Validation Log 2025-12-15 02:21:20.755471 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005587/mwtab/txt Study ID: ST003404 Analysis ID: AN005587 File format: txt Status: Contains Validation Issues Number of Issues: 26 Number of Warnings: 23 Number of Value Errors: 24 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "0.15ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "25", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: Unknown or invalid section, "FACTORS". Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Factors: "Sample source" Warning: The "Quantified m/z" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem ID" column at position 4 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG ID" column at position 5 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Retention Index" column at position 2 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "Retention Index" was found in the METABOLITES table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found.