Validation Log
2025-12-15 02:25:05.008507
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005641/mwtab/json
Study ID:      ST003434
Analysis ID:   AN005641
File format:   json
Status: Contains Validation Issues
Number of Issues: 33

Number of Warnings: 10

Number of Value Errors: 29

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: The value, "Single dose, 6 h monitoring", in ["TREATMENT"]["TREATMENT_DOSEDURATION"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['h', 'weeks', 'days']. Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected in ["SAMPLEPREP"]["EXTRACT_ENRICHMENT"]. Either a legitimate value should be provided for this key, or it should be removed altogether.
Error: An empty value or a null value was detected in ["SAMPLEPREP"]["EXTRACT_CLEANUP"]. Either a legitimate value should be provided for this key, or it should be removed altogether.
Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLE_RESUSPENSION"]. Either a legitimate value should be provided for this key, or it should be removed altogether.
Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLE_DERIVATIZATION"]. Either a legitimate value should be provided for this key, or it should be removed altogether.
Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLE_SPIKING"]. Either a legitimate value should be provided for this key, or it should be removed altogether.
Error: The value, "500 °C", in ["MS"]["CAPILLARY_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "-4500", in ["MS"]["CAPILLARY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required.
Error: The value, "70", in ["MS"]["DRY_GAS_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required.
Error: The value, "500 °C", in ["MS"]["DRY_GAS_TEMP"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "500 °C", in ["MS"]["ION_SOURCE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "-4500", in ["MS"]["ION_SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required.
Error: The value, "500 °C", in ["MS"]["SOURCE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "-4500", in ["MS"]["SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['kV']. Ignore this when more complicated descriptions are required.
Error: The value, "70", in ["MS"]["DESOLVATION_GAS_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required.
Error: The value, "500 °C", in ["MS"]["DESOLVATION_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "40", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "1-5 ul", in ["CHROMATOGRAPHY"]["SAMPLE_INJECTION"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required.
Error: The value, "4", in ["CHROMATOGRAPHY"]["INJECTION_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required.
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"Fructose-1_6-bisphosphate 177"
	"Fructose-1_6-bisphosphate 97"
	"Glucono-1_5-lactone 129"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"Fructose-1,6-bisphosphate 177"
	"Fructose-1,6-bisphosphate 97"
	"Glucono-1,5-lactone 129"
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table.
Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.