Validation Log 2025-12-15 01:44:40.143636 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004873/mwtab/txt Study ID: ST002966 Analysis ID: AN004873 File format: txt Status: Contains Validation Issues Number of Issues: 14 Number of Warnings: 13 Number of Value Errors: 14 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "40°C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: The "PubChem_ID" column at position 2 in the METABOLITES table, matches a standard column name, "pubchem_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 C02294 1 C01746 2 C00134 3 C19524 4 C01672 5 C00334 6 C01026 8 C03665 9 C00114 10 C00065 11 C06772 13 C00148 14 C00719 15 C00183 16 C00188 17 C00263 19 C06463 20 C20782 21 C09815 22 C05332 23 C00153 24 C05853 25 C00253 26 C07446 27 C11101 29 C00408 30 C03969 32 C02714 33 C00179 34 C00430 36 C00407 37 C02378 38 C00123 39 C01933 40 C00152 41 C00077 42 C22040 44 C00147 45 C15561 46 C00262 47 C00568 48 C01004 49 C02918 50 C02735 51 C00483 52 C00870 53 C00860 54 C10172 55 C21514 56 C02946 57 C01035 58 C00315 59 C00064 60 C00047 61 C01996 62 C00025 63 C00979 65 C00073 66 C17883 67 C00242 68 C16666 69 C00135 70 C00956 71 C10475 72 C17213 73 C02989 74 C00079 75 C16614 76 C05831 77 C00250 78 C04548 79 C00314 80 C00062 81 C17203 82 C00780 83 C00329 84 C10575 85 C00082 89 C00588 90 C21283 93 C02727 94 C02155 97 C01924 98 C03884 99 C02427 100 C00355 101 C03626 103 C00750 105 C05660 106 C05944 108 C00864 109 C01132 110 C00140 111 C02029 113 C18326 115 C00214 116 C02961 117 C00475 118 C00120 121 C03002 122 C00559 123 C05841 124 C00670 125 C10497 128 C00330 129 C00212 131 C06346 136 C08364 141 C19670 142 C00387 144 C06161 148 C00170 150 C20674 152 C09340 154 C05176 155 C05243 162 C16984 163 C02717 169 C09342 170 C17567 171 C16991 173 C12144 174 C11347 177 C05175 184 C05174 185 C20792 188 C17591 189 C09541 191 C09365 192 C12326 200 C02105 202 C00360 203 C03996 204 C06196 205 C12226 206 C05191 207 C00455 208 C09430 219 C09553 223 C17426 224 C06533 226 C19985 228 C03329 235 C09549 243 C17046 244 C09581 253 C08680 255 C00020 260 C09360 265 C05315 267 C09024 270 C05189 271 C12242 274 C10882 282 C09341 285 C02890 286 C09446 294 C00144 295 C09643 296 C17790 305 C02134 306 C15530 308 C10190 309 C00255 312 C16443 315 C00021 319 C03690 321 C10112 331 C10025 333 C01750 340 C05623 342 C10073 381 C10020 402 C17563 404 C17910 409 C00003