Validation Log
2025-12-15 02:18:46.880824
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005530/mwtab/json
Study ID:      ST003378
Analysis ID:   AN005530
File format:   json
Status: Contains Validation Issues
Number of Issues: 14

Number of Warnings: 9

Number of Value Errors: 9

Number of Consistency Errors: 2

Number of Format Errors: 1

Issue Log:
Error: The value, "65", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: Unknown or invalid subsection, "SOLVENT_C", in ["CHROMATOGRAPHY"].
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"CL(8:0/8:0/11:0/18:2(9Z_11Z))"
	"CL(8:0/8:0/8:0/18:2(9Z_11Z))"
	"Cyclic di-3^_5^-adenylate;Cyclic di-AMP"
	"ent-2alpha_3alpha-Dihydroxyisokaurene"
	"ent-Cassa-12_15-dien-2beta-ol"
	"Ethyl (2E_4E_7Z)-Decatrienoate"
	"hexadeca-7_11-dien-1-ol"
	"Isorhamnetin 3-(6^^-galloylglucoside)"
	"Isorhamnetin 3-rutinoside 4^-rhamnoside"
	"LPIM1(19:2(9Z_12Z)/0:0)"
	"LysoPA(18:3(6Z_9Z_12Z)/0:0)"
	"LysoPA(22:5(4Z_7Z_10Z_13Z_16Z)/0:0)"
	"LysoPE(0:0/24:6(6Z_9Z_12Z_15Z_18Z_21Z))"
	"methyl-10-hydroperoxy-8E_12Z_15Z-octadecatrienoate"
	"Methyl 2_3_6-tri-O-galloyl-beta-D-glucopyranoside"
	"MG(0:0/20:5(5Z_8Z_11Z_14Z_17Z)/0:0)"
	"MGDG-O(16:3(7Z_10Z_13Z))"
	"Octadeca-8_10_12-triynoic acid"
	"PA(12:0/18:3(6Z_9Z_12Z))"
	"PA(17:2(9Z_12Z)/12:0)"
	"PA(18:3(9Z_12Z_15Z)/20:4(8Z_11Z_14Z_17Z))"
	"PA(18:4(6Z_9Z_12Z_15Z)/18:4(6Z_9Z_12Z_15Z))"
	"PA(20:2(11Z_14Z)/20:4(8Z_11Z_14Z_17Z))"
	"PA(20:4(5Z_8Z_11Z_14Z)e/2:0)"
	"PA(20:5(5Z_8Z_11Z_14Z_17Z)/22:5(4Z_7Z_10Z_13Z_16Z))"
	"PA(21:4(6Z_9Z_12Z_15Z)/0:0)"
	"PA(22:5(7Z_10Z_13Z_16Z_19Z)/16:0)"
	"PA(22:5(7Z_10Z_13Z_16Z_19Z)/18:4(6Z_9Z_12Z_15Z))"
	"Pantetheine 4^-phosphate"
	"PC(16:0/20:4)_ 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine_ PAPC"
	"PC(18:3(6Z_9Z_12Z)/0:0)[U]"
	"PC(19:3(10Z_13Z_16Z)/0:0)"
	"PC(20:3(5Z_8Z_11Z)/16:0)"
	"PC(20:3(8Z_11Z_14Z)/0:0)"
	"PC(20:4(5Z_8Z_11Z_14Z)/0:0)"
	"PC(20:5(5Z_8Z_11Z_14Z_17Z)/18:0)"
	"PC(20:5(5Z_8Z_11Z_14Z_17Z)/20:4(5Z_8Z_11Z_14Z))"
	"PC(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PC(O-16:2(9E_10E)/0:0)[U]"
	"PC(O-18:2(9Z_12Z)/0:0)[U]"
	"PE(16:1(9Z)/22:4(7Z_10Z_13Z_16Z))"
	"PE(16:1(9Z)/22:5(7Z_10Z_13Z_16Z_19Z))"
	"PE(18:3(6Z_9Z_12Z)/0:0)"
	"PE(18:3(6Z_9Z_12Z)/P-18:0)"
	"PE(18:4(6Z_9Z_12Z_15Z)/20:4(8Z_11Z_14Z_17Z))"
	"PE(20:3(5Z_8Z_11Z)/14:0)"
	"PE(20:4(5Z_8Z_11Z_14Z)/0:0)"
	"PE(20:5(5Z_8Z_11Z_14Z_17Z)/18:4(6Z_9Z_12Z_15Z))"
	"PE(22:5(4Z_7Z_10Z_13Z_16Z)/15:0)"
	"PE(22:5(4Z_7Z_10Z_13Z_16Z)/22:5(7Z_10Z_13Z_16Z_19Z))"
	"PE(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PE-NMe(18:4(6Z_9Z_12Z_15Z)/18:4(6Z_9Z_12Z_15Z))"
	"PG(16:1(9Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PG(18:3(6Z_9Z_12Z)/0:0)"
	"PG(20:4(5Z_8Z_11Z_14Z)/0:0)"
	"PG(20:5(5Z_8Z_11Z_14Z_17Z)/0:0)"
	"PG(22:4(7Z_10Z_13Z_16Z)/0:0)"
	"PG(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PG(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/20:4(8Z_11Z_14Z_17Z))"
	"PG(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PGP(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/20:2(11Z_14Z))"
	"PI(17:1(9Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PI(18:3(9Z_12Z_15Z)/0:0)"
	"PI(18:4(6Z_9Z_12Z_15Z)/19:1(9Z))"
	"PI(19:0/20:5(5Z_8Z_11Z_14Z_17Z))"
	"PI(19:0/22:2(13Z_16Z))"
	"PI(20:4(5Z_8Z_11Z_14Z)/0:0)"
	"PI(22:0/20:2(11Z_14Z))"
	"PI(22:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PI(22:1(11Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PI(22:4(7Z_10Z_13Z_16Z)/0:0)"
	"PI(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PIM1(18:2(9Z_12Z)/18:1(9Z))"
	"PIM2(16:0/16:2(9Z_12Z))"
	"PIM2(18:0/16:2(9Z_12Z))"
	"PIM2(19:1(9Z)/16:2(9Z_12Z))"
	"PIM2(19:2(9Z_12Z)/18:1(9Z))"
	"PIP(18:3(6Z_9Z_12Z)/18:1(11Z))"
	"PIP(20:3(8Z_11Z_14Z)/16:0)"
	"PIP2(18:0/16:2(9Z_12Z))"
	"PS(20:3(5Z_8Z_11Z)/20:1(11Z))"
	"PS(22:4(7Z_10Z_13Z_16Z)/0:0)"
	"PS(22:4(7Z_10Z_13Z_16Z)/17:2(9Z_12Z))"
	"PS(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/19:1(9Z))"
	"PS(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/20:3(8Z_11Z_14Z))"
	"PS(MonoMe(13_5)/DiMe(9_5))"
	"PS(O-18:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"TG(15:0/20:5(5Z_8Z_11Z_14Z_17Z)/22:5(7Z_10Z_13Z_16Z_19Z))"
	"TG(20:5(5Z_8Z_11Z_14Z_17Z)/15:0/20:5(5Z_8Z_11Z_14Z_17Z))"
	"TG(21:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))[iso3]"
	"TG(22:1(13Z)/15:0/20:4(5Z_8Z_11Z_14Z))"
	"TG(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/o-18:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"Uridine 5^-diphosphate"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"CL(8:0/8:0/11:0/18:2(9Z,11Z))"
	"CL(8:0/8:0/8:0/18:2(9Z,11Z))"
	"Cyclic di-3',5'-adenylate;Cyclic di-AMP"
	"ent-2alpha,3alpha-Dihydroxyisokaurene"
	"ent-Cassa-12,15-dien-2beta-ol"
	"Ethyl (2E,4E,7Z)-Decatrienoate"
	"hexadeca-7,11-dien-1-ol"
	"Isorhamnetin 3-(6''-galloylglucoside)"
	"Isorhamnetin 3-rutinoside 4'-rhamnoside"
	"LPIM1(19:2(9Z,12Z)/0:0)"
	"LysoPA(18:3(6Z,9Z,12Z)/0:0)"
	"LysoPA(22:5(4Z,7Z,10Z,13Z,16Z)/0:0)"
	"LysoPE(0:0/24:6(6Z,9Z,12Z,15Z,18Z,21Z))"
	"methyl-10-hydroperoxy-8E,12Z,15Z-octadecatrienoate"
	"Methyl 2,3,6-tri-O-galloyl-beta-D-glucopyranoside"
	"MG(0:0/20:5(5Z,8Z,11Z,14Z,17Z)/0:0)"
	"MGDG-O(16:3(7Z,10Z,13Z))"
	"Octadeca-8,10,12-triynoic acid"
	"PA(12:0/18:3(6Z,9Z,12Z))"
	"PA(17:2(9Z,12Z)/12:0)"
	"PA(18:3(9Z,12Z,15Z)/20:4(8Z,11Z,14Z,17Z))"
	"PA(18:4(6Z,9Z,12Z,15Z)/18:4(6Z,9Z,12Z,15Z))"
	"PA(20:2(11Z,14Z)/20:4(8Z,11Z,14Z,17Z))"
	"PA(20:4(5Z,8Z,11Z,14Z)e/2:0)"
	"PA(20:5(5Z,8Z,11Z,14Z,17Z)/22:5(4Z,7Z,10Z,13Z,16Z))"
	"PA(21:4(6Z,9Z,12Z,15Z)/0:0)"
	"PA(22:5(7Z,10Z,13Z,16Z,19Z)/16:0)"
	"PA(22:5(7Z,10Z,13Z,16Z,19Z)/18:4(6Z,9Z,12Z,15Z))"
	"Pantetheine 4'-phosphate"
	"PC(16:0/20:4), 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine, PAPC"
	"PC(18:3(6Z,9Z,12Z)/0:0)[U]"
	"PC(19:3(10Z,13Z,16Z)/0:0)"
	"PC(20:3(5Z,8Z,11Z)/16:0)"
	"PC(20:3(8Z,11Z,14Z)/0:0)"
	"PC(20:4(5Z,8Z,11Z,14Z)/0:0)"
	"PC(20:5(5Z,8Z,11Z,14Z,17Z)/18:0)"
	"PC(20:5(5Z,8Z,11Z,14Z,17Z)/20:4(5Z,8Z,11Z,14Z))"
	"PC(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PC(O-16:2(9E,10E)/0:0)[U]"
	"PC(O-18:2(9Z,12Z)/0:0)[U]"
	"PE(16:1(9Z)/22:4(7Z,10Z,13Z,16Z))"
	"PE(16:1(9Z)/22:5(7Z,10Z,13Z,16Z,19Z))"
	"PE(18:3(6Z,9Z,12Z)/0:0)"
	"PE(18:3(6Z,9Z,12Z)/P-18:0)"
	"PE(18:4(6Z,9Z,12Z,15Z)/20:4(8Z,11Z,14Z,17Z))"
	"PE(20:3(5Z,8Z,11Z)/14:0)"
	"PE(20:4(5Z,8Z,11Z,14Z)/0:0)"
	"PE(20:5(5Z,8Z,11Z,14Z,17Z)/18:4(6Z,9Z,12Z,15Z))"
	"PE(22:5(4Z,7Z,10Z,13Z,16Z)/15:0)"
	"PE(22:5(4Z,7Z,10Z,13Z,16Z)/22:5(7Z,10Z,13Z,16Z,19Z))"
	"PE(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PE-NMe(18:4(6Z,9Z,12Z,15Z)/18:4(6Z,9Z,12Z,15Z))"
	"PG(16:1(9Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PG(18:3(6Z,9Z,12Z)/0:0)"
	"PG(20:4(5Z,8Z,11Z,14Z)/0:0)"
	"PG(20:5(5Z,8Z,11Z,14Z,17Z)/0:0)"
	"PG(22:4(7Z,10Z,13Z,16Z)/0:0)"
	"PG(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PG(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/20:4(8Z,11Z,14Z,17Z))"
	"PG(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PGP(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/20:2(11Z,14Z))"
	"PI(17:1(9Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PI(18:3(9Z,12Z,15Z)/0:0)"
	"PI(18:4(6Z,9Z,12Z,15Z)/19:1(9Z))"
	"PI(19:0/20:5(5Z,8Z,11Z,14Z,17Z))"
	"PI(19:0/22:2(13Z,16Z))"
	"PI(20:4(5Z,8Z,11Z,14Z)/0:0)"
	"PI(22:0/20:2(11Z,14Z))"
	"PI(22:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PI(22:1(11Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PI(22:4(7Z,10Z,13Z,16Z)/0:0)"
	"PI(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PIM1(18:2(9Z,12Z)/18:1(9Z))"
	"PIM2(16:0/16:2(9Z,12Z))"
	"PIM2(18:0/16:2(9Z,12Z))"
	"PIM2(19:1(9Z)/16:2(9Z,12Z))"
	"PIM2(19:2(9Z,12Z)/18:1(9Z))"
	"PIP(18:3(6Z,9Z,12Z)/18:1(11Z))"
	"PIP(20:3(8Z,11Z,14Z)/16:0)"
	"PIP2(18:0/16:2(9Z,12Z))"
	"PS(20:3(5Z,8Z,11Z)/20:1(11Z))"
	"PS(22:4(7Z,10Z,13Z,16Z)/0:0)"
	"PS(22:4(7Z,10Z,13Z,16Z)/17:2(9Z,12Z))"
	"PS(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/19:1(9Z))"
	"PS(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/20:3(8Z,11Z,14Z))"
	"PS(MonoMe(13,5)/DiMe(9,5))"
	"PS(O-18:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"TG(15:0/20:5(5Z,8Z,11Z,14Z,17Z)/22:5(7Z,10Z,13Z,16Z,19Z))"
	"TG(20:5(5Z,8Z,11Z,14Z,17Z)/15:0/20:5(5Z,8Z,11Z,14Z,17Z))"
	"TG(21:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))[iso3]"
	"TG(22:1(13Z)/15:0/20:4(5Z,8Z,11Z,14Z))"
	"TG(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/o-18:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"Uridine 5'-diphosphate"
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table.
Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.