Validation Log 2025-12-15 02:17:49.706240 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005512/mwtab/txt Study ID: ST003364 Analysis ID: AN005512 File format: txt Status: Contains Validation Issues Number of Issues: 10 Number of Warnings: 7 Number of Value Errors: 10 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected for the subsection, "ADDITIVES", in the "COLLECTION" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SAMPLE_DERIVATIZATION", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Warning: The "Lib_mz" column at position 4 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula_neutral" column at position 3 in the METABOLITES table, matches a standard column name, "formula". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula_neutral" column at position 3 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 15 27H46O Warning: The "Species Level" column at position 2 in the METABOLITES table, matches a standard column name, "species". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Species Level" column at position 2 in the METABOLITES table, matches a standard column name, "species", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 CE 16:0 1 CE 16:1 2 CE 17:1 3 CE 18:0 4 CE 18:1 5 CE 18:2 6 CE 18:3 7 CE 20:3 8 CE 20:4 9 CE 20:5 10 CE 22:4 11 CE 22:5 12 CE 22:6 13 CE 24:4 14 CE 24:5 15 Cholesterol 16 TG 24:0 17 TG 26:0 18 TG 28:0 19 TG 34:0 20 TG 36:0 21 TG 38:0 22 TG 40:0 23 TG 40:1 24 TG 40:2 25 TG 41:0 26 TG 41:1 27 TG 42:0 28 TG 42:1 29 TG 42:2 30 TG 43:0 31 TG 43:1 32 TG 44:0 33 TG 44:1 34 TG 44:2 35 TG 44:3 36 TG 44:4 37 TG 45:0 38 TG 45:1 39 TG 45:2 40 TG 46:0 41 TG 46:1 42 TG 46:2 43 TG 46:3 44 TG 46:4 45 TG 47:0 46 TG 47:1 47 TG 47:2 48 TG 47:3 49 TG 48:0 50 TG 48:1 51 TG 48:2 52 TG 48:3 53 TG 48:4 54 TG 49:1 55 TG 49:2 56 TG 49:3 57 TG 50:1 58 TG 50:2 59 TG 50:3 60 TG 50:4 61 TG 50:5 62 TG 50:6 63 TG 50:7 64 TG 51:2 65 TG 51:3 66 TG 51:4 67 TG 51:5 68 TG 52:2 69 TG 52:3 70 TG 52:4 71 TG 52:5 72 TG 52:6 73 TG 52:7 74 TG 52:8 75 TG 53:3 76 TG 53:4 77 TG 53:5 78 TG 53:6 79 TG 54:3 80 TG 54:4 81 TG 54:5 82 TG 54:6 83 TG 54:7 84 TG 54:8 85 TG 55:4 86 TG 55:5 87 TG 55:6 88 TG 55:7 89 TG 56:5 90 TG 56:6 91 TG 56:7 92 TG 56:8 93 TG 56:9 94 TG 57:6 95 TG 57:7 96 TG 57:9 97 TG 58:6 98 TG 58:7 99 TG 58:8 100 TG 58:9 101 TG 59:7 102 TG 60:7 103 TG 60:8 104 TG 60:9 105 TG 62:9 106 DG 32:0 107 DG 32:1 108 DG 33:1 109 DG 34:0 110 DG 34:1 111 DG 34:2 112 DG 34:3 113 DG 36:1 114 DG 36:2 115 DG 36:3 116 DG 36:4 117 DG 36:5 118 DG 37:4 119 DG 38:2 120 DG 38:4 121 DG 38:5 122 DG 38:6 123 DG 40:4 124 DG 40:5 125 DG 40:6 126 PC 30:0 127 PC 31:0 128 PC 32:0 129 PC 32:1 130 PC 32:2 131 PC 33:0 132 PC 33:0 133 PC 33:1 134 PC 33:1 135 PC 33:2 136 PC 34:0 137 PC 34:1 138 PC 34:2 139 PC 34:3 140 PC 34:3 141 PC 35:1 142 PC 35:1 143 PC 35:2 144 PC 35:2 145 PC 36:1 146 PC 36:2 147 PC 36:2 148 PC 36:3 149 PC 36:3 150 PC 36:4 151 PC 36:5 152 PC 36:5 153 PC 37:4 154 PC 38:2 155 PC 38:2 156 PC 38:3 157 PC 38:4 158 PC 38:4 159 PC 38:5 160 PC 38:5 161 PC 38:6 162 PC 38:6 163 PC 40:4 164 PC 40:5 165 PC 40:6 166 PC 40:6 167 PC 40:7 168 PC 40:7 169 PC 40:8 170 PC O-32:0 171 PC O-34:0 172 PC O-34:1 173 PC O-34:2 174 PC O-36:4 175 PC O-38:4 176 PC P-32:0 177 PC P-34:1 178 PC P-34:2 179 PC P-36:4 180 PC P-38:4 181 PC P-38:4 182 PE 32:0 183 PE 34:0 184 PE 34:1 185 PE 34:2 186 PE 36:1 187 PE 36:2 188 PE 36:2 189 PE 36:3 190 PE 36:3 191 PE 36:4 192 PE 36:5 193 PE 38:1 194 PE 38:1 195 PE 38:2 196 PE 38:2 197 PE 38:2 198 PE 38:3 199 PE 38:4 200 PE 38:4 201 PE 38:5 202 PE 38:5 203 PE 38:6 204 PE 40:2 205 PE 40:4 206 PE 40:5 207 PE 40:7 208 PE 42:1 209 PE 42:2 210 PE O-40:4 211 PE O-40:6 212 PE P-32:0 213 PE P-34:0 214 PE P-34:1 215 PE P-34:2 216 PE P-36:1 217 PE P-36:2 218 PE P-36:3 219 PE P-36:4 220 PE P-36:5 221 PE P-38:3 222 PE P-38:3 223 PE P-38:4 224 PE P-38:4 225 PE P-38:5 226 PE P-38:5 227 PE P-38:6 228 PE P-40:4 229 PE P-40:4 230 PE P-40:5 231 PE P-40:6 232 PE P-42:5 233 PE P-42:6 234 PS 34:0 235 PS 34:1 236 PS 36:1 237 PS 36:2 238 PS 38:2 239 PS 38:3 240 PS 38:4 241 PS 40:2 242 PS 40:4 243 PS 40:5 244 PS 40:6 245 PI 32:0 246 PI 32:1 247 PI 34:1 248 PI 34:2 249 PI 35:2 250 PI 36:1 251 PI 36:2 252 PI 36:4 253 PI 37:4 254 PI 38:3 255 PI 38:4 256 PI 38:5 257 PI 38:6 258 PI 40:4 259 PI 40:5 260 PI 40:6 261 PI 40:8 262 PG 34:1 263 PG 36:2 264 PG 38:5 265 PG 40:5 266 PG 40:6 267 PG 40:7 268 PG 40:8 269 PG 40:8 270 CL 70:7 271 CL 72:6 272 CL 72:7 273 CL 72:8 274 CL 74:10 275 LPC 14:0 276 LPC 16:0 277 LPC 16:1 278 LPC 17:0 279 LPC 17:1 280 LPC 18:0 281 LPC 18:1 282 LPC 18:2 283 LPC 20:0 284 LPC 20:1 285 LPC 20:2 286 LPC 20:3 287 LPC 20:4 288 LPC 22:4 289 LPC 22:5 290 LPC 22:6 291 LPC 24:1 292 LPC O-16:0 293 LPC O-18:0 294 LPC O-20:0 295 LPC P-16:0 296 LPC P-18:0 297 LPE 16:0 298 LPE 18:0 299 LPE 18:1 300 LPE 18:2 301 LPE 20:4 302 LPE 22:4 303 LPE 22:6 304 LPE P-16:0 305 LPE P-18:0 306 LPI 18:0 307 LPI 18:1 308 LPI 20:4 309 LPS 18:0 310 LPS 18:1 311 LPS 20:4 312 SM 28:1;O2 313 SM 30:0;O2 314 SM 31:1;O2 315 SM 32:0;O2 316 SM 32:0;O3 317 SM 32:1;O2 318 SM 32:1;O3 319 SM 32:2;O2 320 SM 33:0;O2 321 SM 33:1;O2 322 SM 33:1;O3 323 SM 33:2;O2 324 SM 34:0;O2 325 SM 34:0;O3 326 SM 34:0;O4 327 SM 34:1;O2 328 SM 34:1;O3 329 SM 34:1;O4 330 SM 34:2;O2 331 SM 34:2;O3 332 SM 34:3;O2 333 SM 35:0;O2 334 SM 35:1;O2 335 SM 35:1;O3 336 SM 35:2;O2 337 SM 36:0;O2 338 SM 36:1;O2 339 SM 36:1;O3 340 SM 36:2;O2 341 SM 36:2;O3 342 SM 36:3;O2 343 SM 37:1;O2 344 SM 37:2;O2 345 SM 38:0;O2 346 SM 38:1;O2 347 SM 38:2;O2 348 SM 39:1;O2 349 SM 39:2;O2 350 SM 40:0;O2 351 SM 40:1;O2 352 SM 40:1;O3 353 SM 40:2;O2 354 SM 41:1;O2 355 SM 41:2;O2 356 SM 42:1;O2 357 SM 42:1;O3 358 SM 42:1;O4 359 SM 42:2;O2 360 SM 42:2;O3 361 SM 42:3;O2 362 SM 42:3;O3 363 SM 43:1;O2 364 SM 43:2;O2 365 SM 43:3;O2 366 SM 44:1;O2 367 SM 44:2;O2 368 SM 44:3;O2 369 SM 44:4;O2 370 SM 50:2;O3 371 SM 52:2;O3 372 SM 52:3;O3 373 SM 54:2;O3 374 Cer 33:1;O2 375 Cer 34:1;O2 376 Cer 35:1;O2 377 Cer 36:1;O2 378 Cer 37:1;O2 379 Cer 37:1;O2 380 Cer 38:1;O2 381 Cer 38:1;O2 382 Cer 39:1;O2 383 Cer 40:1;O2 384 Cer 40:1;O2 385 Cer 40:2;O2 386 Cer 40:3;O2 387 Cer 40:3;O2 388 Cer 41:1;O2 389 Cer 41:1;O2 390 Cer 41:2;O2 391 Cer 42:1;O2 392 Cer 42:2;O2 393 Cer 43:1;O2 394 Cer 43:2;O2 395 Cer 43:2;O2 396 Cer 44:1;O2 397 Cer 44:2;O2 398 Cer 44:3;O2 399 Cer 32:2;O2 400 Cer 34:2;O2 401 Cer 36:2;O2 402 Cer 38:2;O2 403 Cer 40:2;O2 404 Cer 41:2;O2 405 Cer 42:2;O2 406 Cer 42:3;O2 407 Cer 42:4;O2 408 Cer 36:1;O 409 Cer 38:1;O 410 Cer 40:1;O 411 Cer 41:1;O 412 Cer 42:1;O 413 Cer 42:2;O 414 Cer 44:2;O 415 Cer 34:0;O 416 Cer 38:0;O 417 Cer 40:0;O 418 Cer 41:0;O 419 Cer 41:0;O 420 Cer 42:0;O 421 Cer 42:0;O 422 Cer 42:1;O 423 Cer 43:0;O 424 Cer 34:0;O2 425 Cer 36:0;O2 426 Cer 38:0;O2 427 Cer 40:0;O2 428 Cer 41:0;O2 429 Cer 42:0;O2 430 Cer 40:0;O3 431 Cer 41:0;O3 432 Cer 41:0;O3 433 Cer 41:1;O3 434 Cer 42:0;O3 435 Cer 42:1;O3 436 Cer 42:0;O4 437 Cer 42:0;O4 438 Hex1Cer 32:1;O2 439 Hex1Cer 33:1;O2 440 Hex1Cer 34:1;O2 441 Hex1Cer 36:1;O2 442 Hex1Cer 38:1;O2 443 Hex1Cer 40:1;O2 444 Hex1Cer 41:1;O2 445 Hex1Cer 42:1;O2 446 Hex1Cer 43:1;O2 447 Hex1Cer 43:1;O2 448 Hex2Cer 34:1;O2 449 Hex2Cer 36:1;O2 450 Hex2Cer 38:1;O2 451 Hex2Cer 40:1;O2 452 Hex2Cer 42:1;O2 453 Hex2Cer 42:2;O2 454 Hex2Cer 42:3;O2 455 Hex3Cer 32:1;O2 456 Hex2Cer 34:2;O2 457 Hex2Cer 40:2;O2 458 GM3 34:0;O2 459 GM3 34:1;O2 460 GM3 34:2;O2 461 GM3 36:0;O2 462 GM3 36:1;O2 463 GM3 36:2;O2 464 GM3 38:1;O2 465 GM3 38:2;O2 466 GM3 39:1;O2 467 GM3 40:0;O2 468 GM3 40:1;O2 469 GM3 40:2;O2 470 GM3 41:1;O2 471 GM3 42:1;O2 472 GM3 42:2;O2 473 GM3 44:1;O2 474 GM3 44:2;O2 Warning: The "retention time C30 [min] Exploris" column at position 5 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "retention time C18 [min] Altis" column at position 6 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.