Validation Log 2026-03-15 06:53:01.662541 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005738/mwtab/json Study ID: ST003496 Analysis ID: AN005738 File format: json Status: Contains Validation Issues Number of Issues: 12 Number of Warnings: 10 Number of Value Errors: 12 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "Male and female", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The value, "45", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 11 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "SMILES" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "smiles", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 17 C1=CC(=C(C=C1C(=O)O)N)O'' 96 C1(C(C(OC(C1O)O)C(=O)O)O)O'' 148 O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]... 149 O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]... Warning: The "RefMet" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "refmet", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 2-Aminophenol 1 2-Deoxy-glucose 2 2-Deoxy-glucose 3 2-Hydroxy-4-(methylthio)butanoic acid 4 2-Hydroxybutyric acid 5 2-Dehydro-3-deoxy-D-gluconic acid 6 2-Methylglutaric acid 7 Citraconic acid 8 2-Phosphoglyceric acid 9 2-Pyrocatechuic acid 10 Lumazine 11 Gentisic acid 12 2'',4''-Dihydroxyacetophenone 13 2-Hydroxyglutaric acid 14 3-(2-Hydroxyphenyl)propanoic acid 15 4-Hydroxyphenylpyruvic acid 16 Tetrahydrocortisol 17 3-Amino-4-hydroxybenzoic acid 18 3-Dehydroshikimate 19 3-Hydroxybenzoic acid 20 3-Hydroxybenzyl alcohol 21 3-Hydroxymethylglutaric acid 22 Hydroxypyruvic acid 23 Vanillylmandelic acid 24 3-Methyloxindole 25 3-Methyl-2-oxovaleric acid 26 3E-Methylglutaconic acid 27 Nitrotyrosine 28 3-Phosphoglyceric acid 29 3,4-Dihydroxymandelic acid 30 Protocatechuic acid 31 3,4-Dihydroxybenzeneacetic acid 32 3,4-Dihydroxyphenylglycol 33 p-Aminobenzoic acid 34 Vanylglycol 35 4-Hydroxybenzaldehyde 36 4-Hydroxybenzoic acid 37 4-Methylcatechol 38 5-Hydroxylysine 39 Pimelic acid 40 6-Phosphogluconic acid 41 Acetoin 42 Acetyl-CoA 43 Adipic acid 44 ADP 45 ADP-glucose 46 2-Oxoglutaric acid 47 Allantoin 48 Allose 49 Glucose 50 AMP 51 2-Aminobenzenesulfonic acid 52 Arabitol 53 ATP 54 Azelaic acid 55 Benzoic acid 56 sn-Glycero-2-phosphate 57 Butyric acid 58 Caffeic acid 59 Cellobiose 60 cis-Aconitic acid 61 Citramalic acid 62 Citric acid 63 Coenzyme A 64 3'',5'' cyclic GMP 65 Cys-Gly 66 Cysteic acid 67 Cysteine 68 Cystine 69 CDP 70 CMP 71 Glucuronolactone 72 Pinitol 73 Ribose 5-phosphate 74 Sedoheptulose 75 L-Dehydroascorbic acid 76 Deoxyuridine 77 dUTP 78 dUMP 79 Dethiobiotin 80 dGDP 81 4,5-Dihydroorotic acid 82 Dihydrouracil 83 Dihydroxyacetone phosphate 84 dTDP-glucose 85 Erythritol 86 Ethylmalonic acid 87 trans-Ferulic acid 88 Fructose 89 Fructose 1,6-bisphosphate 90 Fructose 6-phosphate 91 Fumaric acid 92 Galactaric acid 93 Galactitol 94 Galactose 95 Galactose 1-phosphate 96 Galacturonic acid 97 GDP 98 Geranyl diphosphate 99 Gluconic acid 100 Gluconolactone 101 Glucosamine 6-sulfate 102 Glucose 103 Glucose 1-phosphate 104 Glucose 6-phosphate 105 Glucuronic acid 106 Glutaric acid 107 Glyceric acid 108 sn-Glycero-3-phosphate 109 Glycochenodeoxycholic acid 110 Glycocholic acid 111 GMP 112 GTP 113 GDP 114 GDP-mannose 115 Gulose 116 Hippuric acid 117 Homogentisic acid 118 Homovanillic acid 119 Hydroxyphenyllactic acid 120 Hydroquinone 121 Hydroxyphenyllactic acid 122 Hydroxypyruvic acid 123 IMP 124 Indolepyruvate 125 Indoleacetaldehyde 126 Indoxyl sulfate 127 Indican 128 Isocitric acid 129 Isopentenyl-diphosphate 130 Itaconic acid 131 L-Gulonolactone 132 Lactic acid 133 Malic acid 134 Maleic acid 135 Malonic acid 136 Maltose 137 Mannitol 138 Mannose 139 Mannose 6-phosphate 140 Melibiose 141 3-Mercaptopyruvic acid 142 Mesoxalic acid 143 Methylglutaric acid 144 Methyl beta-D-galactoside 145 Methylmalonic acid 146 Mevalonic acid 147 Monomethyl glutaric acid 148 Myo-inositol 149 Myo-inositol 150 N-Acetylalanine 151 N-Acetylaspartic acid 152 N-Acetylcysteine 153 N-Acetylglycine 154 N-Acetylleucine 155 N-Acetylmethionine 156 N-Acetylserine 157 N-Formylmethionine 158 N-Formylglycine 159 Nicotinic acid 160 O-Acetylserine 161 Orotic acid 162 Oxalic acid 163 2-Oxoadipic acid 164 2-Oxoglutaric acid 165 Oxoproline 166 4-Hydroxyphenylacetic acid 167 Palatinose 168 Palmitic acid 169 Palmitoleic acid 170 Phosphoenolpyruvic acid 171 Pregnenolone sulfate 172 Psicose 173 Pyridoxal 5''-phosphate 174 Pyrocatechol 175 Pyroglutamic acid 176 Pyrrole-2-carboxylic acid 177 Pyruvic acid 178 Quinic acid 179 Quinolinic acid 180 Raffinose 181 Ribitol 182 Ribose 5-phosphate 183 Ribose 5-phosphate 184 Ribulose 5-phosphate 185 Glucaric acid 186 Salicylamide 187 Salicylic acid 188 Sebacic acid 189 Sedoheptulose 7-phosphate 190 Shikimic acid 191 Sorbic acid 192 Sorbitol 193 Sorbose 194 Stachyose 195 Suberic acid 196 Succinic acid 197 Sucrose 198 D-Tagatose 199 Tartaric acid 200 Threitol 201 Thymidine 202 dTMP 203 trans-Aconitic acid 204 Trehalose 205 UDP 206 UDP-N-acetylglucosamine 207 UMP 208 Uracil 209 Uracil-5-carboxylic acid 210 Uric acid 211 Uridine 212 UDP 213 UDP-glucose 214 UDP-glucuronic acid 215 UDP-N-acetylgalactosamine 216 UDP-N-acetylglucosamine 217 UDP-galactose 218 UMP 219 UTP 220 Xanthine 221 XMP 222 Xylitol 223 Xylulose 5-phosphate Warning: The "PubChem_CID" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS_ID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS_ID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 16 19391 19 36320 23 20369 24 -144465 28 -394151 29 -410884 43 -648571 80 582078 82 -509690 105 1700908 108 20883 118 -581982 124 -550448 131 1615286 145 -505370 202 -560463 216 -501018 Warning: The "ChEBI" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "chebi_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.