Validation Log 2025-12-15 01:51:03.596411 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN004993/mwtab/json Study ID: ST003044 Analysis ID: AN004993 File format: json Status: Contains Validation Issues Number of Issues: 5 Number of Warnings: 3 Number of Value Errors: 5 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "0.3-0.4 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "45", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "parent" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "parent_moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 10 C26 H45 N O8 S2 11 C26 H45 N O6 S 12 C26 H43 N O7 S 13 C40 H77 N O12 S 26 C39 H49 N O14 29 C58 H89 N O3 32 C42 H84 N O9 P 33 C46 H76 N O10 P 34 C44 H78 N O10 P 49 C42 H82 N O10 P 51 C47 H82 N O7 P 52 C43 H82 N O7 P 53 C45 H74 N O7 P 54 C45 H78 N O7 P 55 C45 H82 N O7 P 56 C43 H78 N O7 P 57 C41 H78 N O7 P 58 C41 H80 N O7 P 59 C45 H80 N O8 P 60 C41 H74 N O7 P 61 C39 H74 N O7 P 62 C43 H74 N O8 P 63 C41 H74 N O8 P 64 C39 H74 N O8 P 65 C39 H76 N O8 P 66 C13 H13 N O4 67 C52 H96 N O7 P 68 C48 H88 N O7 P 69 C48 H90 N O7 P 70 C46 H86 N O7 P 71 C42 H84 N O8 P 72 C45 H82 N O8 P 73 C44 H80 N O7 P 74 C42 H80 N O7 P 75 C44 H82 N O7 P 76 C42 H80 N O8 P 77 C42 H82 N O8 P 78 C41 H82 N O8 P 79 C45 H78 N O8 P 80 C43 H78 N O8 P 81 C41 H78 N O8 P 82 C41 H80 N O8 P 83 C42 H76 N O8 P 93 C43 H84 N O10 P 94 C40 H80 N O9 P 95 C44 H88 N O9 P 96 C30 H60 N O9 P 97 C26 H54 N O8 P 98 C26 H52 N O9 P 99 C43 H82 N O10 P 100 C44 H82 N O9 P 101 C44 H86 N O10 P 102 C46 H92 N O9 P 103 C28 H56 N O9 P 104 C39 H76 N O9 P 105 C46 H84 N O9 P 106 C47 H84 N O10 P 107 C48 H88 N O9 P 108 C45 H80 N O10 P 109 C49 H88 N O10 P 110 C46 H80 N O9 P 111 C48 H84 N O9 P 112 C50 H86 N O10 P 113 C46 H86 N O10 P 114 C44 H82 N O10 P 115 C44 H84 N O9 P 116 C50 H94 N O10 P 117 C47 H90 N O10 P 118 C50 H98 N O10 P 119 C47 H94 N O9 P 120 C46 H90 N O10 P 121 C48 H94 N O10 P 122 C45 H88 N O10 P 123 C28 H52 N O9 P 124 C42 H82 N O9 P 125 C50 H90 N O10 P 126 C48 H86 N O9 P 127 C50 H88 N O10 P 128 C48 H80 N O10 P 129 C46 H84 N O10 P 130 C47 H86 N O10 P 131 C45 H82 N O10 P 132 C48 H90 N O9 P 133 C48 H88 N O10 P 134 C50 H92 N O10 P 135 C44 H84 N O10 P 136 C45 H88 N O9 P 137 C30 H62 N O9 P 138 C28 H58 N O9 P 140 C42 H85 N O3 141 C44 H89 N O4 142 C9 H13 N O4 143 C33 H49 N O7 144 C33 H49 N O6 145 C43 H85 N O4 146 C42 H81 N O4 147 C44 H85 N O4 148 C40 H79 N O4 149 C44 H87 N O4 150 C43 H87 N O4 152 C10 H15 N O4 154 C44 H89 N O5 159 C18 H38 N O5 P 168 C24 H48 N O9 P 172 C27 H44 N O7 P 173 C25 H44 N O7 P 174 C25 H46 N O7 P 175 C23 H44 N O7 P 176 C23 H46 N O7 P 177 C21 H44 N O7 P 178 C25 H50 N O7 P 179 C25 H52 N O7 P 180 C24 H50 N O7 P 181 C23 H48 N O7 P 186 C6 H13 N O2 187 C32 H58 N O11 P 196 C46 H87 N O13 197 C48 H91 N O8 198 C40 H77 N O8 202 C26 H43 N O8 S 203 C26 H43 N O6 204 C26 H43 N O5 205 C42 H79 N O8 218 C4 H6 Br I O2 225 C42 H78 N O10 P Warning: The "medRt" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.