Validation Log 2025-12-15 01:55:09.837053 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005074/mwtab/json Study ID: ST003101 Analysis ID: AN005074 File format: json Status: Contains Validation Issues Number of Issues: 57 Number of Warnings: 52 Number of Value Errors: 54 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "0.4 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "65", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][10] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][11] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][12] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][13] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][14] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][15] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][16] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][17] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][18] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][19] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][20] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][21] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][22] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][23] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][24] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][25] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][26] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][27] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][28] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][29] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][30] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][31] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][32] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][33] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][34] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][35] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][36] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][37] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][38] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][39] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" "RAW_FILE_NAME" "RAW_FILE_NAME" Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "13_14-dihydro-19-hydroxyPGE1" "13_14-dihydro-PGE1" "2_3-dinor-8-iso-PGF2a" "orsellinic acid_ ethyl ester" "TG(14:0/20:5(5Z_8Z_11Z_14Z_17Z)/18:4)" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "13,14-dihydro-19-hydroxyPGE1" "13,14-dihydro-PGE1" "2,3-dinor-8-iso-PGF2a" "orsellinic acid, ethyl ester" "TG(14:0/20:5(5Z,8Z,11Z,14Z,17Z)/18:4)" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.