Validation Log 2025-12-15 01:44:43.354818 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004874/mwtab/txt Study ID: ST002966 Analysis ID: AN004874 File format: txt Status: Contains Validation Issues Number of Issues: 14 Number of Warnings: 13 Number of Value Errors: 14 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "40°C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: The "PubChem_ID" column at position 2 in the METABOLITES table, matches a standard column name, "pubchem_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 C00213 1 C01089 2 C00383 3 C00106 4 C00122 6 C02170 7 C00042 8 C20827 9 C00872 10 C00097 11 C00633 12 C10164 13 C00490 14 C03065 15 C00489 19 C03589 20 C02642 21 C03264 23 C19911 24 C00049 25 C03064 26 C00149 27 C04039 28 C21649 29 C00548 30 C10700 31 C05585 32 C00587 33 C16700 34 C00805 35 C00156 36 C00346 37 C07185 38 C00026 41 C06104 42 C06006 43 C03618 44 C06032 45 C02614 46 C00652 47 C00898 48 C00121 49 C00216 51 C00755 52 C00474 53 C00379 54 C03087 55 C02656 56 C16657 58 C19837 60 C01127 61 C03761 62 C03079 63 C06337 64 C00502 65 C16322 66 C05422 68 C08278 69 C00437 70 C01042 71 C02504 72 C04411 73 C03975 74 C05003 75 C00031 76 C00137 78 C01697 79 C00794 80 C00392 82 C17715 83 C18078 85 C17878 86 C08261 87 C00624 88 C02712 89 C00158 90 C00311 91 C00296 92 C00333 93 C00191 94 C01494 95 C03844 96 C00257 97 C00279 98 C02679 99 C00078 102 C03519 103 C05610 105 C00879 106 C00818 107 C02076 108 C00672 109 C00673 111 C06424 112 C00117 113 C09376 114 C10314 116 C16537 117 C00299 120 C10200 122 C00249 123 C06156 124 C00085 125 C00103 126 C00092 127 C01096 128 C06082 131 C10343 133 C06186 135 C00831 136 C06427 137 C06426 138 C07289 140 C01595 141 C04056 142 C01712 143 C21944 144 C08363 145 C01762 146 C01530 147 C19615 151 C16342 153 C16346 155 C14825 156 C14762 157 C14767 158 C14826 159 C08365 166 C06046 169 C03042 171 C04256 173 C09159 174 C00219 175 C00239 176 C00051 177 C16525 180 C16321 181 C21923 182 C04785 184 C14827 186 C20186 187 C07354 188 C04717 190 C14829 194 C18699 195 C00105 196 C06739 200 C00575 202 C12165 205 C14835 206 C14837 207 C01158 211 C00354 212 C01231 213 C08281 216 C05402 217 C01235 218 C00243 219 C01083 220 C00089 221 C01971 222 C01742 223 C00942 224 C00852 226 C17759 228 C01175 232 C00015 233 C00689 234 C00008 239 C01604 244 C17420 245 C08619 248 C08988 250 C09731 257 C16939 263 C00713 264 C08243 266 C10445 269 C00190 272 C00029 273 C00043 275 C05625 276 C00127 277 C17908 282 C00006