Validation Log 2025-12-15 02:23:38.766922 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005614/mwtab/json Study ID: ST003415 Analysis ID: AN005614 File format: json Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 4 Number of Value Errors: 9 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["FLOW_GRADIENT"]. A legitimate value should be provided for this required key. Error: The value, "none", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_A"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_B"]. A legitimate value should be provided for this required key. Warning: The "m/z" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Mol. Mass" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RefMet" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "refmet", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 3 Bendiocarb 5 Benzyl salicylate 7 Bis(2-ethylhexyl)phthalate 8 Bisphenol A 9 2,6-Di-tert-butyl-4-methylphenol 11 Cinnamyl alcohol 13 N,N-Diethyl-m-toluamide 14 Dioctyl phthalate 15 Diflubenzuron 17 Estrone 18 Furmecyclox 24 Phenanthrene 27 Progesterone 33 Testosterone 34 Tributyl phosphate Warning: The "RT_sec" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.