Validation Log
2025-12-15 01:43:32.605231
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004853/mwtab/txt
Study ID:      ST002956
Analysis ID:   AN004853
File format:   txt
Status: Contains Validation Issues
Number of Issues: 15

Number of Warnings: 11

Number of Value Errors: 12

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: The value, "8wks and 32 wks", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required.
Error: The value, "35", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"GcGM2(34:1_2-OH)_16.791_[M-H]-_209"
	"GcGM2(34:1_2-OH)_17.931_[M+Na]+_3647"
	"GcGM2(36:1_2-OH)_18.771_[M-H]-_232"
	"GcGM2(38:1_2-OH)_23.658_[M+Na]+_4553"
	"GcGM2(40:1_2-OH)_24.985_[M-H]-_100"
	"GcGM2(40:1_2-OH)_29.306_[M+Na]+_4095"
	"GcGM2(42:1_2-OH)_34.35_[M+Na]+_4173"
	"GcGM2(42:2_2-OH)_28.02_[M+Na]+_4078"
	"LacCer(34:2_2-OH)_17.807_[M+Na]+_3644"
	"LacCer(34:2_3-OH)_17.309_[M+Na]+_3630"
	"PE(18:1e/11_12-EET)_20.811_[M-H]-_280"
	"PE(18:2e/16_17-EpDPE)_20.26_[M-H]-_278"
	"SM(32:1_2-OH)_17.163_[M+FA-H]-_130"
	"SM(32:1_2-OH)_18.217_[M+K]+_3659"
	"SM(32:1_3-OH)_17.324_[M+H]+_3632"
	"SM(34:0_3-OH)_18.023_[M+FA-H]-_225"
	"SM(34:0_3-OH)_19.317_[M+H]+_3725"
	"SM(34:1_2-OH)_20.389_[M+H]+_3795"
	"SM(34:1_2-OH)_20.897_[M+H]+_3818"
	"SM(34:1_2-OH)_20.906_[M+Na]+_3817"
	"SM(34:1_3-OH)_18.369_[M+FA-H]-_205"
	"SM(34:2_2-OH)_17.39_[M+FA-H]-_48"
	"SM(34:2_2-OH)_18.519_[M+H]+_3675"
	"SM(34:2_3-OH)_16.647_[M+FA-H]-_262"
	"SM(34:2_3-OH)_17.605_[M+H]+_3637"
	"SM(34:2_4-OH)_18.989_[M+H]+_3697"
	"SM(34:3_4-OH)_18.989_[M+Na]+_3698"
	"SM(36:2_2-OH)_19.837_[M+FA-H]-_164"
	"SM(36:3_2-OH)_17.598_[M+FA-H]-_239"
	"SM(36:3_2-OH)-2_17.808_[M+FA-H]-_249"
	"SM(38:5_4-OH)_19.656_[M+Na]+_3745"
	"SM(38:6_4-OH)_19.508_[M+Na]+_3734"
	"SM(39:1_2-OH)_29.373_[M+FA-H]-_187"
	"SM(39:1_4-OH)_17.728_[M+H]+_3641"
	"SM(39:5_1-OH)_22.365_[M+H]+_3892"
	"SM(40:1_2-OH)_31.921_[M+FA-H]-_30"
	"SM(40:2_2-OH)-2_25.293_[M+FA-H]-_143"
	"SM(40:2_2-OH)_25.983_[M+FA-H]-_80"
	"SM(40:5_2-OH)_19.984_[M+H]+_3772"
	"SM(41:1_2-OH)_34.482_[M+FA-H]-_44"
	"SM(42:1_2-OH)_34.742_[M+H]+_4210"
	"SM(42:3_2-OH)_32.144_[M+Na]+_4138"
	"SM(42:4_4-OH)_34.184_[M+Na]+_4172"
	"SM(42:5_2-OH)_22.953_[M+H]+_3920"
	"SM(42:6_3-OH)_27.316_[M+Na]+_4059"
	"SM(42:8_2-OH)_18.698_[M+Na]+_3684"
	"SM(42:8_2-OH)_18.699_[M+H]+_3683"
	"SM(43:2_2-OH)_34.903_[M+H]+_4218"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"GcGM2(34:1,2-OH)_16.791_[M-H]-_209"
	"GcGM2(34:1,2-OH)_17.931_[M+Na]+_3647"
	"GcGM2(36:1,2-OH)_18.771_[M-H]-_232"
	"GcGM2(38:1,2-OH)_23.658_[M+Na]+_4553"
	"GcGM2(40:1,2-OH)_24.985_[M-H]-_100"
	"GcGM2(40:1,2-OH)_29.306_[M+Na]+_4095"
	"GcGM2(42:1,2-OH)_34.35_[M+Na]+_4173"
	"GcGM2(42:2,2-OH)_28.02_[M+Na]+_4078"
	"LacCer(34:2,2-OH)_17.807_[M+Na]+_3644"
	"LacCer(34:2,3-OH)_17.309_[M+Na]+_3630"
	"PE(18:1e/11,12-EET)_20.811_[M-H]-_280"
	"PE(18:2e/16,17-EpDPE)_20.26_[M-H]-_278"
	"SM(32:1,2-OH)_17.163_[M+FA-H]-_130"
	"SM(32:1,2-OH)_18.217_[M+K]+_3659"
	"SM(32:1,3-OH)_17.324_[M+H]+_3632"
	"SM(34:0,3-OH)_18.023_[M+FA-H]-_225"
	"SM(34:0,3-OH)_19.317_[M+H]+_3725"
	"SM(34:1,2-OH)_20.389_[M+H]+_3795"
	"SM(34:1,2-OH)_20.897_[M+H]+_3818"
	"SM(34:1,2-OH)_20.906_[M+Na]+_3817"
	"SM(34:1,3-OH)_18.369_[M+FA-H]-_205"
	"SM(34:2,2-OH)_17.39_[M+FA-H]-_48"
	"SM(34:2,2-OH)_18.519_[M+H]+_3675"
	"SM(34:2,3-OH)_16.647_[M+FA-H]-_262"
	"SM(34:2,3-OH)_17.605_[M+H]+_3637"
	"SM(34:2,4-OH)_18.989_[M+H]+_3697"
	"SM(34:3,4-OH)_18.989_[M+Na]+_3698"
	"SM(36:2,2-OH)_19.837_[M+FA-H]-_164"
	"SM(36:3,2-OH)_17.598_[M+FA-H]-_239"
	"SM(36:3,2-OH)-2_17.808_[M+FA-H]-_249"
	"SM(38:5,4-OH)_19.656_[M+Na]+_3745"
	"SM(38:6,4-OH)_19.508_[M+Na]+_3734"
	"SM(39:1,2-OH)_29.373_[M+FA-H]-_187"
	"SM(39:1,4-OH)_17.728_[M+H]+_3641"
	"SM(39:5,1-OH)_22.365_[M+H]+_3892"
	"SM(40:1,2-OH)_31.921_[M+FA-H]-_30"
	"SM(40:2,2-OH)-2_25.293_[M+FA-H]-_143"
	"SM(40:2,2-OH)_25.983_[M+FA-H]-_80"
	"SM(40:5,2-OH)_19.984_[M+H]+_3772"
	"SM(41:1,2-OH)_34.482_[M+FA-H]-_44"
	"SM(42:1,2-OH)_34.742_[M+H]+_4210"
	"SM(42:3,2-OH)_32.144_[M+Na]+_4138"
	"SM(42:4,4-OH)_34.184_[M+Na]+_4172"
	"SM(42:5,2-OH)_22.953_[M+H]+_3920"
	"SM(42:6,3-OH)_27.316_[M+Na]+_4059"
	"SM(42:8,2-OH)_18.698_[M+Na]+_3684"
	"SM(42:8,2-OH)_18.699_[M+H]+_3683"
	"SM(43:2,2-OH)_34.903_[M+H]+_4218"
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri" column at position 7 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.
Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.