Validation Log 2025-12-15 01:55:05.060164 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005073/mwtab/txt Study ID: ST003101 Analysis ID: AN005073 File format: txt Status: Contains Validation Issues Number of Issues: 55 Number of Warnings: 51 Number of Value Errors: 52 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "0.3 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "55", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "1_4-cyclohexanedicarboxylic acid" "2^_5^-dideoxyadenosine" "2^-deoxyguanosine monohydrate" "2^-o-Methyluridine" "3_4-dihydroxymandelic acid" "3_4-dihydroxyphenyl ethanol" "adenosine 5^-monophosphate disodium salt" "N2_N2-dimethylguanosine" "SM(d19:0/18:1(12Z)-2OH(9_10))" "thymidine-5^-monophosphate" "uridine 2^_3^-cyclic phosphate" "uridine 5^-diphospho-N-acetylglucosamine sodium salt" "uridine 5^-monophosphate" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "1,4-cyclohexanedicarboxylic acid" "2',5'-dideoxyadenosine" "2'-deoxyguanosine monohydrate" "2'-o-Methyluridine" "3,4-dihydroxymandelic acid" "3,4-dihydroxyphenyl ethanol" "adenosine 5'-monophosphate disodium salt" "N2,N2-dimethylguanosine" "SM(d19:0/18:1(12Z)-2OH(9,10))" "thymidine-5'-monophosphate" "uridine 2',3'-cyclic phosphate" "uridine 5'-diphospho-N-acetylglucosamine sodium salt" "uridine 5'-monophosphate" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values. Warning: The "other_id" column at position 5 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.