Validation Log 2025-12-15 02:33:19.166196 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005820/mwtab/json Study ID: ST003544 Analysis ID: AN005820 File format: json Status: Contains Validation Issues Number of Issues: 25 Number of Warnings: 21 Number of Value Errors: 24 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "45°C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.