Validation Log 2025-12-15 02:15:04.685349 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005460/mwtab/json Study ID: ST003333 Analysis ID: AN005460 File format: json Status: Contains Validation Issues Number of Issues: 6 Number of Warnings: 4 Number of Value Errors: 6 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value, "25", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Calc. MW" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 C17 H27 N O4 1 C15 H27 N O4 4 C16 H31 N O4 5 C35 H71 N O3 6 C17 H29 N O4 8 C17 H31 N O4 9 C8 H15 N O2 11 C17 H25 N O4 13 C11 H21 N O4 14 C9 H9 N O3 15 C33 H67 N O3 16 C9 H11 N O2 17 C37 H75 N O3 19 C7 H13 N O2 20 C9 H17 N O4 21 C11 H9 N O2 25 C16 H29 N O4 27 C12 H23 N O4 28 C17 H31 N O5 29 C7 H13 N O4 S 32 C6 H13 N O2 S 33 C5 H7 N O3 38 C12 H23 N O5 39 C9 H15 N O5 S 43 C7 H7 N O2 45 C9 H11 N O3 47 C14 H25 N O4 48 C8 H17 N O2 S 51 C8 H17 N O2 52 C9 H19 N O2 53 C26 H41 N O5 61 C6 H11 N O3 64 C13 H13 N O4 65 C15 H29 N O5 67 C15 H29 N O4 69 C7 H11 N O2 72 C18 H33 N O4 77 C14 H25 N O6 79 C16 H27 N O6 80 C8 H15 N O4 S 82 C15 H25 N O4 84 C13 H25 N O4 89 C9 H17 N O5 92 C20 H31 B N4 O4 S 93 C19 H29 N O4 94 C19 H41 N O2 96 C13 H25 N O5 97 C11 H19 N O6 100 C5 H11 N O2 S 102 C9 H11 N O6 S 104 C17 H31 N O6 107 C13 H23 N O4 113 C13 H15 N O5 114 C19 H22 Cl N3 O S 115 C7 H7 N O4 116 C8 H13 N O3 S 117 C10 H19 N O4 118 C19 H35 N O4 120 C14 H19 N O4 121 C15 H16 F N5 O 122 C12 H21 N O4 S 123 C16 H22 Cl N3 124 C21 H39 N O6 125 C16 H17 Cl N2 S 127 C19 H35 N O5 129 C7 H15 N O3 131 C14 H27 N O4 133 C11 H15 N O4 134 C17 H23 N O4 141 C9 H9 N O4 143 C16 H29 N O5 146 C14 H17 N O8 150 C11 H15 N O10 151 C16 H17 N O8 152 C12 H23 N O9 153 C7 H11 N O 155 C10 H17 N O3 164 C7 H13 N O3 166 C15 H27 N O5 167 C15 H25 N O5 169 C7 H15 N O2 S 171 C10 H7 N O4 172 C22 H43 N O 175 C6 H9 N O 180 C16 H27 N O4 182 C12 H13 N O5 185 C12 H17 N O5 188 C10 H19 N O2 S2 189 C21 H37 N O6 193 C5 H7 N O2 199 C13 H21 B N2 O3 S 200 C8 H9 N O 214 C13 H23 N O9 215 C17 H33 N O5 216 C15 H24 N O4 P S 223 C8 H7 N O3 224 C21 H31 N O8 226 C16 H25 N O10 227 C31 H44 Cl N3 O2 S 228 C8 H9 N O4 229 C10 H9 N O3 231 C10 H19 N O S2 234 C6 H9 N O S 237 C31 H63 N O3 243 C22 H23 Cl F N3 O2 248 C9 H13 N O4 249 C3 H7 Cl O2 250 C17 H33 N O4 253 C16 H31 N O5 254 C23 H45 N O3 257 C15 H17 N O8 265 C16 H23 N O6 271 C5 H9 N O2 272 C18 H35 N O5 275 C23 H37 N O6 S 276 C21 H37 N O4 278 C12 H17 N O3 280 C26 H37 N O6 281 C18 H15 B O2 284 C17 H24 F3 N O2 285 C14 H15 N O8 289 C37 H75 N O4 293 C8 H7 N O2 297 C8 H11 N O 303 C12 H17 N O3 304 C14 H23 N O11 305 C18 H20 F N5 O 306 C2 H6 Cl O3 P 307 C29 H33 F N2 O4 311 C8 H9 N O4 S 312 C12 H15 N O5 313 S Se 314 C12 H21 N O3 317 C15 H21 N O9 323 C16 H23 N O5 324 C24 H32 Cl N3 O3 S 325 C35 H71 N O4 329 C22 H43 N O4 334 C39 H79 N O4 335 C14 H19 N O8 336 C17 H35 N O2 337 C33 H65 N O4 338 C15 H15 N O8 341 C35 H69 N O4 342 C18 H39 N O3 344 C25 H47 N O6 345 C22 H45 N O2 346 C20 H41 N O3 348 C20 H39 N O5 349 C24 H47 N O4 350 C11 H11 Br N2 O2 Warning: The "RT [min]" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.