Validation Log 2025-12-15 01:40:28.169007 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004802/mwtab/txt Study ID: ST002928 Analysis ID: AN004802 File format: txt Status: Contains Validation Issues Number of Issues: 88 Number of Warnings: 76 Number of Value Errors: 87 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "Male and female", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the "RAW_FILE_NAME" in "Additional sample data" in entry 11 of the "SUBJECT_SAMPLE_FACTORS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the "RAW_FILE_NAME" in "Additional sample data" in entry 18 of the "SUBJECT_SAMPLE_FACTORS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the "RAW_FILE_NAME" in "Additional sample data" in entry 31 of the "SUBJECT_SAMPLE_FACTORS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the "RAW_FILE_NAME" in "Additional sample data" in entry 36 of the "SUBJECT_SAMPLE_FACTORS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the "RAW_FILE_NAME" in "Additional sample data" in entry 41 of the "SUBJECT_SAMPLE_FACTORS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the "RAW_FILE_NAME" in "Additional sample data" in entry 44 of the "SUBJECT_SAMPLE_FACTORS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the "RAW_FILE_NAME" in "Additional sample data" in entry 60 of the "SUBJECT_SAMPLE_FACTORS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the "RAW_FILE_NAME" in "Additional sample data" in entry 63 of the "SUBJECT_SAMPLE_FACTORS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "0.28 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "45", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: Unknown or invalid section, "FACTORS". Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #41 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #42 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #43 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #44 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #45 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #46 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #47 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #48 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #49 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #50 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #51 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #52 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #53 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #54 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #55 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #56 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #57 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #58 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #59 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #60 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #61 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #62 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #63 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #64 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #65 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #66 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #67 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #68 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #69 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #70 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #71 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #72 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #73 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #74 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #75 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #76 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME"