Validation Log
2025-12-15 02:18:50.185214
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005531/mwtab/json
Study ID:      ST003378
Analysis ID:   AN005531
File format:   json
Status: Contains Validation Issues
Number of Issues: 15

Number of Warnings: 10

Number of Value Errors: 10

Number of Consistency Errors: 2

Number of Format Errors: 1

Issue Log:
Error: The value, "65", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: Unknown or invalid subsection, "SOLVENT_C", in ["CHROMATOGRAPHY"].
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"(10E_12Z)-Hexadeca-10_12-dienoyl-CoA"
	"(13S_17R_20S)-delta14-16-NeuroF[16R_19R]"
	"CL(8:0/8:0/11:0/18:2(9Z_11Z))"
	"Cyclic di-3^_5^-adenylate;Cyclic di-AMP"
	"DAT(19:0/25:0(2Me[S]_3OH[S]_4Me[S]_6Me[S]))"
	"Deoxycorticosterone acetate;21-Acetoxypregn-4-ene-3_20-dione;Percotol"
	"DG(14:1(9Z)/18:4(6Z_9Z_12Z_15Z)/0:0)"
	"DG(15:0/18:3(6Z_9Z_12Z)/0:0)"
	"DG(18:3(6Z_9Z_12Z)/14:0/0:0)"
	"DG(18:3(6Z_9Z_12Z)/16:0/0:0)[iso2]"
	"DG(18:4(6Z_9Z_12Z_15Z)/18:3(9Z_12Z_15Z)/0:0)[iso2]"
	"DG(20:4(5Z_8Z_11Z_14Z)/15:0/0:0)"
	"DG(20:4(5Z_8Z_11Z_14Z)/20:4(5Z_8Z_11Z_14Z)/0:0)"
	"DG(20:5(5Z_8Z_11Z_14Z_17Z)/0:0/20:5(5Z_8Z_11Z_14Z_17Z)) (d5)"
	"dTDP-4-dimethylamino-4_6-dideoxy-5-C-methyl-D-allose"
	"dTDP-4-(methylamino)-2_3_4_6-tetradeoxy-D-glucose;dTDP-4-(methylamino)-2_3_4_6-tetradeoxy-alpha-D-erythro-hexopyranose"
	"ent-15_16-Epoxy-1(10)_13(16)_14-halimatrien-19-oic acid"
	"ent-2alpha_3alpha-Dihydroxyisokaurene"
	"ent-Cassa-12_15-dien-2beta-ol"
	"LysoPA(20:2(11Z_14Z)/0:0)"
	"LysoPE(0:0/24:6(6Z_9Z_12Z_15Z_18Z_21Z))"
	"Methyl 2_3_6-tri-O-galloyl-beta-D-glucopyranoside"
	"MG(0:0/18:4(6Z_9Z_12Z_15Z)/0:0)"
	"MG(0:0/24:6(6Z_9Z_12Z_15Z_18Z_21Z)/0:0)"
	"MG(18:2(9Z_12Z)/0:0/0:0)"
	"MG(18:3(6Z_9Z_12Z)/0:0/0:0)"
	"N-(2^-(4-benzenesulfonamide)-ethyl) arachidonoyl amine"
	"PA(17:2(9Z_12Z)/18:4(6Z_9Z_12Z_15Z))"
	"PA(17:2(9Z_12Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PA(20:2(11Z_14Z)/15:0)"
	"PA(22:2(13Z_16Z)/22:4(7Z_10Z_13Z_16Z))"
	"PA(22:5(4Z_7Z_10Z_13Z_16Z)/22:0)"
	"PA(24:0/18:3(6Z_9Z_12Z))"
	"PA(24:1(15Z)/22:5(4Z_7Z_10Z_13Z_16Z))"
	"PA(P-16:0/18:3(6Z_9Z_12Z))"
	"PA(P-16:0/20:5(5Z_8Z_11Z_14Z_17Z))"
	"PC(14:2(Z)l8_8/0:0)[U]"
	"PC(18:2(9Z_12Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PC(19:3(10Z_13Z_16Z)/0:0)"
	"PC(20:3(8Z_11Z_14Z)/0:0)"
	"PC(20:4(5Z_8Z_11Z_14Z)/0:0)"
	"PC(20:5(5Z_8Z_11Z_14Z_17Z)/18:0)"
	"PC(22:2(13Z_16Z)/24:1(15Z))"
	"PC(22:5(4Z_7Z_10Z_13Z_16Z)/P-18:1(11Z))"
	"PC(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PC(DiMe(11_3)/DiMe(9_5))"
	"PC(P-16:0/22:2(13Z_16Z))"
	"PC(P-20:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PE(18:4(6Z_9Z_12Z_15Z)/18:4(6Z_9Z_12Z_15Z))"
	"PE(20:3(5Z_8Z_11Z)/14:0)"
	"PE(20:3(8Z_11Z_14Z)/0:0)"
	"PE(20:3(8Z_11Z_14Z)/14:1(9Z))"
	"PE(20:4(5Z_8Z_11Z_14Z)/0:0)"
	"PE(22:1(13Z)/18:3(9Z_12Z_15Z))"
	"PE(22:4(7Z_10Z_13Z_16Z)/0:0)"
	"PE(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PE(DiMe(13_5)/DiMe(9_5))"
	"PE(MonoMe(11_5)/MonoMe(11_5))"
	"PG(18:2(9Z_12Z)/0:0)"
	"PG(18:3(6Z_9Z_12Z)/15:0)"
	"PG(18:3(6Z_9Z_12Z)/22:4(7Z_10Z_13Z_16Z))"
	"PG(20:3(8Z_11Z_14Z)/0:0)"
	"PG(20:4(5Z_8Z_11Z_14Z)/0:0)"
	"PG(20:4(5Z_8Z_11Z_14Z)/15:1(9Z))"
	"PG(21:0/22:2(13Z_16Z))"
	"PG(22:2(13Z_16Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PG(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PGP(18:3(6Z_9Z_12Z)/18:3(9Z_12Z_15Z))"
	"PGP(18:3(6Z_9Z_12Z)/22:5(7Z_10Z_13Z_16Z_19Z))"
	"PG(P-20:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PGP(22:5(4Z_7Z_10Z_13Z_16Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PGP(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/20:4(5Z_8Z_11Z_14Z))"
	"PI(12:0/18:4(6Z_9Z_12Z_15Z))"
	"PI(18:3(9Z_12Z_15Z)/0:0)"
	"PI(18:4(6Z_9Z_12Z_15Z)/0:0)"
	"PI(19:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PI(20:3(8Z_11Z_14Z)/0:0)"
	"PI(20:4(5Z_8Z_11Z_14Z)/0:0)"
	"PI(22:0/20:4(5Z_8Z_11Z_14Z))"
	"PI(22:1(11Z)/22:2(13Z_16Z))"
	"PI(22:1(11Z)/22:4(7Z_10Z_13Z_16Z))"
	"PI(22:4(7Z_10Z_13Z_16Z)/0:0)"
	"PI(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PIM1(18:2(9Z_12Z)/16:2(9Z_12Z))"
	"PIM2(18:2(9Z_12Z)/16:2(9Z_12Z))"
	"PI(O-16:0/20:2(11Z_14Z))"
	"PI(O-16:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PI(O-18:0/18:4(6Z_9Z_12Z_15Z))"
	"PI(P-16:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PIP(18:3(6Z_9Z_12Z)/18:1(11Z))"
	"PIP(20:3(8Z_11Z_14Z)/16:0)"
	"PS(17:1(9Z)/22:2(13Z_16Z))"
	"PS(18:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PS(18:4(6Z_9Z_12Z_15Z)/18:4(6Z_9Z_12Z_15Z))"
	"PS(20:2(11Z_14Z)/21:0)"
	"PS(20:3(8Z_11Z_14Z)/0:0)"
	"PS(20:3(8Z_11Z_14Z)/21:0)"
	"PS(21:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"PS(22:2(13Z_16Z)/22:4(7Z_10Z_13Z_16Z))"
	"PS(22:4(7Z_10Z_13Z_16Z)/17:2(9Z_12Z))"
	"PS(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/0:0)"
	"PS(22:6(4Z_7Z_10Z_13Z_16Z_19Z)/18:2(9Z_12Z))"
	"PS(DiMe(11_5)/DiMe(11_3))"
	"PS(DiMe(13_5)/DiMe(13_5))"
	"Purine deoxyribonucleoside;Purine 2^-deoxyribonucleoside"
	"TG(15:0/22:4(7Z_10Z_13Z_16Z)/15:0)"
	"TG(15:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z)/20:5(5Z_8Z_11Z_14Z_17Z))"
	"TG(15:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z)/24:1(15Z))"
	"TG(20:0/18:3(6Z_9Z_12Z)/20:0)"
	"TG(20:1(11Z)/22:5(4Z_7Z_10Z_13Z_16Z)/20:1(11Z))"
	"TG(20:1(11Z)/o-18:0/20:4(5Z_8Z_11Z_14Z))"
	"TG(20:3(5Z_8Z_11Z)/o-18:0/20:3(5Z_8Z_11Z))"
	"TG(20:4(5Z_8Z_11Z_14Z)/22:1(13Z)/20:4(5Z_8Z_11Z_14Z))"
	"TG(20:5(5Z_8Z_11Z_14Z_17Z)/22:2(13Z_16Z)/o-18:0)"
	"TG(20:5(5Z_8Z_11Z_14Z_17Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z)/20:5(5Z_8Z_11Z_14Z_17Z))"
	"TG(20:5(5Z_8Z_11Z_14Z_17Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"TG(21:0/22:5(7Z_10Z_13Z_16Z_19Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))[iso6]"
	"TG(21:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z)/22:6(4Z_7Z_10Z_13Z_16Z_19Z))[iso3]"
	"TG(22:1(13Z)/19:2n6/22:6(4Z_7Z_10Z_13Z_16Z_19Z))"
	"TG(22:2(13Z_16Z)/18:4(6Z_9Z_12Z_15Z)/22:2(13Z_16Z))"
	"TG(22:4(7Z_10Z_13Z_16Z)/o-18:0/22:4(7Z_10Z_13Z_16Z))"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"(10E,12Z)-Hexadeca-10,12-dienoyl-CoA"
	"(13S,17R,20S)-delta14-16-NeuroF[16R,19R]"
	"CL(8:0/8:0/11:0/18:2(9Z,11Z))"
	"Cyclic di-3',5'-adenylate;Cyclic di-AMP"
	"DAT(19:0/25:0(2Me[S],3OH[S],4Me[S],6Me[S]))"
	"Deoxycorticosterone acetate;21-Acetoxypregn-4-ene-3,20-dione;Percotol"
	"DG(14:1(9Z)/18:4(6Z,9Z,12Z,15Z)/0:0)"
	"DG(15:0/18:3(6Z,9Z,12Z)/0:0)"
	"DG(18:3(6Z,9Z,12Z)/14:0/0:0)"
	"DG(18:3(6Z,9Z,12Z)/16:0/0:0)[iso2]"
	"DG(18:4(6Z,9Z,12Z,15Z)/18:3(9Z,12Z,15Z)/0:0)[iso2]"
	"DG(20:4(5Z,8Z,11Z,14Z)/15:0/0:0)"
	"DG(20:4(5Z,8Z,11Z,14Z)/20:4(5Z,8Z,11Z,14Z)/0:0)"
	"DG(20:5(5Z,8Z,11Z,14Z,17Z)/0:0/20:5(5Z,8Z,11Z,14Z,17Z)) (d5)"
	"dTDP-4-dimethylamino-4,6-dideoxy-5-C-methyl-D-allose"
	"dTDP-4-(methylamino)-2,3,4,6-tetradeoxy-D-glucose;dTDP-4-(methylamino)-2,3,4,6-tetradeoxy-alpha-D-erythro-hexopyranose"
	"ent-15,16-Epoxy-1(10),13(16),14-halimatrien-19-oic acid"
	"ent-2alpha,3alpha-Dihydroxyisokaurene"
	"ent-Cassa-12,15-dien-2beta-ol"
	"LysoPA(20:2(11Z,14Z)/0:0)"
	"LysoPE(0:0/24:6(6Z,9Z,12Z,15Z,18Z,21Z))"
	"Methyl 2,3,6-tri-O-galloyl-beta-D-glucopyranoside"
	"MG(0:0/18:4(6Z,9Z,12Z,15Z)/0:0)"
	"MG(0:0/24:6(6Z,9Z,12Z,15Z,18Z,21Z)/0:0)"
	"MG(18:2(9Z,12Z)/0:0/0:0)"
	"MG(18:3(6Z,9Z,12Z)/0:0/0:0)"
	"N-(2'-(4-benzenesulfonamide)-ethyl) arachidonoyl amine"
	"PA(17:2(9Z,12Z)/18:4(6Z,9Z,12Z,15Z))"
	"PA(17:2(9Z,12Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PA(20:2(11Z,14Z)/15:0)"
	"PA(22:2(13Z,16Z)/22:4(7Z,10Z,13Z,16Z))"
	"PA(22:5(4Z,7Z,10Z,13Z,16Z)/22:0)"
	"PA(24:0/18:3(6Z,9Z,12Z))"
	"PA(24:1(15Z)/22:5(4Z,7Z,10Z,13Z,16Z))"
	"PA(P-16:0/18:3(6Z,9Z,12Z))"
	"PA(P-16:0/20:5(5Z,8Z,11Z,14Z,17Z))"
	"PC(14:2(Z)l8,8/0:0)[U]"
	"PC(18:2(9Z,12Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PC(19:3(10Z,13Z,16Z)/0:0)"
	"PC(20:3(8Z,11Z,14Z)/0:0)"
	"PC(20:4(5Z,8Z,11Z,14Z)/0:0)"
	"PC(20:5(5Z,8Z,11Z,14Z,17Z)/18:0)"
	"PC(22:2(13Z,16Z)/24:1(15Z))"
	"PC(22:5(4Z,7Z,10Z,13Z,16Z)/P-18:1(11Z))"
	"PC(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PC(DiMe(11,3)/DiMe(9,5))"
	"PC(P-16:0/22:2(13Z,16Z))"
	"PC(P-20:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PE(18:4(6Z,9Z,12Z,15Z)/18:4(6Z,9Z,12Z,15Z))"
	"PE(20:3(5Z,8Z,11Z)/14:0)"
	"PE(20:3(8Z,11Z,14Z)/0:0)"
	"PE(20:3(8Z,11Z,14Z)/14:1(9Z))"
	"PE(20:4(5Z,8Z,11Z,14Z)/0:0)"
	"PE(22:1(13Z)/18:3(9Z,12Z,15Z))"
	"PE(22:4(7Z,10Z,13Z,16Z)/0:0)"
	"PE(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PE(DiMe(13,5)/DiMe(9,5))"
	"PE(MonoMe(11,5)/MonoMe(11,5))"
	"PG(18:2(9Z,12Z)/0:0)"
	"PG(18:3(6Z,9Z,12Z)/15:0)"
	"PG(18:3(6Z,9Z,12Z)/22:4(7Z,10Z,13Z,16Z))"
	"PG(20:3(8Z,11Z,14Z)/0:0)"
	"PG(20:4(5Z,8Z,11Z,14Z)/0:0)"
	"PG(20:4(5Z,8Z,11Z,14Z)/15:1(9Z))"
	"PG(21:0/22:2(13Z,16Z))"
	"PG(22:2(13Z,16Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PG(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PGP(18:3(6Z,9Z,12Z)/18:3(9Z,12Z,15Z))"
	"PGP(18:3(6Z,9Z,12Z)/22:5(7Z,10Z,13Z,16Z,19Z))"
	"PG(P-20:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PGP(22:5(4Z,7Z,10Z,13Z,16Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PGP(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/20:4(5Z,8Z,11Z,14Z))"
	"PI(12:0/18:4(6Z,9Z,12Z,15Z))"
	"PI(18:3(9Z,12Z,15Z)/0:0)"
	"PI(18:4(6Z,9Z,12Z,15Z)/0:0)"
	"PI(19:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PI(20:3(8Z,11Z,14Z)/0:0)"
	"PI(20:4(5Z,8Z,11Z,14Z)/0:0)"
	"PI(22:0/20:4(5Z,8Z,11Z,14Z))"
	"PI(22:1(11Z)/22:2(13Z,16Z))"
	"PI(22:1(11Z)/22:4(7Z,10Z,13Z,16Z))"
	"PI(22:4(7Z,10Z,13Z,16Z)/0:0)"
	"PI(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PIM1(18:2(9Z,12Z)/16:2(9Z,12Z))"
	"PIM2(18:2(9Z,12Z)/16:2(9Z,12Z))"
	"PI(O-16:0/20:2(11Z,14Z))"
	"PI(O-16:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PI(O-18:0/18:4(6Z,9Z,12Z,15Z))"
	"PI(P-16:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PIP(18:3(6Z,9Z,12Z)/18:1(11Z))"
	"PIP(20:3(8Z,11Z,14Z)/16:0)"
	"PS(17:1(9Z)/22:2(13Z,16Z))"
	"PS(18:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PS(18:4(6Z,9Z,12Z,15Z)/18:4(6Z,9Z,12Z,15Z))"
	"PS(20:2(11Z,14Z)/21:0)"
	"PS(20:3(8Z,11Z,14Z)/0:0)"
	"PS(20:3(8Z,11Z,14Z)/21:0)"
	"PS(21:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"PS(22:2(13Z,16Z)/22:4(7Z,10Z,13Z,16Z))"
	"PS(22:4(7Z,10Z,13Z,16Z)/17:2(9Z,12Z))"
	"PS(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/0:0)"
	"PS(22:6(4Z,7Z,10Z,13Z,16Z,19Z)/18:2(9Z,12Z))"
	"PS(DiMe(11,5)/DiMe(11,3))"
	"PS(DiMe(13,5)/DiMe(13,5))"
	"Purine deoxyribonucleoside;Purine 2'-deoxyribonucleoside"
	"TG(15:0/22:4(7Z,10Z,13Z,16Z)/15:0)"
	"TG(15:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z)/20:5(5Z,8Z,11Z,14Z,17Z))"
	"TG(15:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z)/24:1(15Z))"
	"TG(20:0/18:3(6Z,9Z,12Z)/20:0)"
	"TG(20:1(11Z)/22:5(4Z,7Z,10Z,13Z,16Z)/20:1(11Z))"
	"TG(20:1(11Z)/o-18:0/20:4(5Z,8Z,11Z,14Z))"
	"TG(20:3(5Z,8Z,11Z)/o-18:0/20:3(5Z,8Z,11Z))"
	"TG(20:4(5Z,8Z,11Z,14Z)/22:1(13Z)/20:4(5Z,8Z,11Z,14Z))"
	"TG(20:5(5Z,8Z,11Z,14Z,17Z)/22:2(13Z,16Z)/o-18:0)"
	"TG(20:5(5Z,8Z,11Z,14Z,17Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z)/20:5(5Z,8Z,11Z,14Z,17Z))"
	"TG(20:5(5Z,8Z,11Z,14Z,17Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"TG(21:0/22:5(7Z,10Z,13Z,16Z,19Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))[iso6]"
	"TG(21:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))[iso3]"
	"TG(22:1(13Z)/19:2n6/22:6(4Z,7Z,10Z,13Z,16Z,19Z))"
	"TG(22:2(13Z,16Z)/18:4(6Z,9Z,12Z,15Z)/22:2(13Z,16Z))"
	"TG(22:4(7Z,10Z,13Z,16Z)/o-18:0/22:4(7Z,10Z,13Z,16Z))"
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table.
Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.