Validation Log 2025-12-15 02:00:02.602670 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005166/mwtab/txt Study ID: ST003148 Analysis ID: AN005166 File format: txt Status: Contains Validation Issues Number of Issues: 53 Number of Warnings: 37 Number of Value Errors: 51 Number of Consistency Errors: 1 Number of Format Errors: 1 Issue Log: Error: The value, "60", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "EXTRACT_CONCENTRATION_DILUTION", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "EXTRACT_ENRICHMENT", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "EXTRACT_CLEANUP", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "SAMPLE_RESUSPENSION", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "SAMPLE_DERIVATIZATION", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "SAMPLE_SPIKING", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "200", for the subsection, "ION_SOURCE_TEMPERATURE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "3600", for the subsection, "ION_SPRAY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "Both", for the subsection, "IONIZATION", in the "MS" section should not be "positive" or "negative". "ION_MODE" is where that should be indicated. Error: The value, "200", for the subsection, "SOURCE_TEMPERATURE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "0.2 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "40", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: Unknown or invalid section, "FACTORS". Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw File Name)" Warning: The "quantified m/z" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "parent" column at position 4 in the METABOLITES table, matches a standard column name, "parent_moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "pubchem id" column at position 5 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "kegg id" column at position 6 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "kegg id" column at position 6 in the METABOLITES table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 11 65359 12 65359 13 65359 14 65359 15 65359 16 65359 17 65359 18 65359 19 65359 20 65359 21 65359 22 65359 23 65359 24 65359 25 65359 26 65359 27 65359 28 65359 29 65359 30 65359 31 65359 Warning: The "regno" column at position 7 in the METABOLITES table, matches a standard column name, "mw_regno". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "regno" column at position 7 in the METABOLITES table, matches a standard column name, "mw_regno", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 11 C00127 12 C00127 13 C00127 14 C00127 15 C00127 16 C00127 17 C00127 18 C00127 19 C00127 20 C00127 21 C00127 22 C00127 23 C00127 24 C00127 25 C00127 26 C00127 27 C00127 28 C00127 29 C00127 30 C00127 31 C00127 Warning: The "retention time" column at position 2 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "comments" column at position 8 in the METABOLITES table, matches a standard column name, "comment". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "comments" column at position 8 in the METABOLITES table, matches a standard column name, "comment", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 11 49863 12 49863 13 49863 14 49863 15 49863 16 49863 17 49863 18 49863 19 49863 20 49863 21 49863 22 49863 23 49863 24 49863 25 49863 26 49863 27 49863 28 49863 29 49863 30 49863 31 49863 Warning: The "01_Blank" column at position 2 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "01_Blank_20220515015111" column at position 3 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "11_Blank" column at position 13 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "21_Blank" column at position 23 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Error: Column(s) with no name were found in the METABOLITES table. Warning: The "" column at position 9 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Error: The section, METABOLITES, has a mismatch between the number of headers and the number of elements in each line. Either a line(s) has more values than headers or there are too few headers.