Validation Log 2025-12-15 02:06:09.910402 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005286/mwtab/txt Study ID: ST003224 Analysis ID: AN005286 File format: txt Status: Contains Validation Issues Number of Issues: 7 Number of Warnings: 5 Number of Value Errors: 6 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "0.200 mL/minute", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "30", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "chemical formula" column at position 2 in the METABOLITES table, matches a standard column name, "formula". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Pubchem ID" column at position 3 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Pubchem ID" column at position 3 in the METABOLITES table, matches a standard column name, "pubchem_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 C00629 3 C01180 4 C00197 5 C01005 6 C00334 7 C03492 8 C00847 9 C00345 11 C00024 13 C02727|C12989 14 C00417|C02341 15 C00147 16 C00498 17 C00026 18 C00213 19 C01551 20 C00956 21 C00108 22 C00062 23 C00072 24 C00152 25 C00049 26 C00049 27 C00512 28 C00169 29 C00318|C15025 31 C00112 32 C00307 33 C00570 35 C06907 36 C02226 37 C00158|C00311 38 C00055 39 C00010 40 C00300 41 C00063 42 C00542 43 C00491 44 C00475 45 C00360 46 C00131 47 C00705 48 C00239 49 C00458 50 C05274 51 C00559 52 C00212 53 C05512 54 C00673 55 C00526 56 C00279 57 C00008 58 C00257 59 C03783 60 C00362 61 C00002 62 C00337 63 C00111 65 C00408 67 C00281|C05382|C06222 68 C00363 69 C00364 70 C00459 71 C00365 72 C00016 73 C00061 74 C00504 76 C00122 77 C00035 78 C00198 79 C00103 80 C00025 81 C00064 82 C00051 83 C00127 84 C00258 85 C06193 86 C00044 87 C00581 88 C00242 89 C00387 91 C00085 92 C00135 93 C00155 95 C05852 96 C01157 97 C00262 98 C00104 99 C00130 100 C16074 101 HMDB00734 102 C00294 104 C00328|C01718 105 C00186|C00256|C01432 106 C03406 108 C00123 109 C00047 110 C00149|C00497|C00711 111 C01384 113 C00073 114 C00137 115 C00140 116 C04256|C00357 117 C00624 118 HMDB06029 119 C01073 120 C00437 121 C00003 122 C00004 123 C00006 124 C00005 125 C00438 127 C00253 131 C00077 132 C00295 133 C01103 134 C00036 135 C00568 136 C00864 142 C00079 143 C00074 144 C00156|C00587 145 C00251 146 C00148 147 C00100 149 C00314 150 C01879 151 C00013 152 C00022 153 C03722 154 C00255 157 C03539 158 C00117 160 C00021 161 C00019 165 C00065 166 C03175 168 C00170 169 C00093 170 C02170 171 C00091|C00683|C02557 172 C00245 173 C00272 174 C00378 175 C00068 176 C01081 177 C00263 178 C00214 179 C00689 180 C00078|C00525|C00806 181 C00082 182 C00015 183 C00029 184 C00167 185 C00043 186 C00105 187 C00299 188 C00075 189 C00183 191 C00385 192 C01762 193 C00655 194 C02470 Warning: The "retention index" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "retention index" was found in the METABOLITES table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found.