136 AHLPHDHHMVZTML-BYPYZUCNBZ 138 ZNXZGRMVNNHPCA-VIFPVBQEBP 139 UTYVDVLMYQPLQB-UHFFFAOYAZ 140 COLNVLDHVKWLRT-QMMMGPOBBC 141 MIDZLCFIAINOQN-WPRPVWTQBF 142 GLUBLISJVJFHQS-UHFFFAOYAD 144 ONPXCLZMBSJLSP-ALKRTJFJBT 145 ONIBWKKTOPOVIA-BYPYZUCNBZ 146 RNKSNIBMTUYWSH-YFKPBYRVBZ 147 UFAHZIUFPNSHSL-UHFFFAOYAT 148 KIDHWZJUCRJVML-UHFFFAOYAX 149 NHZMQXZHNVQTQA-UHFFFAOYAS 150 ZMJGSOSNSPKHNH-UHFFFAOYAM 152 MTCFGRXMJLQNBG-REOHCLBHBX 153 QZAYGJVTTNCVMB-UHFFFAOYAX 154 ATHGHQPFGPMSJY-UHFFFAOYAK 155 PFNFFQXMRSDOHW-UHFFFAOYAC 156 CMUNUTVVOOHQPW-LURJTMIEBI 158 XOAAWQZATWQOTB-UHFFFAOYAA 159 JKLRIMRKZBSSED-UHFFFAOYAU 161 DZLNHFMRPBPULJ-VKHMYHEABX 162 AYFVYJQAPQTCCC-GBXIJSLDBG 163 WURBQCVBQNMUQT-RMKNXTFCBN 164 PMMYEEVYMWASQN-DMTCNVIQBF 165 SEQKRHFRPICQDD-UHFFFAOYAK 166 GSEJCLTVZPLZKY-UHFFFAOYAL 167 WWNNZCOKKKDOPX-UHFFFAOYAV 168 UYPYRKYUKCHHIB-UHFFFAOYAU 169 PIEPQKCYPFFYMG-UHFFFAOYAE 170 QIVBCDIJIAJPQS-VIFPVBQEBP 171 OUYCCCASQSFEME-QMMMGPOBBZ 172 XSQUKJJJFZCRTK-UHFFFAOYAF 173 KZSNJWFQEVHDMF-BYPYZUCNBW 200 LRFVTYWOQMYALW-UHFFFAOYAT Warning: The "SUPER_PATHWAY" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pathway". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "SUB_PATHWAY" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pathway". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PUBCHEM" column at position 12 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 11 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CHEMSPIDER" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "chemspider_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 16 214139-20-5,10569-72-9 23 463-003,463-00-3 43 107-95-9,56-41-7 57 56-89-3,52-90-4 78 1499-55-4,1499-55-4 151 86867-01-8,24346-00-7,86867-0108