Validation Log 2025-12-15 02:25:33.448153 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005649/mwtab/txt Study ID: ST003438 Analysis ID: AN005649 File format: txt Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 6 Number of Value Errors: 8 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: The value, "250 µL/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "30C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "MZ" column at position 2 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB_ID_specificity (1=match,2=representative)" column at position 5 in the METABOLITES table, matches a standard column name, "mass_spectrum". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB_ID_specificity (1=match,2=representative)" column at position 5 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB_ID_specificity (1=match,2=representative)" column at position 5 in the METABOLITES table, matches a standard column name, "hmdb_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 5 1 8 1 9 1 10 1 11 1 12 1 13 1 14 1 15 1 16 2 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 1 29 1 30 1 31 1 32 1 33 1 34 1 35 1 36 1 37 1 38 1 39 1 40 1 41 1 42 1 43 1 44 1 45 1 46 1 47 1 48 1 49 1 50 1 51 1 52 1 53 1 54 1 55 1 56 1 57 1 58 1 59 1 60 1 61 1 62 1 63 1 64 1 65 1 66 1 67 1 68 1 69 1 70 1 71 1 72 1 73 1 74 1 75 1 76 1 77 1 78 1 79 1 80 1 81 1 82 1 83 1 84 1 85 1 86 1 87 1 88 1 89 1 90 1 91 1 92 1 93 1 94 2 95 1 96 1 97 1 98 1 99 1 100 1 101 1 102 1 103 1 104 1 105 1 106 1 107 1 108 1 109 1 110 1 111 1 112 1 113 1 114 1 115 1 117 1 118 1 119 1 120 1 122 1 123 1 124 1 125 1 126 1 127 1 128 1 129 1 130 1 131 1 132 1 133 1 134 1 135 1 137 1 138 1 139 1 140 1 141 1 142 1 143 1 144 1 145 1 146 1 147 1 148 1 149 1 150 1 151 1 152 1 153 1 154 1 155 1 156 1 157 1 158 1 159 1 160 1 162 1 163 1 164 1 165 1 166 1 167 1 168 2 169 2 170 1 171 1 172 2 173 2 174 2 175 2 176 2 177 2 178 0 179 2 180 1 181 2 182 2 183 2 184 1 185 1 186 1 187 2 188 2 189 2 190 2 192 2 193 2 194 2 195 2 196 2 197 2 198 2 199 1 200 2 201 2 202 0 203 2 204 2 205 0 206 2 207 2 208 2 209 1 210 2 211 2 212 2 213 2 214 2 215 2 216 2 217 1 218 1 219 2 220 1 221 2 222 2 223 2 224 1 225 2 226 2 227 2 228 2 229 2 230 2 231 2 232 2 233 2 234 1 235 2 236 2 237 2 238 2 239 2 240 2 241 2 242 2 243 2 247 1 248 1 250 2 251 1 252 1 254 2 255 1 260 1 261 1 262 1 263 1 264 1 270 1 Warning: The "RT" column at position 3 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column, "HMDB_ID_specificity (1=match,2=representative)", in the METABOLITES table was matched to multiple standard names, ['mass_spectrum', 'hmdb_id']. This is a good indication that the values in that column should be split into the appropriate individual columns.