Validation Log 2026-03-15 06:52:58.225948 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005737/mwtab/json Study ID: ST003496 Analysis ID: AN005737 File format: json Status: Contains Validation Issues Number of Issues: 11 Number of Warnings: 9 Number of Value Errors: 11 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "Male and female", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The value, "45", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 11 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RefMet" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "refmet", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 Ciliatine 1 1-Aminocyclopropanecarboxylic acid 2 1-Methylhistidine 3 1-Methyladenosine 4 N-Acetyl-beta-glucosaminylamine 5 Quinaldic acid 6 2,6-Dihydroxypyridine 7 3-Hydroxyphenylacetic acid 8 3-Methoxytyramine 9 3-Methylhistidine 10 3-Methyladenine 11 3-Methylbut-2-enoyl-CoA 12 3-Sulfino-alanine 13 Hydroxykynurenine 14 4-Acetamidobutanoic acid 15 4-Guanidinobutanoic acid 16 4-Hydroxyphenylglycine 17 Imidazoleacetic acid 18 4-Pyridoxic acid 19 4-Quinolinecarboxylic acid 20 5-Amino-levulinic acid 21 5-Aminopentanoic acid 22 5-Hydroxy-tryptophan 23 5-Hydroxyindoleacetic acid 24 5-Methylcytosine 25 5-Valerolactone 26 5''-Deoxyadenosine 27 Adenine 28 Adenosine 29 2'',3'' cyclic AMP 30 Adenosine 3'',5''-diphosphate 31 ADP 32 ADP-ribose 33 ATP 34 AMP 35 AICAR 36 Alanine 37 Allothreonine 38 Aminoadipic acid 39 Anserine 40 Arginine 41 Argininosuccinic acid 42 Asparagine 43 Aspartic acid 44 Benzylamine 45 beta-Alanine 46 NAD 47 Betaine 48 Bilirubin 49 Biliverdin 50 Biotin 51 Carnosine 52 CDP-Ethanolamine 53 cis-4-Hydroxy-D-proline 54 CDP-choline 55 Citrulline 56 Cortisol 57 Cortisol 21-acetate 58 Creatine 59 Creatinine 60 3'',5'' cyclic AMP 61 Cystathionine 62 Cytidine 63 2'',3'' cyclic CMP 64 Cytosine 65 D-Alanine 66 2-Amino-2-deoxy-D-mannose 67 Deoxyadenosine 68 dAMP 69 dATP 70 3-Dehydroxycarnitine 71 Deoxycytidine 72 dCMP 73 dCDP 74 Deoxyguanosine 75 dGMP 76 2,6-Diaminopimelic acid 77 LPC 12:0 78 Diethanolamine 79 4a-Carbinolamine tetrahydrobiopterin 80 Epinephrine 81 Ethyl 3-indoleacetate 82 FAD 83 Folic acid 84 Galactosamine 85 gamma-Aminobutyric acid 86 Glutamine 87 Glucosaminic acid 88 Glucosamine 89 Glucosamine 6-phosphate 90 Glutamic acid 91 Glutamine 92 CAR DC5:0 93 Glutathione 94 Glycine 95 Glutathione 96 Oxidized glutathione 97 Guanidoacetic acid 98 Guanidinosuccinic acid 99 Guanine 100 Guanosine 101 GMP 102 Histamine 103 Histidine 104 L-Histidinol 105 Homocysteine 106 L-Homocysteine thiolactone 107 Homoserine 108 Hydroxykynurenine 109 Hypotaurine 110 Hypoxanthine 111 1H-Indole-3-acetamide 112 Indoleacetic acid 113 Tryptophanol 114 Indole-3-methyl acetate 115 Inosine 116 IMP 117 Isoleucine 118 Kynurenic acid 119 Kynurenine 120 Carnitine 121 Tryptophanamide 122 Lactose 123 CAR 12:0 124 Leucine 125 Lipoamide 126 Lumichrome 127 Lysine 128 Maleimide 129 Melatonin 130 Methionine 131 Methionine sulfoximine 132 Methyl 4-aminobutanoate 133 Methylthioadenosine 134 N-Acetylasparagine 135 N-Acetylgalactosamine 136 N-Acetylglucosamine 137 N-Acetylglutamic acid 138 N-Acetyl-mannosamine 139 N-Acetylneuraminic acid 140 N-Acetylphenylalanine 141 N-Acetyl-proline 142 N-Acetylputrescine 143 N-Acetylserotonin 144 N-Acetyl-tryptophan 145 N(2)-Acetyllysine 146 N-Methyl-D-aspartic acid 147 N-Methyl-glutamic acid 148 N-Methyltryptamine 149 Dimethylarginine 150 N-6-Trimethyllysine 151 N6-Isopentenyladenine 152 NAD 153 NADH 154 NADP 155 NADPH 156 Niacinamide 157 Nicotinamide purin-6-ol-dinucleotide 158 Nicotinamide ribotide 159 Nicotinic acid 160 Norleucine 161 Normetanephrine 162 Norvaline 163 CAR 2:0 164 Phosphoethanolamine 165 DL-O-Phosphoserine 166 o-Succinylhomoserine 167 Ophthalmic acid 168 Ornithine 169 CAR 16:0 170 Pantothenic acid 171 Paraxanthine 172 Phenylalanine 173 Phosphoserine 174 Pipecolic acid 175 Porphobilinogen 176 Proline 177 Pterin 178 Purine 179 Pyridoxal 180 Pyridoxamine 181 Pyridoxine 182 Riboflavin 183 S-Adenosylhomocysteine 184 S-Adenosylmethionine 185 S-Adenosylhomocysteine 186 S-Adenosylmethionine 187 S-Carboxymethyl-cysteine 188 Salsolinol 189 Sarcosine 190 Serine 191 Serotonin 192 Taurine 193 Theobromine 194 Theophylline 195 Thiamine monophosphate 196 Thiamine diphosphate 197 6-Methylthiopurine 198 Thiourea 199 Threonine 200 Thymine 201 Thyrotropin releasing hormone 202 trans-4-Hydroxyproline 203 Cinnamaldehyde 204 Trigonelline 205 Tryptamine 206 Tryptophan 207 Tyramine 208 Tyrosine 209 Ureidopropionic acid 210 Urocanic acid 211 Valine 212 Xanthosine 213 Xanthurenic acid Warning: The "PubChem_CID" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS_ID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS_ID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 3 5063510 5 34249 22 895096 24 -491605 29 -462388 57 18325 67 -343801 74 -342766 75 -364411 85 20791 132 20791 157 -17709 165 5838619 203 4555222 Warning: The "ChEBI" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "chebi_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.