Validation Log 2025-12-15 02:31:40.257660 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005785/mwtab/json Study ID: ST003523 Analysis ID: AN005785 File format: json Status: Contains Validation Issues Number of Issues: 11 Number of Warnings: 9 Number of Value Errors: 11 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "Not applicable", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The value, "45", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 12 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RefMet" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "refmet", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 1-Methylhistidine 1 1-Methyladenosine 2 N-Acetyl-beta-glucosaminylamine 3 Quinaldic acid 4 2,6-Dihydroxypyridine 5 3-Hydroxyphenylacetic acid 6 3-Methoxytyramine 7 3-Methylhistidine 8 3-Methyladenine 9 3-Methylbut-2-enoyl-CoA 10 3-Sulfino-alanine 11 Hydroxykynurenine 12 4-Acetamidobutanoic acid 13 4-Guanidinobutanoic acid 14 Imidazoleacetic acid 15 4-Pyridoxic acid 16 4-Quinolinecarboxylic acid 17 5-Aminopentanoic acid 18 5-Hydroxyindoleacetic acid 19 5-Methylcytosine 20 5-Methylcytosine 21 5-Methylcytosine 22 5-Methylcytosine 23 5-Methylcytosine 24 5-Valerolactone 25 5''-Deoxyadenosine 26 Adenine 27 Adenine 28 Adenine 29 Adenosine 30 ADP 31 ADP-ribose 32 ATP 33 AMP 34 AICAR 35 Alanine 36 Alanine 37 Alanine 38 Alanine 39 Allothreonine 40 Aminoadipic acid 41 Anserine 42 Arginine 43 Arginine 44 Arginine 45 Arginine 46 Argininosuccinic acid 47 Argininosuccinic acid 48 Argininosuccinic acid 49 Argininosuccinic acid 50 Argininosuccinic acid 51 Argininosuccinic acid 52 Argininosuccinic acid 53 Argininosuccinic acid 54 Asparagine 55 Asparagine 56 Asparagine 57 Asparagine 58 Asparagine 59 Aspartic acid 60 Aspartic acid 61 Aspartic acid 62 Aspartic acid 63 Aspartic acid 64 Benzylamine 65 beta-Alanine 66 NAD 67 Betaine 68 Biotin 69 Carnosine 70 CDP-Ethanolamine 71 CDP-choline 72 Citrulline 73 Cortisol 74 Cortisol 21-acetate 75 Creatine 76 Creatine 77 Creatine 78 Creatinine 79 Cystathionine 80 Cystathionine 81 Cystathionine 82 Cytidine 83 2'',3'' cyclic CMP 84 Cytosine 85 D-Alanine 86 2-Amino-2-deoxy-D-mannose 87 Deoxyadenosine 88 dAMP 89 dATP 90 Deoxycytidine 91 dCMP 92 dGMP 93 2,6-Diaminopimelic acid 94 Diethanolamine 95 4a-Carbinolamine tetrahydrobiopterin 96 Ethyl 3-indoleacetate 97 FAD 98 Folic acid 99 Galactosamine 100 gamma-Aminobutyric acid 101 gamma-Aminobutyric acid 102 gamma-Aminobutyric acid 103 gamma-Aminobutyric acid 104 gamma-Aminobutyric acid 105 Glutamine 106 Glutamine 107 Glutamine 108 Glutamine 109 Glutamine 110 Glutamine 111 Glucosaminic acid 112 Glucosamine 113 Glucosamine 6-phosphate 114 Glucosamine 6-phosphate 115 Glucosamine 6-phosphate 116 Glutamic acid 117 Glutamic acid 118 Glutamic acid 119 Glutamic acid 120 Glutamic acid 121 Glutamic acid 122 Glutamine 123 CAR DC5:0 124 Glutathione 125 Glutathione 126 Glutathione 127 Glutathione 128 Glutathione 129 Glutathione 130 Glutathione 131 Glutathione 132 Glutathione 133 Glutathione 134 Glutathione 135 Glycine 136 Glycine 137 Glycine 138 Glutathione 139 Glutathione 140 Glutathione 141 Glutathione 142 Glutathione 143 Glutathione 144 Glutathione 145 Glutathione 146 Glutathione 147 Oxidized glutathione 148 Guanidoacetic acid 149 Guanidinosuccinic acid 150 Guanine 151 Guanosine 152 GMP 153 Histamine 154 Histidine 155 L-Histidinol 156 Homocysteine 157 Homocysteine 158 Homocysteine 159 Homocysteine 160 Homocysteine 161 L-Homocysteine thiolactone 162 Hydroxykynurenine 163 Hypotaurine 164 Hypotaurine 165 Hypotaurine 166 Hypoxanthine 167 1H-Indole-3-acetamide 168 Indoleacetic acid 169 Tryptophanol 170 Indole-3-methyl acetate 171 Inosine 172 IMP 173 Isoleucine 174 Kynurenine 175 Carnitine 176 Carnitine 177 Carnitine 178 Carnitine 179 Carnitine 180 Carnitine 181 Carnitine 182 Tryptophanamide 183 Lactose 184 CAR 12:0 185 Leucine 186 Leucine 187 Leucine 188 Lipoamide 189 Lumichrome 190 Lysine 191 Maleimide 192 Melatonin 193 Methionine 194 Methionine 195 Methionine 196 Methionine 197 Methionine 198 Methionine 199 Methionine 200 Methionine 201 Methionine sulfoximine 202 Methyl 4-aminobutanoate 203 Methylthioadenosine 204 N-Acetylasparagine 205 N-Acetylgalactosamine 206 N-Acetylglucosamine 207 N-Acetylglutamic acid 208 N-Acetyl-mannosamine 209 N-Acetylneuraminic acid 210 N-Acetylphenylalanine 211 N-Acetylserotonin 212 N-Acetyl-tryptophan 213 N(2)-Acetyllysine 214 N-Methyl-D-aspartic acid 215 N-Methyl-glutamic acid 216 N-Methyltryptamine 217 N-Methylalanine 218 Dimethylarginine 219 N-6-Trimethyllysine 220 N6-Isopentenyladenine 221 NAD 222 NADH 223 NADP 224 NADPH 225 Niacinamide 226 Nicotinamide purin-6-ol-dinucleotide 227 Nicotinamide ribotide 228 Nicotinic acid 229 Norleucine 230 Normetanephrine 231 Norvaline 232 CAR 2:0 233 Phosphoethanolamine 234 DL-O-Phosphoserine 235 o-Succinylhomoserine 236 Ophthalmic acid 237 Ornithine 238 Ornithine 239 Ornithine 240 Ornithine 241 Ornithine 242 CAR 16:0 243 Pantothenic acid 244 Paraxanthine 245 Phenylalanine 246 Phosphoserine 247 Pipecolic acid 248 Proline 249 Proline 250 Proline 251 Proline 252 Proline 253 Proline 254 Pterin 255 Purine 256 Pyridoxal 257 Pyridoxamine 258 Pyridoxine 259 Riboflavin 260 S-Adenosylhomocysteine 261 S-Adenosylmethionine 262 S-Adenosylhomocysteine 263 S-Adenosylmethionine 264 Salsolinol 265 Sarcosine 266 Serine 267 Serine 268 Serine 269 Serine 270 Serotonin 271 Taurine 272 Taurine 273 Taurine 274 Theobromine 275 Theophylline 276 Thiamine monophosphate 277 Thiamine diphosphate 278 6-Methylthiopurine 279 Thiourea 280 Threonine 281 Thymine 282 Thyrotropin releasing hormone 283 Cinnamaldehyde 284 Trigonelline 285 Tryptamine 286 Tryptophan 287 Tryptophan 288 Tryptophan 289 Tryptophan 290 Tyrosine 291 Tyrosine 292 Tyrosine 293 Tyrosine 294 Ureidopropionic acid 295 Urocanic acid 296 Valine 297 Valine 298 Valine 299 Xanthosine Warning: The "PubChem_CID" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS_ID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS_ID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 5063510 3 34249 19 -491605 20 -491605 21 -491605 22 -491605 23 -491605 74 18325 87 -343801 92 -364411 100 20791 101 20791 102 20791 103 20791 104 20791 202 20791 226 -17709 234 5838619 283 4555222 Warning: The "ChEBI" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "chebi_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT" column at position 11 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.