Validation Log
2025-12-15 02:18:10.232618
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005518/mwtab/txt
Study ID:      ST003367
Analysis ID:   AN005518
File format:   txt
Status: Contains Validation Issues
Number of Issues: 72

Number of Warnings: 58

Number of Value Errors: 72

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: The value, "60", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected for the subsection, "EXTRACT_ENRICHMENT", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: An empty value or a null value was detected for the subsection, "EXTRACT_CLEANUP", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: An empty value or a null value was detected for the subsection, "SAMPLE_RESUSPENSION", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: An empty value or a null value was detected for the subsection, "SAMPLE_DERIVATIZATION", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: An empty value or a null value was detected for the subsection, "SAMPLE_SPIKING", in the "SAMPLEPREP" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: The value, "-4500", for the subsection, "CAPILLARY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required.
Error: The value, "70", for the subsection, "DRY_GAS_FLOW", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required.
Error: The value, "-4500", for the subsection, "ION_SPRAY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required.
Error: The value, "-4500", for the subsection, "SPRAY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['kV']. Ignore this when more complicated descriptions are required.
Error: The value for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "40", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "1-5 ul", for the subsection, "SAMPLE_INJECTION", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required.
Error: The value, "4", for the subsection, "INJECTION_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required.
Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #41 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #42 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #43 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #44 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #45 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #46 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #47 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #48 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #49 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #50 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #51 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #52 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The "compound group name" column at position 2 in the METABOLITES table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "pubchem id" column at position 6 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "kegg id" column at position 7 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "regno" column at position 8 in the METABOLITES table, matches a standard column name, "mw_regno". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "expected retention time" column at position 3 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "retention time" column at position 4 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.