Validation Log
2025-12-15 02:09:49.334308
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005367/mwtab/txt
Study ID:      ST003277
Analysis ID:   AN005367
File format:   txt
Status: Contains Validation Issues
Number of Issues: 12

Number of Warnings: 9

Number of Value Errors: 9

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: The value, "40-50", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"12_13-DiHOME"
	"1_2_3-benzenetriol sulfate (1)"
	"1_2_3-benzenetriol sulfate (2)"
	"1_5-anhydroglucitol (1_5-AG)"
	"2_3-dihydroxy-5-methylthio-4-pentenoate (DMTPA)*"
	"2_4_6-trihydroxybenzoate"
	"2_4-di-tert-butylphenol"
	"2_8-quinolinediol sulfate"
	"2^-deoxyguanosine"
	"2^-deoxyinosine"
	"2^-deoxyuridine"
	"2^-O-methyluridine"
	"(3^-5^)-adenylyladenosine*"
	"(3^-5^)-adenylylcytidine"
	"(3^-5^)-adenylylguanosine*"
	"(3^-5^)-adenylyluridine"
	"(3^-5^)-cytidylyladenosine"
	"(3^-5^)-cytidylylcytidine*"
	"(3^-5^)-cytidylylguanosine"
	"(3^-5^)-cytidylyluridine*"
	"(3^-5^)-guanylyladenosine*"
	"(3^-5^)-guanylylcytidine"
	"(3^-5^)-guanylyluridine"
	"(3^-5^)-uridylyladenosine"
	"(3^-5^)-uridylylcytidine*"
	"(3^-5^)-uridylylguanosine"
	"(3^-5^)-uridylyluridine"
	"5_6-dihydrouridine"
	"5alpha-pregnan-3beta_20alpha-diol disulfate"
	"9_10-DiHOME"
	"adenosine-2^_3^-cyclic monophosphate"
	"adenosine 3^_5^-cyclic monophosphate (cAMP)"
	"adenosine 3^-monophosphate (3^-AMP)"
	"adenosine 5^-diphosphoribose (ADP-ribose)"
	"bilirubin degradation product_ C16H18N2O5 (1)**"
	"bilirubin degradation product_ C16H18N2O5 (2)**"
	"bilirubin degradation product_ C16H18N2O5 (3)**"
	"bilirubin degradation product_ C16H18N2O5 (4)**"
	"bilirubin degradation product_ C17H18N2O4 (1)**"
	"bilirubin degradation product_ C17H18N2O4 (3)**"
	"bilirubin degradation product_ C17H20N2O5 (2)**"
	"chrysoeriol (3^-O-methylluteolin)"
	"cyclo(pro-arg) (D_L)*"
	"cytidine 2^_3^-cyclic monophosphate"
	"guanosine-2^_3^-cyclic monophosphate"
	"guanosine 2^-monophosphate (2^-GMP)*"
	"guanosine 3^-monophosphate (3^-GMP)"
	"N2_N6-diacetyllysine"
	"thymidine 5^-monophosphate"
	"uridine-2^_3^-cyclic monophosphate"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"12,13-DiHOME"
	"1,2,3-benzenetriol sulfate (1)"
	"1,2,3-benzenetriol sulfate (2)"
	"1,5-anhydroglucitol (1,5-AG)"
	"2,3-dihydroxy-5-methylthio-4-pentenoate (DMTPA)*"
	"2,4,6-trihydroxybenzoate"
	"2,4-di-tert-butylphenol"
	"2,8-quinolinediol sulfate"
	"2'-deoxyguanosine"
	"2'-deoxyinosine"
	"2'-deoxyuridine"
	"2'-O-methyluridine"
	"(3'-5')-adenylyladenosine*"
	"(3'-5')-adenylylcytidine"
	"(3'-5')-adenylylguanosine*"
	"(3'-5')-adenylyluridine"
	"(3'-5')-cytidylyladenosine"
	"(3'-5')-cytidylylcytidine*"
	"(3'-5')-cytidylylguanosine"
	"(3'-5')-cytidylyluridine*"
	"(3'-5')-guanylyladenosine*"
	"(3'-5')-guanylylcytidine"
	"(3'-5')-guanylyluridine"
	"(3'-5')-uridylyladenosine"
	"(3'-5')-uridylylcytidine*"
	"(3'-5')-uridylylguanosine"
	"(3'-5')-uridylyluridine"
	"5,6-dihydrouridine"
	"5alpha-pregnan-3beta,20alpha-diol disulfate"
	"9,10-DiHOME"
	"adenosine-2',3'-cyclic monophosphate"
	"adenosine 3',5'-cyclic monophosphate (cAMP)"
	"adenosine 3'-monophosphate (3'-AMP)"
	"adenosine 5'-diphosphoribose (ADP-ribose)"
	"bilirubin degradation product, C16H18N2O5 (1)**"
	"bilirubin degradation product, C16H18N2O5 (2)**"
	"bilirubin degradation product, C16H18N2O5 (3)**"
	"bilirubin degradation product, C16H18N2O5 (4)**"
	"bilirubin degradation product, C17H18N2O4 (1)**"
	"bilirubin degradation product, C17H18N2O4 (3)**"
	"bilirubin degradation product, C17H20N2O5 (2)**"
	"chrysoeriol (3'-O-methylluteolin)"
	"cyclo(pro-arg) (D,L)*"
	"cytidine 2',3'-cyclic monophosphate"
	"guanosine-2',3'-cyclic monophosphate"
	"guanosine 2'-monophosphate (2'-GMP)*"
	"guanosine 3'-monophosphate (3'-GMP)"
	"N2,N6-diacetyllysine"
	"thymidine 5'-monophosphate"
	"uridine-2',3'-cyclic monophosphate"
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri" column at position 7 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.
Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.